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Journal of the Physical Society of Japan

On the Theory of Brownian Motion and Spin Relaxation

Takeyasu Kotera, Morikazu Toda

Published Nov 1, 1959• 7 citations
Publisher

Abstract

The Brownian motion of a harmonic oscillator is treated quantum-mechanically and the same method is applied to the relaxation of a spin. The method is quite general and applicable to a system displaced from the equilibrium state by an arbitrary amount initially. The oscillator or the spin is interacting with a thermostat composed of a great number of harmonic oscillators. The equation of motion is solved in operator form taking average as to the thermostat to the second order of the interaction parameter. The Langevin equation, the Kramers-Chandra-sekhar equation for a harmonic oscillator and the Bloch equation for a static field are derived.

DOI
10.1143/jpsj.14.1475

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The Brownian motion of a harmonic oscillator is treated quantum-mechanically and the same method is applied to the relaxation of a spin. The method is quite general and applicable to a system displaced from the equilibrium state by an arbitrary amount initially. The oscillator or the spin is interacting with a thermostat composed of a great number of harmonic oscillators. The equation of motion is solved in operator form taking average as to the thermostat to the second order of the interaction parameter. The Langevin equation, the Kramers-Chandra-sekhar equation for a harmonic oscillator and the Bloch equation for a static field are derived.
The theory of Brownian motion of a quantum oscillator is presented. The equation of motion for the density operator of the oscillator is obtained by a model Hamiltonian which characterizes the interaction between this oscillator and a reservoir. By applying iteration methods the equation of motion is solved and the time development of the density operator is obtained. The solution is then used to write the normally ordered generating functional for the field of the oscillator executing Brownian motion. This field appears to be the superposition of a thermal field in equilibrium with the reservoir, a chaotic field, and a field statistically similar to the one before the interaction. Next, it is shown that for large times the oscillator approaches equilibrium; moreover, it is shown that, if the reservoir is at zero temperature and initially the state of the oscillator is a coherent state, then it remains in a coherent state for later time. In order to obtain by differentiation two-time modal densities, a suitable two-time generating functional is introduced. This functional allows two-time averages to be computed from one-time averages before the interaction. Finally, some time-dependent statistical properties of the oscillator are studied.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.
A method is developed for generating relaxation by introducing a fundamental interval $\ensuremath{\tau}$ and a stirring hypothesis. The application to spin and harmonic oscillator systems is discussed in some detail. All the results are obtained by exact calculations without applying perturbation theory as the systems considered are simple and completely soluble. Equations similar to phenomenological Bloch equations are derived in the case of spin systems. The relaxation times obtained by the application of the theory are not only proportional to the strength of interaction, but also to the fundamental interval $\ensuremath{\tau}$ which plays an important role in the theory. It is shown that in the case of a harmonic oscillator system, an initial Boltzmann distribution relaxes to a final equilibrium Boltzman distribution through a sequence of transient Boltzman distributions.
The author presents a quantum Langevin equation in the Schrodinger picture. The friction term is motivated by a natural generalisation of Wigner's theorem or, equivalently, of Dirac's superposition principle. The author applies the model to spin relaxation and to the Brownian motion of the harmonic oscillator. In both cases the state vectors evolve asymptotically to a distribution which has the Gibbs state as corresponding density matrix. It is shown that for any initial state, the harmonic oscillator tends to a coherent state.
The theory of Brownian motion of a quantum oscillator is developed. The Brownian motion is described by a model Hamiltonian which is taken to be the one describing the interaction between this oscillator and a reservoir. Use is made of the master equation recently derived by the author, to obtain the equation of motion for the various reduced phase-space distribution functions that are obtained by mapping the density operator onto ccc-number functions. The equations of motion for the reduced phase-space distribution functions are found to be of the Fokker-Planck type. On transforming the Fokker-Planck equation to real variables, it is found to have the same form as the Fokker-Planck equation obtained by Wang and Uhlenbeck to describe the Brownian motion of a classical oscillator. The Fokker-Planck equation is solved for the conditional probability (Green's function) which is found to be in the form of a two-dimensional Gaussian distribution. This solution is then used to obtain various time-dependent quantum statistical properties of the oscillator. Next, the entropy for a quantum oscillator undergoing Brownian motion is calculated and we show that this system approaches equilibrium as $t\ensuremath{\rightarrow}\ensuremath{\infty}$. Finally we show that in the weak-coupling limit the Fokker-Planck equation reduces to the one obtained by making the usual rotating-wave approximation.
We consider a paradigmatic model of a quantum Brownian particle coupled to a thermostat consisting of harmonic oscillators. In the framework of a generalized Langevin equation, the memory (damping) kernel is assumed to be in the form of exponentially-decaying oscillations. We discuss a quantum counterpart of the equipartition energy theorem for a free Brownian particle in a thermal equilibrium state. We conclude that the average kinetic energy of the Brownian particle is equal to thermally-averaged kinetic energy per one degree of freedom of oscillators of the environment, additionally averaged over all possible oscillators' frequencies distributed according to some probability density in which details of the particle-environment interaction are present via the parameters of the damping kernel.