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The Journal of Chemical Physics

Optimal control of quantum non-Markovian dissipation: Reduced Liouville-space theory

Rui‐Xue Xu, YiJing Yan, Yukiyoshi Ohtsuki, Yuichi Fujimura, HERSCHEL A. RABITZ

Published Mar 24, 2004• 63 citations
Publisher

Abstract

An optimal control theory for open quantum systems is constructed containing non-Markovian dissipation manipulated by an external control field. The control theory is developed based on a novel quantum dissipation formulation that treats both the initial canonical ensemble and the subsequent reduced control dynamics. An associated scheme of backward propagation is presented, allowing the efficient evaluation of general optimal control problems. As an illustration, the control theory is applied to the vibration of the hydrogen fluoride molecule embedded in a non-Markovian dissipative medium. The importance of control-dissipation correlation is evident in the results.

DOI
10.1063/1.1665486

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An optimal control theory for open quantum systems is constructed containing non-Markovian dissipation manipulated by an external control field. The control theory is developed based on a novel quantum dissipation formulation that treats both the initial canonical ensemble and the subsequent reduced control dynamics. An associated scheme of backward propagation is presented, allowing the efficient evaluation of general optimal control problems. As an illustration, the control theory is applied to the vibration of the hydrogen fluoride molecule embedded in a non-Markovian dissipative medium. The importance of control-dissipation correlation is evident in the results.
An efficient optimal-control theory based on the Krotov method is introduced for a non-Markovian open quantum system with a time-nonlocal master equation in which the control parameter and the bath correlation function are correlated. This optimal-control method is developed via a quantum dissipation formulation that transforms the time-nonlocal master equation to a set of coupled linear time-local equations of motion in an extended auxiliary Liouville space. As an illustration, the optimal-control method is applied to find the control sequences for high-fidelity ZZZ gates and identity gates of a qubit embedded in a non-Markovian bath. ZZZ gates and identity gates with errors less than ${10}^{\ensuremath{-}5}$ for a wide range of bath decoherence parameters can be achieved for the non-Markovian open qubit system with control over only the ${\ensuremath{\sigma}}_{z}$ term. The control-dissipation correlation and the memory effect of the bath are crucial in achieving the high-fidelity gates.
Based on a recently developed quantum dissipation formulation [R. X. Xu and Y. J. Yan, J. Chem. Phys. 116, 9196 (2002)], we present a reduced Liouville-space approach to evaluate the response and correlation functions of dissipative systems. The weak system-bath interaction is treated properly for its effects on the initial state, the evolution, and the correlation between coherent driving and non-Markovian dissipation. Numerical demonstration shows this correlated effect cannot be neglected even in the calculation of linear response quantities that do not explicitly depend on external fields. Highlighted in this paper is also the proper choice of theory among various formulations in the weak system-bath interaction regime.
The problem of optimal control of non-Markovian open quantum system via weak measurement is presented. Based on the non-Markovian master equation, we evaluate exactly the non-Markovian effect on the dynamics of the system of interest interacting with a dissipative reservoir. We find that the non-Markovian reservoir has dual effects on the system: dissipation and backaction. The dissipation exhausts the coherence of the quantum system, whereas the backaction revives it. Moreover, we design the control Hamiltonian with the control laws attained by the stochastic optimal control and the corresponding optimal principle. At last, we considered the exact decoherence dynamics of a qubit in a dissipative reservoir composed of harmonic oscillators, and demonstrated the effectiveness of our optimal control strategy. Simulation results showed that the coherence will completely lost in the absence of control neither in non-Markovian nor Markovian system. However, the optimal feedback control steers it to a stationary stochastic process which fluctuates around the target. In this case the decoherence can be controlled effectively, which indicates that the engineered artificial reservoirs with optimal feedback control may be designed to protect the quantum coherence in quantum information and quantum computation.
This paper considers the optimal control of quantum systems. The controlled quantum systems are described by the probability-density-matrix-based Liouville–von Neumann equation. Using projection operators, the states of the quantum system are decomposed into two sub-spaces, namely the 'main state' space and the 'remaining state' space. Since the control energy is limited, a solution for optimizing the external control force is proposed in which the main state is brought to the desired main state at a certain target time, while the population of the remaining state is simultaneously suppressed in order to diminish its effects on the final population of the main state. The optimization problem is formulated by maximizing a general cost functional of states and control force. An efficient algorithm is developed to solve the optimization problem. Finally, using the hydrogen fluoride (HF) molecular population transfer problem as an illustrative example, the effectiveness of the proposed scheme for a quantum system initially in a mixed state or in a pure state is investigated through numerical simulations.
A Markovian master equation describing the evolution of open quantum systems in the presence of a time-dependent external field is derived within the Bloch-Redfield formalism. It leads to a system-bath interaction which depends on the control field. Optimal control theory is used to select control fields which allow accelerated or decelerated system relaxation, or suppression of relaxation (dissipation) altogether, depending on the dynamics we impose on the quantum system. The control-dissipation correlation and the nonperturbative treatment of the control field are essential for reaching this goal. The optimal control problem is formulated within Pontryagin's minimum principle and the resulting optimal differential system is solved numerically. As an application, we study the dynamics of a spin-boson model in the strong coupling regime under the influence of an external control field. We show how trapping the system in unstable quantum states and transfer of population can be achieved by optimized control of the dissipative quantum system. We also used optimal control theory to find the driving field that generates the quantum ZZZ gate. In several cases studied, we find that the selected optimal field which reduces the purity loss significantly is a multicomponent low-frequency field including higher harmonics, all of which lie below the phonon cutoff frequency. Finally, in the undriven case we present an analytic result for the Lamb shift at zero temperature.
We study the optimal control problem in a non-Markovian open quantum system. The quantum system of interest is coupled to its local environment, which is dissipative in nature and tends to decay the quantum system. Based on the non-Markovian master equation, we study the non-Markovian effects on the system dynamics. The non-Markovian environment has dual effects on the quantum system: the dissipation and the backaction. The dissipation effect makes the system lose of quantum features, whereas the backaction revives it. We further design quantum control laws to control the system. The optimal control principle is studied to steer to quantum state to a target state. Finally, as an example, we used the optimal control method to control the quantum decoherence.