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Canadian Journal of Physics

Semiclassical position and momentum information entropy for sech2 and a family of rational potentials

Mark W. Coffey

Published Jul 1, 2007• 30 citations
Publisher

Abstract

The classical and semiclassical position and momentum information entropies for the reflectionless sech2 potential and a family of rational potentials are obtained explicitly. The sum of these entropies is of interest for the entropic uncertainty principle that is stronger than the Heisenberg uncertainty relation. The analytic results relate the classical period of the motion, total energy, position and momentum entropy, and dependence upon the principal quantum number n. The logarithmic energy dependence of the entropies is presented. The potentials considered include as special cases the attractive delta function and square well. PACS Nos.: 03.67–a, 03.65.Sq, 03.65.Ge, 03.65.–w

DOI
10.1139/p07-062

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The exact analytical values of the position and momentum information entropies are calculated for the single-slit and double-slit diffraction experiments. In both cases, the product of the exponentials of the entropies is strictly greater than the lower bound $\ensuremath{\pi}e\ensuremath{\Elzxh}$ given by the optimal entropic uncertainty relation for position and momentum, which implies that the single-slit and double-slit configurations are not minimum-uncertainty states. The results obtained show that the position-momentum entropic uncertainty relation provides a rigorous quantitative expression for the uncertainty principle in these experiments, unlike the Heisenberg inequality for standard deviations. However, it is also shown that, in the double-slit experiment, wave-particle duality cannot be derived from the entropic uncertainty relation.
Heisenberg’s uncertainty principle for position-momentum delta x delta p >= hbar/2 is considered as an important statement regarding quantum mechanics i.e. one cannot know both p and x exactly. Delta x and delta p stand out because in classical mechanics one has an eact p and x at each t. Mathematically, however, delta x and delta p are standard deviations which may also be calculated in classical statistical mechanics, for example with the Maxwell-Boltzmann distribution. In particular, if one considers the ground state of a simple harmonic oscillator, the quantum P(x) proportional to exp(-pp/a) and P(p) proportional to exp(-xxa) match the classical statistical probabilities P(x) and P(p) for a fixed value of T proportional to sqrt(k/m) where k is the spring constant. Thus for this special T, delta x delta p for a classical statistical mechanical gas is identical to delta x delta p for the ground state quantum oscillator. The probability is normalized the same way for both. The physics of the two situations, however, is completely different. Thus the Heisenberg uncertainty principle does not necessarily describe quantum mechanical behaviour alone. If one uses entropic uncertainty, i.e. Sp + Sx where S is Shannon’s entropy, once again one uses P(p)=a*(p)a(p) and P(x)=W*(x)W(x) where W(x)=wavefunction = Sum over p a(p)exp(ipx). In principle, one could also calculate such an entropy for a classical gas i.e. use P(x)P(p) in Shannon’s entropy. The result Sp+Sx does not imply one does not know about p if one knows x i.e. the usual quantum statement.
The entropic moments of the probability density of a quantum system in position and momentum spaces describe not only some fundamental and/or experimentally accessible quantities of the system but also the entropic uncertainty measures of Rényi type, which allow one to find the most relevant mathematical formalizations of the position-momentum Heisenberg’s uncertainty principle, the entropic uncertainty relations. It is known that the solution of difficult three-dimensional problems can be very well approximated by a series development in 1/D in similar systems with a non-standard dimensionality D; moreover, several physical quantities of numerous atomic and molecular systems have been numerically shown to have values in the large-D limit comparable to the corresponding ones provided by the three-dimensional numerical self-consistent field methods. The D-dimensional hydrogenic atom is the main prototype of the physics of multidimensional many-electron systems. In this work, we rigorously determine the leading term of the Rényi entropies of the D-dimensional hydrogenic atom at the limit of large D. As a byproduct, we show that our results saturate the known position-momentum Rényi-entropy-based uncertainty relations.
This paper deals with the standard and entropic uncertainty relations for the finite-potential well with different length and potential depth. We calculate the position and momentum dispersions and entropies that are dependent on the quantum states of the finite well and determine the corresponding standard and entropic uncertainty relations. Then we calculate the entropy of occurrence for the mass point inside and outside the well. We discuss the results and determine a class of probability distributions with a parameter for which the standard deviation becomes infinite, independent of the value of this parameter.
We calculate the analytical and numerical values of the position space Shannon entropy, momentum space Shannon entropy, and total Shannon entropy, [Formula: see text], [Formula: see text], and [Formula: see text], respectively, of free and trapped Rydberg hydrogen-like atoms. The influence of atomic number Z, the principal quantum number n, and energy E on the Shannon entropy of the Rydberg atoms are illustrated. The scaling properties of Shannon entropy with energy of states E and the principal quantum number n have been reported for the first time to the best of our knowledge. Our work explains how Shannon entropy indicates localization-delocalization of the wavefunction. The total Shannon entropy as a measure of the number of nodes in the trapped Rydberg atom's wavefunction is also discussed. We show why an uncertainty relation based on Shannon entropy is superior to Heisenberg uncertainty for Rydberg atoms.