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European Journal of Physics

Approximations of time-dependent phenomena in quantum mechanics: adiabatic versus sudden processes

S V Melnichuk, W. van Dijk, Yukihisa Nogami

Published Apr 5, 2005• 3 citations
Publisher

Abstract

By means of a one-dimensional model of a particle in an infinite square-well potential with one wall moving at a constant speed, we examine aspects of time-dependent phenomena in quantum mechanics such as adiabatic and sudden processes. The particle is assumed to be initially in the ground state of the potential with its initial width. The time dependence of the wavefunction of the particle in the well is generally more complicated when the potential well is compressed than when it is expanded. We are particularly interested in the case in which the potential well is suddenly compressed. The so-called sudden approximation is not applicable in this case. We also study the energy of the particle in the changing well as a function of time for expansion and contraction as well as for expansion followed by contraction and vice versa.

DOI
10.1088/0143-0807/26/3/019

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By means of a one-dimensional model of a particle in an infinite square-well potential with one wall moving at a constant speed, we examine aspects of time-dependent phenomena in quantum mechanics such as adiabatic and sudden processes. The particle is assumed to be initially in the ground state of the potential with its initial width. The time dependence of the wavefunction of the particle in the well is generally more complicated when the potential well is compressed than when it is expanded. We are particularly interested in the case in which the potential well is suddenly compressed. The so-called sudden approximation is not applicable in this case. We also study the energy of the particle in the changing well as a function of time for expansion and contraction as well as for expansion followed by contraction and vice versa.
By means of a one-dimensional model of a particle in an infinite square-well potential with one wall moving at a constant speed, we examine aspects of time-dependent phenomena in quantum mechanics such as adiabatic and sudden processes. The particle is assumed to be initially in the ground state of the potential with its initial width. The time dependence of the wavefunction of the particle in the well is generally more complicated when the potential well is compressed than when it is expanded. We are particularly interested in the case in which the potential well is suddenly compressed. The so-called sudden approximation is not applicable in this case. We also study the energy of the particle in the changing well as a function of time for expansion and contraction as well as for expansion followed by contraction and vice versa.
The one-dimensional square quantum well of varying width is shown to be an instructive example for testing the appropriateness of approximate solutions in quantum mechanics. The range of wall speeds over which the adiabatic approximation is applicable is investigated and related to the initial energy of the quantum system for both expanding and contracting wells. However, of more interest is the applicability of the sudden approximation to these systems. It is shown that this approximation is appropriate for expanding wells at quite modest wall speeds, whereas the approximation cannot be applied for contracting wells no matter how rapidly the well width contracts. The physical reasons for the inapplicability of the sudden approximation for contracting wells is investigated.
The motion of a quantum particle in a time-dependent circular billiard is studied on the basis of the Schrödinger equation with time-dependent boundary conditions.The cases of monotonically expanding (contracting), non-harmonically, harmonically breathing circles the case when billiard wall suddenly disappears are explored in detail.The exact analytical solutions for monotonically expanding and contracting circles are obtained.For all cases, the time-dependence of the quantum average energy is calculated.It is found that for an harmonically breathing circle, the average energy is time-periodic in the adiabatic regime with the same period as that of the oscillation.For intermediate frequencies which are comparable with the initial frequency of the particle in unperturbed billiard, such periodicity is broken.However, for very high frequencies, the average energy once again becomes periodic.A qualitative analysis of the border between adiabatic and non-adiabatic regimes is provided.
The time-dependent Schrödinger equation with a time-dependent delta function potential is solved exactly for many special cases. In all other cases the problem can be reduced to an integral equation of the Volterra type. It is shown that by knowing the wavefunction at the origin, one may derive the wavefunction everywhere. Thus, the problem is reduced from a PDE in two variables to an integral equation in one. These results are used to compare adiabatic versus sudden changes in the potential. It is shown that adiabatic changes in the potential lead to the conservation of the normalization of the probability density.