We present quantum phase transitions and critical phenomena of three-body Coulomb systems with charges (Q, q, Q) and masses (M, m, M). Full numerical results, using the finite-size scaling method, for an arbitrary mass ratio $0<~\ensuremath{\kappa}{=(1+m/M)}^{\ensuremath{-}1}<~1$ over the range $1<~\ensuremath{\lambda}=|Q/q|<~1.25,$ show that there exists a transition curve ${\ensuremath{\lambda}}_{c}(\ensuremath{\kappa})$ through which all systems undergo a first-order phase transition from stable to unstable. Particularly, ${\ensuremath{\lambda}}_{c}(\ensuremath{\kappa})$ has a minimum at ${\ensuremath{\kappa}}_{m}=0.35,$ which leads to a new proposed classification of the three-body Coulomb systems: moleculelike systems, $\ensuremath{\kappa}>{\ensuremath{\kappa}}_{m},$ such as ${\mathrm{Ps}}^{\ensuremath{-}}$ $(\ensuremath{\kappa}=0.5)$ and atomlike systems, $\ensuremath{\kappa}<{\ensuremath{\kappa}}_{m},$ such as ppd $(\ensuremath{\kappa}=0.33).$
We show that the symmetry breaking of the electronic structure configurations at the large-D limit is completely analogous to the standard phase transitions and critical phenomena in statistical mechanics. Electronic structure at the large-D limit exhibits critical points with mean field critical exponents ( $\ensuremath{\beta}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\frac{1}{2}$, $\ensuremath{\alpha}{\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}0}_{\mathrm{dis}}$, $\ensuremath{\delta}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3$, and $\ensuremath{\gamma}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}1$). The complete mapping is presented for the Hartree-Fock two-electron atom in weak electric field and the two Coulomb center problems.
Nonlinear d -dimensional vector σ models, such as O ( N ), SU ( N ), and CP N , are considered in the limit of an infinite number of components N . It is shown that the equation for the two-point correlation function in these models is similar to the Schrödinger equation for a quantum particle moving in a δ-function potential well (− T )δ( x ), where T is the temperature. This equation adequately describes the systems under study both above and below the Curie point. Within this approach, the critical behavior of the SU ( N )-invariant Ginzburg-Landau model in an external uniform magnetic field is determined in the vicinity of the upper critical magnetic field. The critical indices in this case are the same as in the spherical model in a random magnetic field. An exact equation describing the H c 2 ( T ) curve of continuous phase transitions is derived, which allows one to determine the asymptotes of this curve in strong and weak fields. The relation between the one-particle Schrödinger equation and critical phenomena is analyzed, and applications of this method to various models in solid state physics and statistical mechanics are discussed.
In this review we discuss quantum phase transitions and the mapping between symmetry breaking of electronic structure configurations at the large-dimension limit and mean-field theory of phase transitions. We show that the finite size scaling method can be used for the calculations of the critical parameters of the few-body Schrodinger equation. In this approach, the finite size corresponds to the number of elements in a complete basis set used to expand the exact eigenfunction of a given Hamiltonian. The critical parameters such as the critical nuclear charges will be used to explain and predict the stability of atomic and molecular negative ions. For N-electron atoms with 2 N 86, results show that, at most, only one electron can be added to a free atom in the gas phase. However, doubly charged atomic negative ions might exist in a strong magnetic field.
We have studied the critical properties of three-dimensional U(1)-symmetric lattice gauge theories. The models apply to various physical systems such as insulating phases of strongly correlated electron systems as well as superconducting and superfluid states of liquid metallic hydrogen under extreme pressures. This thesis contains an introductory part and a collection of research papers of which seven are published works and one is submitted for publication.\n\nPaper I: Critical properties of the 2+1-dimensional compact abelian Higgs model with gauge charge q=2 are studied. We introduce a novel method of computing the third moment M3 of the action which allows us to extract correlation length and specific heat critical exponents ν and α without invoking hyperscaling. Finite-size scaling analysis of M3 yields the ratio (1+α)/ν and 1/ν separately. We find that α and ν vary along the critical line of the theory, which however exhibits a remarkable resilience of Z2 criticality. We conclude that the model is a fixed-line theory, which we propose to characterize the zero temperature quantum phase transition from a Mott-Hubbard insulator to a charge fractionalized insulator in two spatial dimensions.\n\nPaper II: Large scale Monte Carlo simulations are employed to study phase transitions in the three-dimensional compact abelian Higgs model in adjoint representations of the matter field, labeled by an integer q, for q=2,3,4,5. We also study various limiting cases of the model, such as the Zq lattice gauge theory, dual to the 3DZq spin model, and the 3D xy spin model which is dual to the Zq lattice gauge theory in the limit q → ∞. In addition, for benchmark purposes, we study the 2D square lattice 8-vertex model, which is exactly solvable and features non-universal critical exponents. The critical exponents α and ν are calculated from finite size scaling of the third moment of the action, and the method is tested thoroughly on models with known values for these exponents. We have found that for q=3, the three-dimensional compact abelian Higgs model exhibits a second order phase transition line which joins a first order phase transition line at a tricritical point. The results for q=2 in Paper I are reported with a higher lever of detail.\n\nPaper III: This paper is based on a talk by F. S. Nogueira in the Aachen HEP 2003 conference where a review of the results for the compact abelian Higgs model from Paper I and Paper II was presented, as well as the results for the q=1 case studied by F. S. Nogueira, H. Kleinert and A. Sudbø.