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Journal of Physics B Atomic Molecular and Optical Physics

Rydberg atoms in a magnetic quadrupole field

Igor Lesanovsky, Jörg Schmiedmayer, Peter Schmelcher

Published Jan 6, 2005• 5 citations
Publisher

Abstract

We study electronically excited atoms exposed to a magnetic quadrupole field. In order to describe the electron dynamics, a one-body approach is employed. Due to the inhomogeneity of the field, the spatial and spin degrees of freedom become coupled in a unique way. The underlying unitary and anti-unitary symmetries are discussed in detail leading to remarkable features such as a two-fold degeneracy of any energy level. We analyse the energy level structure throughout a wide range of field gradients. An investigation of the electronic spin properties is performed by studying the spatially dependent spin-polarization which exhibits a rich nodal structure. We compute wavelengths and strengths for electromagnetic transitions and provide the selection rules. A discussion of the so-called ellipsoidal states which exhibit unique properties such as large mean orbital angular momenta and spatial compactness is provided. The property of magnetic field-induced permanent electric dipole moments is analysed in detail. Wherever reasonable, the results obtained for the quadrupole field are compared to the homogeneous field case.

DOI
10.1088/0953-4075/38/2/012

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•Jan 1, 2006•0 citations
We study electronically excited atoms exposed to a magnetic quadrupole field. In order to describe the electron dynamics, a one-body approach is employed. Due to the inhomogeneity of the field, the spatial and spin degrees of freedom become coupled in a unique way. The underlying unitary and anti-unitary symmetries are discussed in detail leading to remarkable features such as a two-fold degeneracy of any energy level. We analyse the energy level structure throughout a wide range of field gradients. An investigation of the electronic spin properties is performed by studying the spatially dependent spin-polarization which exhibits a rich nodal structure. We compute wavelengths and strengths for electromagnetic transitions and provide the selection rules. A discussion of the so-called ellipsoidal states which exhibit unique properties such as large mean orbital angular momenta and spatial compactness is provided. The property of magnetic field-induced permanent electric dipole moments is analysed in detail. Wherever reasonable, the results obtained for the quadrupole field are compared to the homogeneous field case.
We investigate the electronic structure and properties of atoms exposed to a magnetic quadrupole field. The spin spatial as well as generalized time-reversal symmetries are established and shown to lead to a twofold degeneracy of the electronic states in the presence of the field. Low lying as well as highly excited Rydberg states are computed and analyzed for a broad regime of field gradients. The delicate interplay between the Coulomb and various magnetic interactions leads to complex patterns of the spatial spin polarization of individual excited states. Electromagnetic transitions in the quadrupole field are studied in detail thereby providing the selection rules and, in particular, the transition wavelengths and corresponding dipole strengths. The peculiar property that the quadrupole magnetic field induces permanent electric dipole moments of the atoms is derived and discussed.
We investigate the electronic structure and properties of Rydberg atoms exposed to a magnetic quadrupole field. It is shown that the spatial as well as generalized time-reversal symmetries lead to a two-fold degeneracy of the electronic states in the presence of the external field. A delicate interplay between the Coulomb and magnetic interactions in the inhomogeneous field leads to an unusual weak field splitting of the energy levels as well as complex spatial patterns of the corresponding spin polarization density of individual Rydberg states. Remarkably, the magnetic quadrupole field induces a permanent electric-dipole moment of the atom.
We investigate electronically excited atoms in a magnetic guide. It turns out that the Hamiltonian describing this system possesses a wealth of both unitary as well as antiunitary symmetries that constitute an uncommon extensive symmetry group. One consequence is the twofold degeneracy of any energy level. The spectral properties are investigated for a wide range of field gradients and the spatial distributions of the spin polarization are analyzed. Wavelengths, oscillator strengths, and selection rules are provided for the corresponding electromagnetic transitions. The effects due to an additional homogeneous bias field constituting a Ioffe-Pritchard trap are explored equally.
We investigate the quantum properties of an ultracold Rydberg atom exposed to a magnetic quadrupole field and a homogeneous electric field. The properly transformed Hamiltonian explicitly depends on the conserved total angular momentum and couples the centre of mass and electronic degrees of freedom. The corresponding Schrödinger equation is solved by an adiabatic separation focusing on a fixed n -manifold. The shape of the adiabatic electronic potential energy surfaces is analysed. With increasing electric field strength, avoided crossings among them become ubiquitous and the electric field-dominated regime spreads out within the centre-of-mass coordinate space. A transition from smooth surfaces for weak electric fields to surfaces involving a cusp-like behaviour in the strong field regime is observed. The latter involves a characteristic splitting behaviour of the surfaces due to the competition of the Stark and magnetic interactions. In contrast to previous investigations, our setup allows for the trapping of quantum states with a comparatively small electronic angular momentum.
We investigate the theoretical foundations of neutral two-body systems exposed to an inhomogeneous magnetic field. Various representations for the Hamiltonian describing the coupled centre-of-mass and internal motion are derived. For the specific case of a magnetic quadrupole field we establish the continuous and discrete symmetries and show that the energy levels of the interacting system are two-fold degenerate. We exploit the symmetries in two alternative ways and derive corresponding effective equations of motion. The first approach eliminates two of the six spatial degrees of freedom and leads to an (infinite) set of coupled channel equations for the spin and spatial degrees of freedom. The second approach introduces the projection of the total angular momentum onto the symmetry axis of the quadrupole field as a canonical momentum, thereby eliminating the corresponding cyclic angle.
Subject of this thesis is the investigation of the quantum dynamics of ultracold atoms in the presence of external inhomogeneous magnetic fields. We discuss the behavior of ground state atoms inside typical magnetic field configurations. Such atoms can be approximately treated as neutral point-like particles which carry a certain spin. In particular we analyze the resonance spectrum and the density of states of both fermionic and bosonic atoms. We point out the existence of so-called quasi-bound states whose wave functions can be approximately calculated analytically. Moreover, we focus on studying quantum mechanical states of ultracold but electronically highly excited atoms - so-called Rydberg atoms - inside magnetic traps. In a first step we explore their internal dynamics by employing a fixed-nucleus approximation. The latter assumes the atomic nucleus to be fixed in the magnetic field minimum. Within this framework we analyze spectral properties as well as properties of the electronic spin and calculate electromagnetic transitions. Finally we present an adiabatic approach which allows for a thorough description of the coupled center of mass and electronic dynamics. We highlight ways to magnetically trap highly excited atoms and present novel quantum states in which the center of mass and the electronic wave function are equal in size. This finding shows that Rydberg atoms even in inhomogeneous fields with moderate gradients cannot be considered point-like.