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Physical Review A

Inadequacy of Ehrenfest’s theorem to characterize the classical regime

L. E. Ballentine, Yumin Yang, J. P. Zibin

Published Oct 1, 1994• 171 citations
Publisher

Abstract

The classical limit of quantum mechanics is usually discussed in terms of Ehrenfest's theorem, which states that, for a sufficiently narrow wave packet, the mean position in the quantum state will follow a classical trajectory. We show, however, that that criterion is neither necessary nor sufficient to identify the classical regime. Generally speaking, the classical limit of a quantum state is not a single classical orbit, but an ensemble of orbits. The failure of the mean position in the quantum state to follow a classical orbit often merely reflects the fact that the centroid of a classical ensemble need not follow a classical orbit. A quantum state may behave essentially classically, even when Ehrenfest's theorem does not apply, if it yields agreement with the results calculated from the Liouville equation for a classical ensemble. We illustrate this fact with examples that include both regular and chaotic classical motions.

DOI
10.1103/physreva.50.2854

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The classical limit of quantum mechanics is usually discussed in terms of Ehrenfest's theorem, which states that, for a sufficiently narrow wave packet, the mean position in the quantum state will follow a classical trajectory. We show, however, that that criterion is neither necessary nor sufficient to identify the classical regime. Generally speaking, the classical limit of a quantum state is not a single classical orbit, but an ensemble of orbits. The failure of the mean position in the quantum state to follow a classical orbit often merely reflects the fact that the centroid of a classical ensemble need not follow a classical orbit. A quantum state may behave essentially classically, even when Ehrenfest's theorem does not apply, if it yields agreement with the results calculated from the Liouville equation for a classical ensemble. We illustrate this fact with examples that include both regular and chaotic classical motions.
The equations of motion for phase-space moments and correlations are derived systematically for quantum and classical dynamics, and are solved numerically for chaotic and regular motions of the H\'enon-Heiles model. For very narrow probability distributions, Ehrenfest's theorem implies that the centroid of the quantum state will approximately follow a classical trajectory. But the error in Ehrenfest's theorem does not scale with $\ensuremath{\Elzxh},$ and is found to be governed essentially by classical quantities. The difference between the centroids of the quantum and classical probability distributions, and the difference between the variances of those distributions, scale as ${\ensuremath{\Elzxh}}^{2},$ and so are the true measures of quantum effects. For chaotic motions, these differences between quantum and classical motions grow exponentially, with a larger exponent than does the variance of the distributions. For regular motions, the variance of the distributions grows as t2,{t}^{2},t2, whereas the differences between the quantum and classical motions grow as t3.{t}^{3}.t3.
dga te Q L D 4017, Au stra l i a ( Recei ved Jul y 3, 2002) A possibl e way fro m qua ntum me chanics to classical mechanics can b e achie ved w ith an exp onential substitutio n used in the Schr odin ger equation , and then considerin g the classical limit .T his gives a picture of classical Ûuid and an ensemble of classical tra jectories.In di ˜erence from this approach to the classical limit, w hile utilisi ng the same substitution , w e assume a minimum uncertainty w ave packet.It is show n that this approach to the classical limit of quantum mechanics yields a single traj ectory traced by the centroid of the minimum uncertainty w ave packet.T he momentum and the centroid of such packet satisf y the classical H amilton { J acobi equation.
We consider the quantum-to-classical transition for macroscopic systems coupled to their environments. By applying Born's Rule, we are led to a particular set of quantum trajectories, or an unravelling, that describes the state of the system from the frame of reference of the subsystem. The unravelling involves a branch dependent Schmidt decomposition of the total state vector. The state in the subsystem frame, the conditioned state, is described by a Poisson process that involves a non-linear deterministic effective Schrodinger equation interspersed with quantum jumps into orthogonal states. We then consider a system whose classical analogue is a generic chaotic system. Although the state spreads out exponentially over phase space, the state in the frame of the subsystem localizes onto a narrow wave packet that follows the classical trajectory due to Ehrenfest's Theorem. Quantum jumps occur with a rate that is the order of the effective Lyapunov exponent of the classical chaotic system and imply that the wave packet undergoes random kicks described by the classical Langevin equation of Brownian motion. The implication of the analysis is that this theory can explain in detail how classical mechanics arises from quantum mechanics by using only unitary evolution and Born's Rule applied to a subsystem.
A semiclassical approximation is derived by using a family of wavepackets to map arbitrary wavefunctions into phase space. If the Hamiltonian can be approximated as linear over each individual wavepacket, as often done when presenting Ehrenfest's theorem, the resulting approximation is a linear first-order partial differential equation on phase space, which will be referred to as the Schrödinger-Ehrenfest or SE equation. This advectively transports wavefunctions along classical trajectories, so that as a trajectory is followed in time the amplitude remains constant while the phase changes by the action divided by ℏ\hbarℏ. The wavefunction's squared-magnitude is a plausible phase space density and obeys Liouville's equation for the classical time evolution. This is a derivation of the Koopman-von~Neumann (KvN) formulation of classical mechanics, which previously was postulated but not derived. With the time-independent SE equation, continuity of the wavefunction requires the change of phase around any closed path in the torus covered by a classical trajectory to be an integer multiple of 2π2π2π, giving a standing wave picture of old quantum mechanics. While this applies to any system, for separable systems it gives Bohr-Sommerfeld quantization.
Different classical limits of quantum mechanics are discussed in the setting of a simple example, the two-dimensional motion of a spinless electron in a uniform magnetic field. Both the time-independent energy eigenstates and the time-dependent states developing from initial localized states are exactly solvable. In the first example, an ℏ→0 limit with fixed energy leads to a simple ensemble of classical orbits. In the second, ℏ→0 with fixed initial mean position and momentum leads to a unique classical orbit.