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Physics Letters A

Generalized radial equations in a quantum N-body system with non-orthogonal coordinates

Xiaoyan Gu, Bin Duan, Zhong-Qi Ma

Published Oct 1, 2001• 1 citation
Publisher
DOI
10.1016/s0375-9601(01)00581-3

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Abstract Following the recent discussion of Mankame (2026 Eur. J. Phys. 47 025405), we consider the orthogonality of the radial parts of the hydrogen atom wavefunctions, R n , ℓ ( r ) . As Mankame showed, these functions are not in general orthogonal. By this we mean that the overlap integral of the product of two of them weighted by the square of the radial coordinate may be non-zero if the two angular momentum quantum numbers differ. Orthogonality does hold in the case where the two angular momentum quantum numbers are the same, providing that the principal quantum numbers differ. Here we offer an alternate proof of this result, describe some analytic examples to complement Mankame’s numerical ones, and point out some further references on this issue.
Within a stochastic picture quantum systems can be described in terms of kinematic and dynamic equations where the particles follow a conservative diffusion process. Pavon has shown that these equations and the Schrödinger equation can be derived from a quantum Hamilton principle, generalizing the Hamilton principle from classical mechanics. As shown recently by Köppe et al for the one-dimensional case, the reformulation of the quantum Hamilton principle as a stochastic optimal control problem leads to quantum Hamilton equations of motion which can be seen as a non relativistic generalization of Hamilton's equations of motion to the quantum world. In this report we will extend this to higher dimensional problems and derive, by incorporating the concept of supersymmetric quantum mechanics, a general scheme that allows the determination of all bound states within the stochastic framework. Physical principles from classical mechanics like the decoupling of the center-of-mass motion in multi-particle systems or the solution of the Kepler problem, as a special case of the two-body problem, using space-time symmetries, are translated to this formulation of quantum mechanics. We will present numerical results for the ground state and lower excited states of the hydrogen atom in Cartesian coordinates, and, additionally, we will show that for spherically symmetric potentials the solution of the two-body problem can be reduced to a system of equations concerning only the radial part.