Optical pumping by a single-frequency cw ring dye laser of thick sodium vapor targets (
NL>1013 atoms/
cm2) without buffer gas has been investigated for application in a polarized ion source. The atomic polarization of the sodium was determined from the optical rotation of a second dye laser tuned midway between the
D lines. Rate-equation calculations reproduce the experimental data and predict very high polarizations (
P> 0.8) with the use of one or more single-frequency dye lasers in thick alkali-metal vapor targets.