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Journal of Magnetic Resonance (1969)

Fictitious spin description of tunneling effects in NMR

Eric R. Johnston

Published Aug 1, 1988• 1 citation
Publisher
DOI
10.1016/0022-2364(88)90330-7

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In the usual quantum tunneling, a low-energy quantum particle penetrates across a physical barrier of higher potential energy, by traversing a classically forbidden region, and finally escapes into another region. In an analogous scenario, a classical particle inside a closed regular region in the phase space is dynamically bound from escaping to other regions of the phase space. Here, the physical potential barrier is replaced by dynamical barriers which separate different regions of the phase space. However, in the quantum regime, the system can overcome such dynamical barriers and escape through them, giving rise to dynamical tunneling. In chaotic Hamiltonian systems, dynamical tunneling refers to quantum tunneling between states whose classical limits correspond to symmetry-related regular regions separated by a chaotic zone between which any classical transport is prohibited. Here, an experimental realization of dynamical tunneling in spin systems is reported using nuclear magnetic resonance (NMR) architecture. In particular, dynamical tunneling in quantum kicked tops of spin-1 and spin-3/2 systems using two- and three-qubit NMR registers is investigated. By extracting time-dependent expectation values of the angular momentum operator components, size-dependent tunneling behavior for various initial states is systematically investigated. Further, by monitoring the adverse effects of dephasing noise on the tunneling oscillations, we assert the importance of quantum coherence in enabling dynamical tunneling.
Geometric phases have been used in NMR to implement controlled phase shift gates for quantum-information processing, only in weakly coupled systems in which the individual spins can be identified as qubits. In this work, we implement controlled phase shift gates in strongly coupled systems by using nonadiabatic geometric phases, obtained by evolving the magnetization of fictitious spin-1∕21∕21∕2 subspaces, over a closed loop on the Bloch sphere. The dynamical phase accumulated during the evolution of the subspaces is refocused by a spin echo pulse sequence and by setting the delay of transition selective pulses such that the evolution under the homonuclear coupling makes a complete $2\ensuremath{\pi}$ rotation. A detailed theoretical explanation of nonadiabatic geometric phases in NMR is given by using single transition operators. Controlled phase shift gates, two qubit Deutsch-Jozsa algorithm, and parity algorithm in a qubit-qutrit system have been implemented in various strongly dipolar coupled systems obtained by orienting the molecules in liquid crystal media.