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Foundations of Chemistry

Why orbitals do not exist?

Martín Labarca, Olímpia Lombardi

Published Mar 15, 2010• 48 citations
Publisher
DOI
10.1007/s10698-010-9086-5

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The graphic charting of atomic orbitals into the form of chevrons suggests the existence of stealth orbitals occupying the quantum vacant space of the various electronic shells. It is proposed here, the hypothesis that these quantum gates allow transit of electrons from orbital to another, and that these gates can be accesses to quantum singularities without space-time. Singular arithmetic arrangements in the distribution of real and stealthy orbitals of certain genetic code components reinforces the hypothesis to existence of these quantum gates.
By using the reflection positivity method, we rigorously establish some exact properties of a multi-orbital Hubbard model, here adopted to describe a nematic orbital phase transition. We show that, when the on-site intra-orbital Coulomb interaction is equal to the on-site inter-orbital Coulomb interaction, this model supports a staggered nematic orbital order if repulsive or attractive on-site inter-orbital and intra-orbital interactions and off-site repulsive inter-orbital interaction are considered. Depending on the dimensions of the bipartite lattice where the model is defined, we find that, at half-filling, the order may or may not exist. In particular, we prove that the order may exist, in two and three dimensions, at sufficiently low temperatures if the hopping amplitude is small enough.
We demonstrate the existence of compactons matter waves in binary mixtures of Bose-Einstein condensates (BEC) trapped in deep optical lattices (OL) subjected to equal contributions of intraspecies Rashba and Dresselhaus spin-orbit coupling (SOC) under periodic time modulations of the intraspecies scattering length. We show that these modulations lead to a rescaling of the SOC parameters that involves the density imbalance of the two components. This gives rise to density dependent SOC parameters that strongly influence the existence and the stability of compacton matter waves. The stability of SOC-compactons is investigated both by linear stability analysis and by time integrations of the coupled Gross-Pitaevskii equations. We find that SOC restricts the parameter ranges for stable stationary SOC-compacton existence but, on the other side, it gives a more stringent signature of their occurrence. In particular, SOC-compactons should appear when the intraspecies interactions and the number of atoms in the two components are perfectly balanced (or close to being balanced for the metastable case). The possibility to use SOC-compactons as a tool for indirect measurements of the number of atoms and/or the intraspecies interactions is also suggested.