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Journal of Chemical Education

Momentum Distributions for a Particle in a Box

Ying Q. Liang, Yunhong Zhang, Yves M.X.M. Dardenne

Published Feb 1, 1995• 6 citations
Publisher

Abstract

Analysis of momentum distributions for systems in energy eigenstates of the particle-in-a-box Hamiltonian.
DOI
10.1021/ed072p148

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We construct a discrete non-Hermitian momentum operator, which implements faithfully the non-self-adjoint nature of momentum for a particle in a box. Its eigenfunctions are strictly limited to the interior of the box in the continuum limit, with the quarter wave as first nontrivial eigenstate. We show how to construct the corresponding Hermitian Hamiltonian for the infinite well as a concrete example to realize unitary dynamics. The resulting Hilbert space can be decomposed into a physical and unphysical subspace, which are mutually orthogonal. The physical subspace in the continuum limit reproduces that of the continuum theory and we give numerical evidence that the correct probability distributions for momentum and energy are recovered. Published by the American Physical Society 2024
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In this article we consider two classical problems in Quantum Mechanics, namely the 'particle on a ring' and the 'particle in a box' from the viewpoint of symplectic topology. Interpreting the solutions of the corresponding time independent Schrödinger equation as orbits in a suitably chosen time dependent Hamiltonian system allows us to investigate them using Floer theory. More precisely we extend the definition of Rabinowitz Floer homology to non-autonomous Hamiltonians on R2n\mathbb{R}^{2n}R2n with its standard symplectic structure and show that compactness of the moduli space of J-holomorphic curves still holds. With this homology we are then able to prove existence results for energy EEE eigenstates on the 'ring' or in the 'box' for a big range of exterior potentials.