In this continuation paper the theory is further extended to reveal the connection between its formal aparatus, dealing with microscopic quantities, and the formal aparatus of thermodynamics, related to macroscopic properties of large systems. We will also derive the Born-Sommerfeld quantization rules from the formalism of the infinitesimal Wigner-Moyal transformations and, as a consequence of this result, we will also make a connection between the later and the path integral approach of Feynman. Some insights of the relation between quantum mechanics and equilibrium states will be given as a natural development of the interpretation of the above results.
In this continuation paper the theory is further extended to reveal the connection between its formal aparatus, dealing with microscopic quantities, and the formal aparatus of thermodynamics, related to macroscopic properties of large systems. We will also derive the Born-Sommerfeld quantization rules from the formalism of the infinitesimal Wigner-Moyal transformations and, as a consequence of this result, we will also make a connection between the later and the path integral approach of Feynman. Some insights of the relation between quantum mechanics and equilibrium states will be given as a natural development of the interpretation of the above results.
In this tenth paper of the series we aim at showing that our formalism, using the Wigner-Moyal Infinitesimal Transformation together with classical mechanics, endows us with the ways to quantize a system in any coordinate representation we wish. This result is necessary if one even think about making general relativistic extensions of the quantum formalism. Besides, physics shall not be dependent on the specific representation we use and this result is necessary to make quantum theory consistent and complete.
The author presents his experience in teaching at a graduate level the quantal exposition of a new non-statistically based paradigm of physics and thermodynamics. This paradigm, called the Unified Quantum Theory of Mechanics and Thermodynamics, applies to all systems large or small (including one particle systems) either in a state of thermodynamic (i.e. stable) equilibrium or not in a state of thermodynamic equilibrium. It uses as its primitives inertial mass, force, and time and introduces the laws of thermodynamics in the most unambiguous and general formulations found in the literature. Starting with a precise definition of system and of state followed by statements and corollaries of the laws of thermodynamics, the thermodynamic formalism is developed without circularity and ambiguity. In this quantal exposition of the new paradigm, a brief review of the formalism of thermodynamics as a general science not limited to stable equilibrium and large (macroscopic) systems as well as a very brief summary of the three prevalent formalisms in classical physics are presented followed by a presentation and development of solutions for a number of elementary problems in quantum physics (e.g., a particle in a box, a harmonic oscillator, a rigid rotor, etc.). These solutions and the maximum entropy principle are then used in a constrained optimization to develop the canonical and grand canonical distributions for Fermi-Dirac and Bose-Einstein types of particles, i.e. for fermions and bosons. This is done without the use of analogies between statistical and thermodynamic results and without additional hypotheses such as the ergodic hypothesis of statistical mechanics. These distributions are then employed under various assumptions (i.e. the Boltzmann, constant-potential, point-particle, and continuous eigenvalue-spectrum approximations) to derive the corresponding thermodynamic property expressions for perfect, semi-perfect (ideal), and Sommerfeld gases as well as for mixtures of ionized and dissociated gases. In a similar fashion but with a change from a single- to a multi-particle partition function and with the addition of various inter-particle potentials for two-particle interactions (e.g., the Lennard-Jones potential, the square-well potential, etc.), expressions for the thermodynamic properties of dense gases are developed and presented.An initial version of this paper was published inJuly of 2006 in the proceedings of ECOS’06, AghiaPelagia, Crete, Greece.
Some aspects of the interpretation of microscopic physics in terms of quantum theory are discussed. It is first emphasized that quantum theory is formulated in a Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutation relations between ''canonically conjugated'' coordinate and momentum operators leads to a wrong version of quantum mechanics. In this connection the Feynman integral formalism is also discussed. In this formalism the measure is not well defined, and there is no idea how to distinguish between the true version of quantum mechanics and an incorrect one. In this respect, the Feynman approach consists of a mnemonic rule to generate perturbation series from an undefined zero-order term. The origin of time in the quantum framework is then analyzed in detail and illustrated by the example of atomic collisions. It is shown that the time-dependent Schr ¨ odinger equation for the closed three-body (two nuclei + electron) system has no physical meaning because in the high-impact energy limit it transforms into an equation with two independent time-like variables; time naturally appears in the stationary Schr ¨ odinger equation as a result of extraction of a classical subsystem (two nuclei) from a closed three-body system. Finally, following the well-known Einstein-Rosen-Podolsky experiment and Bell's inequality, we reiterate that the wave function must be interpreted as an actual field of information, in a form as elementary as the usual material particles and electromagnetic fields. In fact, experimental measurements transfer this quantum information field into the classical world, which is directly discernable. In my conclusion, the relation between physical reality and its mathematical formulation is discussed. 2012 Physics Essays Publication. (DOI: 10.4006/0836-1398-25.1.27) R ´
We establish a rather deep relation between statistical mechanics and quantum mechanics at an imaginary time. For the quantum field theory, this implies a relation between finite temperature quantum field theory in Minkowski space and quantum field theory in Euclidean space with one compact Euclidean time direction. The quantum mechanical language being a proper formulation of statistical physics as a molecular theory is basically the study of quantum equilibrium as well as non-equilibrium systems. A quantum system found in a thermodynamic equilibrium state with an external classical system (thermostat or thermal reservoir) may be characterized by fixed values of thermodynamic parameters of the system, say, for example, temperature T , volume V and number of particles N . In this way the total energy of the thermostat is assumed to be much greater than the energy of the system. The behavior of the quantum system may be assumed to be independent of the nature of the thermostat. The most convenient object of the quantum theory to describe such non-isolated systems is the density matrix since the partition function does not determine any local thermodynamic quantities. It is for this reason that we introduced quantum mechanical and quantum statistical density matrices which are necessary to do the investigation via path integration. This enables us to make a transition to the quasi-classical approximation of quantum statistical mechanics, which, in turn, enables us to evaluate the first quantum correction to the classical Boltzmann distribution function.
Starting from the axioms of quantum mechanics as formalized by the systems of imprimitivity for homogeneous Riemannian manifolds, the classical theory is derived as a consequence, complete with its phase space realized as the space of pure classical states, a generalized version of the Wigner–Moyal correspondence rule, the Jordan and Lie algebra structures of functions on the cotangent bundle, given by point-wise multiplication and Poisson bracket, and the momentum map. A comparison is also given of the quantum and classical dynamics and equilibrium statistical mechanics of free particles on compact manifolds of constant negative curvature.
Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum systems. In the present contribution a simple but effective theoretical framework is introduced to clarify the connections between a purely mechanical description and the thermodynamic characterization of the equilibrium state of an isolated quantum system. A salient feature of our approach is the very transparent distinction between the statistical aspects and the dynamical aspects in the description of isolated quantum systems. Like in the classical statistical mechanics, the equilibrium distribution of any property is identified on the basis of the time evolution of the considered system. As a consequence equilibrium properties of quantum system appear to depend on the details of the initial state due to the abundance of constants of the motion in the Schrodinger dynamics. On the other hand the study of the probability distributions of some functions, such as the entropy or the equilibrium state of a subsystem, in statistical ensembles of pure states reveals the crucial role of typicality as the bridge between macroscopic thermodynamics and microscopic quantum dynamics. We shall consider two particular ensembles: the random pure state ensemble and the fixed expectation energy ensemble. The relation between the introduced ensembles, the properties of a given isolated system, and the standard quantum statistical description are discussed throughout the presentation. Finally we point out the conditions which should be satisfied by an ensemble in order to get meaningful thermodynamical characterization of an isolated quantum system.