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Mathematical Proceedings of the Cambridge Philosophical Society

A new notation for quantum mechanics

P. A. M. Dirac

Published Jul 1, 1939• 429 citations
Publisher

Abstract

In mathematical theories the question of notation, while not of primary importance, is yet worthy of careful consideration, since a good notation can be of great value in helping the development of a theory, by making it easy to write down those quantities or combinations of quantities that are important, and difficult or impossible to write down those that are unimportant. The summation convention in tensor analysis is an example, illustrating how specially appropriate a notation can be.

DOI
10.1017/s0305004100021162

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In mathematical theories the question of notation, while not of primary importance, is yet worthy of careful consideration, since a good notation can be of great value in helping the development of a theory, by making it easy to write down those quantities or combinations of quantities that are important, and difficult or impossible to write down those that are unimportant. The summation convention in tensor analysis is an example, illustrating how specially appropriate a notation can be.
The mathematical formalism of quantum theory in terms of vectors and operators in infinite-dimensional complex vector spaces is very abstract. The definitions of many mathematical quantities used do not seem to have an intuitive meaning, which makes it difficult to appreciate the mathematical formalism and understand quantum mechanics. This book provides intuition and motivation to the mathematics of quantum theory, introducing the mathematics in its simplest and familiar form, for instance, with three-dimensional vectors and operators, which can be readily understood. Feeling confident about and comfortable with the mathematics used helps readers appreciate and understand the concepts and formalism of quantum mechanics. This book is divided into four parts. Part I is a brief review of the general properties of classical and quantum systems. A general discussion of probability theory is also included which aims to help in understanding the probability theories relevant to quantum mechanics. Part II is a detailed study of the mathematics for quantum mechanics. Part III presents quantum mechanics in a series of postulates. Six groups of postulates are presented to describe orthodox quantum systems. Each statement of a postulate is supplemented with a detailed discussion. To make them easier to understand, the postulates for discrete observables are presented before those for continuous observables. Part IV presents several illustrative applications, which include harmonic and isotropic oscillators, charged particle in external magnetic fields and the Aharonov–Bohm effect. For easy reference, definitions, theorems, examples, comments, properties and results are labelled with section numbers. Various symbols and notations are adopted to distinguish different quantities explicitly and to avoid misrepresentation. Self-contained both mathematically and physically, the book is accessible to a wide readership, including astrophysicists, mathematicians and philosophers of science who are interested in the foundations of quantum mechanics.
The relationship between physical notions and the structures expressing them is an issue of primary importance the history and philosophy of pre-modern natural philosophy and of modern science. Historical evidence suggests that, when investigating the relationship between physics and mathematics, one should pay attention to the material, sensually perceivable forms mediating it: spoken or written words, drawings, artefacts, descriptions of experimental set-ups or, as the case discussed the present paper, symbolic notation. The reason for this is that, historically, physical notions and their expressions have very often been developed as one, and only distinguished from each other at a later stage. This was for example the case with what we today regard as mathematical and classical mechanics, which were developed the course of the eighteenth century as the discipline of the analysis of motion. When considered from a later point of view, both the physical notions and the concepts involved historical developments appear as being in flux, vague, and, as far as the side is concerned, non-rigorous. In such cases, verbal description, mechanical artefacts or symbols do not simply mediate between physical notions and structures, as might be the case at a later stage, but represent both of them one, allowing the historical actors to construct and manipulate physical-mathematical meaning by following, at times, their physical reasoning and, at times, their criteria of rigour. The history of quantum mechanics offers many examples of how new physics and new mathematics can emerge as one, with symbolic notation playing a central role shaping both. Among the many creators of quantum theory, Paul Dirac was particularly sensitive to questions of notation:
Quantum mechanics is one of the most challenging subjects to learn. It is challenging because quantum phenomenon is counterintuitive, and the mathematics used to explain such a phenomenon is very abstract, and difficult to grasp. This textbook is an attempt to overcome these challenges. Every chapter presents quantum ideas step- by- step in a structured way with a comparison between quantum and classical concepts. It provides a clear distinction between classical and quantum logic. Conceptual questions are provided after every important section so that the reader can test their understanding at every step. Such an approach aids in preventing misconceptions. Problem solving is not restricted to solving differential equations and integration. But it requires to systematically and creatively analyze a problem, to apply the new and powerful concepts for finding a solution and to understand the physical meaning of the solution. The tutorials on special topics are an effort to teach problem solving by actively engaging the reader in a thinking process, to apply the concepts and to understand the physical meaning of the solution. The simulations are provided for some of the topics. The simulations aid in the visualization of the quantum phenomenon, and for meaningful understanding of the mathematics. This approach may lead to development of "quantum mechanical intuition "as well as learning mathematical techniques for problem solving. Most importantly, the book is not flooded with numerous topics that makes the reader confused and distracted, rather the most important topics are discussed at a deeper level. The understanding of quantum mechanics is incomplete without understanding the early ideas and experiments that lead to the development of the quantum theory. Thus, the first two chapters of the book are dedicated to such topics. The key features of this book are: A simplified, structured, and step-by-step introduction to quantum mechanics. The simplification is attained through use of two-level system, step- by- step discussion of important topics in a simplified language at a deeper level, analogies, and visualization using illustrations and simulations A systematic arrangement of topics, and numerous worked- out examples. The presentation of the structure in the mathematical formalism of quantum mechanics provides clarity in understanding complicated and abstract mathematics. It also helps to understand the distinction between the quantum mechanical and classical approaches Conceptual questions at the end of every important section. The conceptual questions can be used in a classroom as a point of discussion between an instructor and students Tutorials on special topics. Simulations on special topics aid in the visualization of the physical phenomenon, and demonstration of the application of mathematics An in-depth discussion of the wave-particle duality, measurement problem, and their philosophical implications in Chapter 2 provides an understanding of the broader meaning of quantum mechanics