\n\nPaper IV: We study the effects of a Chern-Simons (CS) term in the phase structure of two different abelian gauge theories in three dimensions. By duality transformations we show how the compact U(1) gauge theory with a CS term for certain values of the CS coupling can be written as a gas of vortex loops interacting through steric repulsion. This theory is known to exhibit a phase transition governed by proliferation of vortex loops. We also employ Monte Carlo simulations to study the non-compact U(1) abelian Higgs model with a CS term. Finite size scaling of the third moment of the action yields critical exponents α and ν that vary continuously with the strength of the CS term, and a comparison with available analytical results is made.\n\nPaper V: The critical properties of N-component Ginzburg-Landau theory are studied in d=2+1 dimensions. The model is dualized to a theory of N vortex fields interacting through a Coulomb and a screened potential. The model with N=2 shows two anomalies in the specific heat. From Monte Carlo simulations we calculate the critical exponents α and ν and the mass of the gauge field. We conclude that one anomaly corresponds to an inverted 3D xy fixed point, while the other corresponds to a 3D xy fixed point. There are N fixed points, namely one corresponding to an inverted 3D xy fixed point, and N-1corresponding to neutral 3D xy fixed points. Applications are briefly discussed.\n\nPaper VI: The phase diagram and critical properties of the N-component London superconductor are studied both analytically and through large-scale Monte-Carlo simulations in d=2+1 dimensions. The model with different bare phase stiffnesses for each flavor is a model of superconductivity which should arise out of metallic phases of light atoms under extreme pressure. A projected mixture of electronic and protonic condensates in liquid metallic hydrogen under extreme pressure is the simplest example, corresponding to N=2 with individually conserved matter fields. We compute critical exponents α and ν for N=2 and N=3. The results from Paper V are presented at a higher level of detail. For the arbitrary N case, there are N fixed points,namely one charged inverted 3D xy fixed point, and N-1 neutral 3D xy fixed points. We explicitly identify one charged vortex mode and N-1 neutral vortex modes. The model for N=2 and equal bare phase stiffnesses corresponds to a field theoretical description of an easy-plane quantum antiferromagnet. In this case, the critical exponents are computed and found to be non 3D xy values. Furthermore, we study the model in an external magnetic field, and find a novel feature, namely N-1 superfluid phases arising out of N charged condensates. In particular, for N=2 we point out the possibility of two novel types of field-induced phase transitions in ordered quantum fluids: i) A phase transition from a superconductor to a superfluid or vice versa, driven by tuning an external magnetic field. This identifies the superconducting phase of liquid metallic hydrogen as a novel quantum fluid. ii) A phase transition corresponding to a quantum fluid analogue of sublattice melting, where a composite field-induced Abrikosov vortex lattice is decomposed and disorders the phases of the constituent condensate with lowest bare phase stiffness. Both transitions belong to the 3D xy universality class.\n\nPaper VII: We consider the vortex superconductor with two individually conserved condensates in a finite magnetic field. The ground state is a lattice of cocentered vortices in both order parameters. We find two novel phase transitions when temperature is increased at fixed magnetic field. i) A "vortex sublattice melting" transition where vortices in the field with lowest phase stiffness ("light vortices") loose cocentricity with the vortices with large phase stiffness ("heavy vortices"), entering a liquid state (the structure factor of the light vortex sublattice vanishes continuously.) This transition is in the 3D xy universality class. ii) A first order melting transition of the lattice of heavy vortices in a liquid of light vortices.\n\nPaper VIII: We report on large-scale Monte Carlo simulations of a novel type of a vortex matter phase transition which should take place in a three dimensional two-component superconductor. We identify the regime where first, at a certain temperature a field-induced lattice of co-centered vortices of both order parameters melts, causing the system to loose superconductivity. In this state the two-gap system retains a broken composite symmetry and we observe that at a higher temperature it undergoes an extra phase transition where the disordered composite one-flux-quantum vortex lines are "ionized" into a "plasma" of constituent fractional flux vortex lines in individual order parameters. This is the hallmark of the superconductor-to-superfluid-to-normal fluid phase transitions projected to occur in e.g. liquid metallic hydrogen.
Abstract The theory of quantum critical phenomena is introduced to study some current many-body problems in condensed matter physics. Renormalization group concepts are applied to strongly correlated electronic materials which are close to a zero-temperature instability. These systems have enhanced effective masses and susceptibility. Scaling arguments yield the exponents which govern the critical behavior of these quantities in terms of the usual critical exponents associated with a zero-temperature phase transition. We show the existence of a new energy scale, related to the quantum nature of the many-body instability, which can be generally associated with the setting of Fermi-liquid behavior with decreasing temperature in three-dimensional strongly interacting electronic systems. The theory of quantum critical phenomena is used to investigate the Kondo lattice problem, which provides a model to describe heavy-fermion systems and to introduce a scaling theory of the Mott transition with special emphasis on charge fluctuation effects. However, this report is not a review on heavy fermions and Mott insulators. The microscopic theories of these systems are still controversial and present some of the most challenging and instigating problems in condensed matter physics. This state of affairs stimulated the author to review and extend the scaling approach. The scaling theory we develop provides a powerful tool, based on the notion of universality, to understand the physical properties of correlated systems beyond the mean-field level. This is illustrated by our treatment of the one-dimensional Hubbard model, where, although the Fermi-liquid fixed point does not survive the fluctuations, the scaling approach is still useful. Finally, we discuss briefly how disorder affect our results.