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Journal of Physics A Mathematical and General

High-temperature series expansion analyses of mixed-spin Ising model

S. L. Schofield, Roger Bowers

Published Aug 1, 1981• 25 citations
Publisher

Abstract

A high-temperature series expansion in the cumulant form of Brout (1959, 1960) is applied to mixed-spin Ising models on simple quadratic, simple cubic and body-centred cubic lattices. Motivation is provided primarily by an investigation of critical phenomena in Ising models with less than the usual translational symmetry and of relevance to the study of ferrimagnetism. Secondary motivation, appropriate to the simple quadratic lattice, is derived from a desire to obtain results that can be compared with those of renormalisation-group calculations performed elsewhere by the authors. Series expansions of the susceptibility and specific heat are obtained to seventh and tenth order, respectively. The derived expansion coefficients are analysed through both ratio and Pade approximant methods and exponent values are found to be in good agreement with those suggested by the universality hypothesis.

DOI
10.1088/0305-4470/14/8/036

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Chinese Physics Letters•Apr 1, 1994•2 citations
A high-temperature series expansion in the cumulant form of Brout (1959, 1960) is applied to mixed-spin Ising models on simple quadratic, simple cubic and body-centred cubic lattices. Motivation is provided primarily by an investigation of critical phenomena in Ising models with less than the usual translational symmetry and of relevance to the study of ferrimagnetism. Secondary motivation, appropriate to the simple quadratic lattice, is derived from a desire to obtain results that can be compared with those of renormalisation-group calculations performed elsewhere by the authors. Series expansions of the susceptibility and specific heat are obtained to seventh and tenth order, respectively. The derived expansion coefficients are analysed through both ratio and Pade approximant methods and exponent values are found to be in good agreement with those suggested by the universality hypothesis.
For pt. I see ibid., vol. 5, no. 5, 624. Extended series expansions for the high temperature zero-field susceptibility of the Ising model are given in powers of the usual high temperature counting variable v=tanh K for the simple cubic lattice to v 17 , the body-centred cubic lattice to v 15 , and the face-centred cubic lattice to v 12 , inclusive. The coefficients are analysed by the ratio method and it is estimated that, subject to the implicit assumptions thereof, the critical temperatures correspond to v f =0.21813+or-0.00001 (SC), v f =0.15612+or-0.00003 (BCC) and v f =0.10174+or-0.00001 (FCC). The symptotic behaviour of the coefficients is studied in detail; for the loose-packed lattices the decay of the even-odd oscillation in the ratios is found to be consistent with the assumption that the critical index of the high temperature specific heat is very close to 1/8.
We have extended the series for the zero-field susceptibility of the spin-sss Ising model through tenth order in the reduced inverse temperature KKK on the square, triangular, simple-cubic, body-centered-cubic, and face-centered-cubic lattices. The series coefficients hn(s){h}_{n}(s)hn​(s) are expressed as simple polynomials in X=s(s+1)X=s(s+1)X=s(s+1). Using extended methods of analysis we have estimated the nature of the leading singularities on the face-centered lattice and conclude with good confidence that the susceptibility exponent ${\ensuremath{\gamma}}_{1}$ equals 1.25, independent of sss. The exponent of the leading correction term is estimated to be ${\ensuremath{\gamma}}_{2}\ensuremath{\simeq}0.75\ifmmode\pm\else\textpm\fi{}0.08$ in good agreement with renormalization-group theory. For s=12s=\frac{1}{2}s=21​ only, the amplitude of the confluent correction apparently vanishes. We have also studied the leading singularities on the triangular lattice and conclude that ${\ensuremath{\gamma}}_{1}=\frac{7}{4}$, independent of sss, with, however, much stronger corrections than in three dimensions. These results provide a very strong corroboration of the universality hypothesis.
For pt. III, see abstr. A21890 of 1970. A new low-temperature expansion variable for the Ising model is given. Expansions in the new variable, x=1-tanh(J/kT), then converge right up to the critical point. Power series in the new variable are derived, and then analysed by the Pade method and the method of N-point fits. For the spontaneous magnetization of the Ising model in three dimensions. beta =0.312+or-0.002 for the simple cubic lattice, beta =0.3125+or-0.0015 for the body-centred cubic lattice, and beta =0.312+or-0.004 for the face-centred cubic lattice. For the low-temperature susceptibility gamma =1.30+or-0.02, gamma =1.28+or-0.04, and gamma '=1.29+or-0.04 for the simple cubic, body-centred cubic and face-centred cubic lattices respectively. For the low-temperature specific heat the authors estimate 1 / 16 <or= alpha =0.2 for all three lattices.
Describes the development of high-temperature series expansions for general mixed spin-S-spin-S' Ising models on simple loose-packed lattices. It extends previous work on the simpler special case S'=1/2. Coefficients of the series for the initial susceptibility and specific heat of these models on the square, SC and BCC lattices are presented. A preliminary analysis of the results for the particular case S=1, S'=3/2 is given, and the critical ratio K c and the susceptibility exponent gamma are estimated.
First, a new method proposed by Baker and Rushbrooke is used to study the simple ferromagnetic Ising model at and below the Curie temperature. Of course, the properties of the Ising model are already well known, so that the main aim here is to assess the potential and reliability of the new method, since it has wide applicability to other models which have not been otherwise studied. Between 8 and 16 coefficients of exact high-temperature expansions for fixed values of the magnetization are derived for various two- and three-dimensional lattices. A Pad\'e-approximant analysis of these expansions at the critical isotherm and magnetic phase boundary enables us to estimate the critical exponents $\ensuremath{\beta}$, ${\ensuremath{\gamma}}^{\ensuremath{'}}$, and $\ensuremath{\delta}$, and plot the spontaneous magnetization. The results are in good agreement with previous calculations. Secondly, an analysis of the exact series expansions provides no support for the conjecture that the phase boundary is a line of essential singularities. However, the same expansions strongly suggest the existence of a "spinodal" curve, whose properties are in reasonable agreement with the predictions of various heuristic arguments (based essentially upon analyticity at the phase boundary and one-phase homogeneity in the critical region). Finally, structure and a mild extension of the proven analyticity of the free energy are used to show the $\ensuremath{\Delta}\ensuremath{\le}{\ensuremath{\Delta}}^{\ensuremath{'}}$, $\ensuremath{\gamma}\ensuremath{\le}{\ensuremath{\gamma}}^{\ensuremath{'}}$.