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American Journal of Physics

Simplified Derivation of Wigner's Quantum Correction for Thermodynamics

Charlie Harper

Published May 1, 1974• 3 citations
Publisher

Abstract

A simplified derivation of Wigner's quantum-mechanical correction for thermodynamic equilibrium is presented. The analysis is restricted to the quantum statistics of systems with classical analogs.
DOI
10.1119/1.1987708

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Entropy is one of the most basic concepts in thermodynamics and statistical mechanics. The most widely used definition of statistical mechanical entropy for a quantum system is introduced by von Neumann. While in classical systems, the statistical mechanical entropy is defined by Gibbs. The relation between these two definitions of entropy is still not fully explored. In this work, we study this problem by employing the phase-space formulation of quantum mechanics. For those quantum states having well-defined classical counterparts, we study the quantum-classical correspondence and quantum corrections of the entropy. We expand the von Neumann entropy in powers of ℏ by using the phase-space formulation, and the zeroth-order term reproduces the Gibbs entropy. We also obtain the explicit expression of the quantum corrections of the entropy. Moreover, we find that for the thermodynamic equilibrium state, all terms odd in ℏ are exactly zero. As an application, we derive quantum corrections for the net work extraction during a quantum Carnot cycle. Our results bring important insights into the understanding of quantum entropy and may have potential applications in the study of quantum heat engines.
Entropy Beyond the Second Law presents a coherent formulation of all aspects of thermodynamics and statistical mechanics with entropy as the unifying theme. This includes formulating equilibrium theory and explaining the role of the Second Law in establishing the equilibrium state. It also establishes the foundations of non-equilibrium theory by generalizing the concept of entropy in an appropriate way. Finally, it addresses the relationship between classical and quantum statistical mechanics by invoking the collapse of the wave function into entropy states. A secondary purpose is to increase the understanding of entropy and the Second Law, and to correct misapprehensions and errors that have arisen over the years.
In this continuation paper the theory is further extended to reveal the connection between its formal aparatus, dealing with microscopic quantities, and the formal aparatus of thermodynamics, related to macroscopic properties of large systems. We will also derive the Born-Sommerfeld quantization rules from the formalism of the infinitesimal Wigner-Moyal transformations and, as a consequence of this result, we will also make a connection between the later and the path integral approach of Feynman. Some insights of the relation between quantum mechanics and equilibrium states will be given as a natural development of the interpretation of the above results.