The concept of indistinguishability is the key element in quantum statistics. But, are particles really either indistinguishable or distinguishable? Most works begin with the premise that all the particles, for example, in a quantum gas, are indistinguishable. Can we vary the degree of distinguishability in some controlled, continuous manner and see how it affects the behavior of the quantum gas, such as Bose-Einstein condensation (BEC)? We have found a complex parameter with a definite phase that does just that. As it deviates from zero, a gas mixture of originally indistinguishable bosons would divide into several distinct species that undergo BEC individually. Each species is found to be in a new type of atomic state whose spin structure adapts itself to the prevailing densities of the gases in the mixture.
The concept of indistinguishability is the key element in quantum statistics. But, are particles really either indistinguishable or distinguishable? Most works begin with the premise that all the particles, for example, in a quantum gas, are indistinguishable. Can we vary the degree of distinguishability in some controlled, continuous manner and see how it affects the behavior of the quantum gas, such as Bose-Einstein condensation (BEC)? We have found a complex parameter with a definite phase that does just that. As it deviates from zero, a gas mixture of originally indistinguishable bosons would divide into several distinct species that undergo BEC individually. Each species is found to be in a new type of atomic state whose spin structure adapts itself to the prevailing densities of the gases in the mixture.
A Bose-Einstein condensate (BEC), the first of which was shown experimentally 22 years ago, isn’t your garden variety state of matter. It formed at a fraction above absolute zero and only in atoms that act like bosons, one of two types of fundamental particles. Bosons don’t follow the Pauli exclusion principle, which prohibits two particles from existing in the same quantum state. When bosonic atoms are cooled to form a condensate, they can lose their individuality. They behave like one big collective superatom, analogous to how photons become indistinguishable in a laser beam. But it’s even weirder than that.
This velocity-distribution data for a gas of rubidium atoms confirmed the discovery of the Bose–Einstein condensate in 1995. In these three snapshots in time, atoms—cooled to near absolute zero—condensed from less dense areas on the left (red, yellow, and green) to very dense areas at the center and the right (blue and white). Image courtesy of NIST/JILA/CU-Boulder.
“In a very good analogy, one can view a BEC as a bell, which begins to ring spontaneously when it is cooled below a certain temperature,” writes physicist Nick Proukakis at the Joint Quantum Centre Durham–Newcastle in the United Kingdom, in Universal Themes of Bose–Einstein Condensation , a forthcoming collection of research essays on progress in BECs (1). That behavior provides physicists with an extraordinary opportunity: to study bizarre quantum effects on a large scale, instead of having to probe individual particles.
For the last two decades, physicists have treated BECs something like Play-Doh. They poke it, smash it, tickle it with lasers, and trap it in magnetic fields. They mix condensates together to see what happens, and use it to slow down light (2). They have observed strange behaviors that would have been impossible to predict even two decades ago: solids that flow …
Ideal Bose-Einstein condensation (BEC) remains a paradigmatic example of a continuous phase transition and a cornerstone for understanding quantum degenerate bosonic matter. We demonstrate that critical behavior of the ideal Bose gas near the BEC phase transition falls into three distinct classes, determined exclusively by the low-energy scaling of the density of states. Depending on its scaling exponent, which is controlled by dimensionality and confinement, the transition displays either the usual algebraic divergences of thermodynamic susceptibilities, divergent behavior with marginal logarithmic corrections, or a more subtle form of criticality, where only the correlation length diverges. Our work provides a unified framework for criticality in noninteracting bosonic systems. This classification applies broadly to atomic, photonic, polaritonic, and magnonic condensates, where dimensionality, confinement, and spectral engineering can strongly reshape the density of states.
About seven decades ago Satyendra Nath Bose and Albert Einstein predicted that a gas of noninteracting integer-spin particles would condense into a macroscopic quantum state when cooled below a critical temperature. Of course Bose–Einstein condensation (BEC) has long since been seen in superfluid He4 and superconductors, but the condensing systems in these examples are far from being noninteracting gases; relatively strong interactions between the condensing particles greatly complicate the theoretical analysis and the experimental behavior. For more than 15 years groups have been cooling and compressing clouds of atoms on a quest to produce and observe a Bose–Einstein condensate in a nearideal gas. They pushed their devices to the limit, seeking to traverse 15 orders of magnitude of phase-space density, and as each technique proved insufficient they developed ingenious variations to create ever colder and denser states.
In quantum mechanics, elementary particles of the same type are considered identical. For example, an electron in an atom could be replaced by another electron and the atom would behave in exactly the same way. Nature has taken particular advantage of this, allowing only two types of elementary particles: bosons and fermions. They differ fundamentally in how a collection of identical particles interact. Identical fermions cannot occupy the same quantum state (only one per state!). Identical bosons can occupy the same quantum state. The statistics of identical particles (how they act in groups) has profound affects. For example, the rich and complex structure of the periodic table arises from the principle that only one electron can occupy each quantum state. The spin and the statistics of particles are closely connected: (fermions) bosons have (half-)integer spin. (Spin is an internal angular momentum measured in units of Planck’s constant.)
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
We consider a mixture of two species of spin-1 atoms with interspecies spin exchange, which may cooperate or compete with intraspecies spin exchanges and thus dramatically affect the ground state. It represents a new class of bosonic gases differing from single-species spinor gases. We determine the exact ground states in several parameter regimes and study the composite structures using the generating function method generalized here to be applicable to a mixture of two species of spinor gases. The most interesting phase is the so-called entangled Bose-Einstein condensation (BEC), which is fragmented BEC with quantum entanglement between the two species and with both interspecies and intraspecies singlet pairs. For comparison, we also apply the generating function method to a mixture of two species of pseudospin-21 atoms, for which the total spin quantum number of each species is fixed as half of the atom number, in contrast with the case of spin 1, for which it is a variable determined by energetics. Consequently, singlet pairs in entangled BEC of a pseudospin-21 mixture are all interspecies. Interspecies spin exchange leads to novel features beyond those of spinor BEC of a single species of atoms as well as mixtures without interspecies spin exchange.