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Journal of Physics A Mathematical and General

Exact solution of a ten-vertex model in two dimensions

Roberto Nicolau Onody, M. Karowski

Published Jan 11, 1983• 3 citations
Publisher

Abstract

A ten-vertex model, which is a multi-state generalisation of the six-vertex model, is formulated on a square lattice and solved exactly in the thermodynamic limit using the inverse scattering method. It is found that this system undergoes a first-order phase transition into a 'frozen' ferroelectric state.
DOI
10.1088/0305-4470/16/1/007

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An exact solution of a 2*n generalisation (two states for horizontal arrows and n states for vertical arrows with total arrow number conservation) of the six-vertex model is given using the commuting transfer matrix method. In the symmetric case, the free energy is a sum of n-1 terms each of which is the free energy of a six-vertex model such that the phase transition into the frozen ferroelectric state of the 2*n model is identical to that in the zero-field six-vertex model. For the six-vertex model the commuting transfer matrix solution is extended to the case of arbitrary vertex weights and a derivation of the Baxter parametrisation is provided.
The thermodynamics of the six-vertex models in direct and staggered electric fields is investigated using the cluster field method. The scheme of the successive approximations of the method is described and the result of the first and second approximations are presented. The cluster field method is shown to combine simplicity with high accuracy, in particular, in the description of ferroelectric phase transitions where the basic results agree with the exact ones in all the exactly soluble cases. The properties of the models in the staggered field s not=0 are investigated in detail. The expressions obtained for the ferroelectric phase transition point T F (s) and for the polarisability near T F (s) are apparently exact for the six-vertex models.
Within the ice-type models, the solution of the five-vertex model is obtained with the use of the Bethe ansatz. Since the allowed number of vertex types is odd, the arrow-reversal symmetry of the system is broken by construction. Due to this, the exact solution obtained and the phase diagram are very different from those of the symmetric six-vertex model. A connection to the asymmetric six-vertex model (of which the five-vertex model is an extreme case) is made. The different regions of the phase diagram are described and the transitions between them are analyzed. Several aspects of the phase diagram are unusual, i.e., the ordered phases (both ferroelectric and antiferroelectric) are frozen-in phases and the disordered phase is replaced by a ferrielectric phase. In the free-fermion case, the known results of the modified KDP model are recovered.
This thesis deals with two two-dimensional lattice models in statistical mechanics. The first of these is the zero-field 20-vertex model on a triangular lattice. This model is the analogue to the ice-type, zero-field six-vertex model on a square lattice. We solve this problem exactly for a restricted set of vertex weights. The other model is the q-component Potts model on a square lattice. This model is equivalent to a staggered ice-type model on a square lattice. Using a variational method we estimate the critical exponent ß for several values of q. In part I we outline the fundamental statistical mechanical ideas needed, including the definition of the partition function and its relation to the thermodynamic quantities. Mention is also made of the existence and uniqueness of the thermodynamic limit for these models. The 20-vertex model is discussed in part II. The transfer matrix approach is adopted and a Bethe ansatz is used for the eigenvector. Unlike the square lattice ice-type model, the triangular lattice 20-vertex model is only soluble by this method for a restricted set of vertex weights. In particular, the ten parameters determining the vertex weights must be expressed in terms of four independent parameters. This results in only one type of non-trivial temperature independent solution. This solution exhibits critical behaviour similar to the square lattice KDP model. The general solution has three states: disordered, antiferroelectric and ferroelectric. Which state the model is in is determined by one of the above four parameters. The transition from the disordered to the antiferroelectric state is of infinite-order (i.e the free energy has an essential singularity), and from the disordered to the ferroelectric state is of finite-order. We also compare our results to the free-fermion solution of the same model and note where the two methods overlap. In part III the Potts model is considered. The model is defined and shown to be equivalent to a staggered ice-type model. A variational principle for the eigenvalues of the transfer matrix of the staggered ice model is determined. Using the zero-temperature solution as a ^uide a simple form for a sequence of approximations to the eigenvector, below T , is developed. By using the variational principle we arrive at a set of matrix equations determining the eigenvector at a given level of approximation. By noting some of the symmetries of the transfer matrix we are able to separate some of the dependences of the matrix elements and consequently simplify the original set of equations. We are also able to express the percolation probability ( the analogue of the spontaneous magnetization for general values of q ) of the Potts model as a simple function of these matrix elements. At each level of approximation there is a set of algebraic equations to solve. We have used an electronic computer to solve these equations for the first five levels of approximation, and for several values of q between zero and four. With our results we estimate the critical exponent 3 for the Potts model. These estimates agree reasonably well with previous work and indicate 3=0.145 ±.017 for q=l.
The ice model Introduction The six-vertex model , which is the object of this chapter, is a special case of the eight-vertex model on a two-dimensional square lattice introduced by Fan and Wu (1970) in order to summarize a class of exactly solvable models in classical statistical mechanics. The thermodynamics of the six-vertex model is by now known in its full generality (Yang and Yang, 1966a–d; Lieb, 1967a) which is not the case for the eight-vertex model, but only the self-conjugate one (Baxter, 1971a). The general model can be considered as a two-dimensional idealization of a crystalline system in which pairs of adjacent atoms or radicals on the network are linked by ‘hydrogen bonds’. Of ionic type, this link between two neighbouring electronegative atoms is realized by a proton H + which is located closer to one of the atoms than to the other. On each link of the network there thus exist two equilibrium positions for H + (Pauling, 1960). If the coordination number at each site equals 4, as is the case for the oxygen atom in hexagonal ice, we indeed have eight possible proton configurations on a given site, which give rise to the eight vertices. In contrast, for the physical systems for which this model could be viewed as a valid idealization – ice H 2 O, the ferroelectric PO 4 H 2 K, the antiferroelectric PO 4 H 2 NH 4 – there exist at most two H + next to each site.