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Physical Review A

Quadratic Zeeman effect in positronium

Gerald Feinberg, A. Rich, Joseph Sucher

Published Apr 1, 1990• 15 citations
Publisher

Abstract

The orbital ${\mathrm{\ensuremath{\mu}}}_{\mathit{L}}$\ensuremath{\cdot}B and diamagnetic ${\mathit{A}}^{2}$ interactions of electrons and positrons with an external magnetic field lead to a small quadratic Zeeman shift in the L=0, ${\mathit{m}}_{\mathit{S}}$=\ifmmode\pm\else\textpm\fi{}1 states of positronium, which, unlike the ${\mathit{m}}_{\mathit{S}}$=0 states, are not affected by the usual, spin-induced Zeeman shifts. For the n=1 states, this shift would be about 2 kHz in a field of 1000 G. These additional shifts are the same in all spin states for L=0 but do depend on n.

DOI
10.1103/physreva.41.3478

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The orbital \ensuremathμL{\mathrm{\ensuremath{\mu}}}_{\mathit{L}}\ensuremathμL​\ensuremath{\cdot}B and diamagnetic A2{\mathit{A}}^{2}A2 interactions of electrons and positrons with an external magnetic field lead to a small quadratic Zeeman shift in the L=0, mS{\mathit{m}}_{\mathit{S}}mS​=\ifmmode\pm\else\textpm\fi{}1 states of positronium, which, unlike the mS{\mathit{m}}_{\mathit{S}}mS​=0 states, are not affected by the usual, spin-induced Zeeman shifts. For the n=1 states, this shift would be about 2 kHz in a field of 1000 G. These additional shifts are the same in all spin states for L=0 but do depend on n.
The linear Zeeman effect in the molecular positronium Ps2 (dipositronium) is predicted for some of S=1S=1S=1, M=±1M=\pm1M=±1 states. This result is opposite to the case of the positronium atom; the latter has only quadratic Zeeman effect.
The excited-state nuclear Zeeman effect and quadratic-electronic Zeeman effect were studied in Pr(3+):LaF(3) using laser-induced hole burning. Hole burning in an external magnetic field gave values for the excited-state enhanced nuclear g tensor of g(x)beta/h = 2.2, g(y)beta/h = 1.9, and g(z)beta/h = 3.6 kHz/G. By applying the field after hole burning, quadratic-electronic Zeeman coefficients as small as 0.1 Hz/G(2) were measured. The hyperfine coupling constant in the excited (1)D(2) level was found to be A(J) = 600 MHz.
Analytical expressions for the dependence of the intensity of Zeeman components of doublet lines on the magnetic field are obtained. Sharp changes of these function on passing from the anomalous Zeeman effect to the Paschen-Back effect lead to the disappearance of marginal lines and the equalization of intensities of remaining lines. In the region of the complete Paschen-Back effect, a strong influence on these dependences is produced by the dynamic atom-field interaction, which weakens the paramagnetic effect in the states with a positive magnetic quantum number m and enhances the effect in the states with a negative m . Simple analytical expressions are obtained that take into account the effect of the diamagnetic interaction on line intensities. The role of the diamagnetic interaction increases in Rydberg atomic states with a large spin-orbit splitting. For the states with m > 0, it can lead to the “diamagnetic reversal” of the Paschen-Back effect, i.e., the recovery of the anomalous Zeeman effect.
We report the observation and manipulation of heteronuclear spin dynamics in a spin-1 mixture of ultracold 87Rb^{87}\mathrm{Rb}87Rb and 23Na^{23}\mathrm{Na}23Na atoms. The dynamics is driven by the interspecies spin-dependent interaction and shows a pronounced dependence on magnetic fields with influences from both linear and quadratic Zeeman shifts. Similar to the well-studied homonuclear cases, the interspecies spin dynamics can be controlled by tuning the quadratic Zeeman shift with far-detuned microwave fields. In addition, we successfully realize spin dynamics' control with vector light shifts which act as a species-selective effective magnetic field on 87Rb^{87}\mathrm{Rb}87Rb atoms. Both methods show negligible loss of atoms thus will be powerful techniques for investigating spin dynamics with fast temporal and high spatial resolutions.