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Physical Review A

Energy spectrum shift for a nonadiabatic process

O. J. Kwon, B. H. Cho

Published Oct 1, 1990• 2 citations
Publisher

Abstract

We derive the semiclassical quantization rule for the external system in two interacting systems for a nonadiabatic process. It is shown that this semiclassical quantization rule accommodates the contribution of the averaged value of the geometrical phase per one evolution of the external system.
DOI
10.1103/physreva.42.4374

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While the scattering phase for several one-dimensional potentials can be exactly derived, less is known in multi-dimensional quantum systems. This work provides a method to extend the one-dimensional phase knowledge to multi-dimensional quantization rules. The extension is illustrated in the example of Bogomolny's transfer operator method applied in two quantum wells bounded by step potentials of different heights. This generalized semiclassical method accurately determines the energy spectrum of the systems, which indicates the substantial role of the proposed phase correction. Theoretically, the result can be extended to other semiclassical methods, such as Gutzwiller trace formula, dynamical zeta functions, and semiclassical Landauer–Büttiker formula. In practice, this recipe enhances the applicability of semiclassical methods to multi-dimensional quantum systems bounded by general soft potentials.