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Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Phase diagram of the five-vertex model

M. Gulácsi, Henk van Beijeren, A.C. Levi

Published Apr 1, 1993• 24 citations
Publisher

Abstract

Within the ice-type models, the solution of the five-vertex model is obtained with the use of the Bethe ansatz. Since the allowed number of vertex types is odd, the arrow-reversal symmetry of the system is broken by construction. Due to this, the exact solution obtained and the phase diagram are very different from those of the symmetric six-vertex model. A connection to the asymmetric six-vertex model (of which the five-vertex model is an extreme case) is made. The different regions of the phase diagram are described and the transitions between them are analyzed. Several aspects of the phase diagram are unusual, i.e., the ordered phases (both ferroelectric and antiferroelectric) are frozen-in phases and the disordered phase is replaced by a ferrielectric phase. In the free-fermion case, the known results of the modified KDP model are recovered.

DOI
10.1103/physreve.47.2473

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Within the ice-type models, the solution of the five-vertex model is obtained with the use of the Bethe ansatz. Since the allowed number of vertex types is odd, the arrow-reversal symmetry of the system is broken by construction. Due to this, the exact solution obtained and the phase diagram are very different from those of the symmetric six-vertex model. A connection to the asymmetric six-vertex model (of which the five-vertex model is an extreme case) is made. The different regions of the phase diagram are described and the transitions between them are analyzed. Several aspects of the phase diagram are unusual, i.e., the ordered phases (both ferroelectric and antiferroelectric) are frozen-in phases and the disordered phase is replaced by a ferrielectric phase. In the free-fermion case, the known results of the modified KDP model are recovered.
An exact solution of a 2*n generalisation (two states for horizontal arrows and n states for vertical arrows with total arrow number conservation) of the six-vertex model is given using the commuting transfer matrix method. In the symmetric case, the free energy is a sum of n-1 terms each of which is the free energy of a six-vertex model such that the phase transition into the frozen ferroelectric state of the 2*n model is identical to that in the zero-field six-vertex model. For the six-vertex model the commuting transfer matrix solution is extended to the case of arbitrary vertex weights and a derivation of the Baxter parametrisation is provided.
The ice model Introduction The six-vertex model , which is the object of this chapter, is a special case of the eight-vertex model on a two-dimensional square lattice introduced by Fan and Wu (1970) in order to summarize a class of exactly solvable models in classical statistical mechanics. The thermodynamics of the six-vertex model is by now known in its full generality (Yang and Yang, 1966a–d; Lieb, 1967a) which is not the case for the eight-vertex model, but only the self-conjugate one (Baxter, 1971a). The general model can be considered as a two-dimensional idealization of a crystalline system in which pairs of adjacent atoms or radicals on the network are linked by ‘hydrogen bonds’. Of ionic type, this link between two neighbouring electronegative atoms is realized by a proton H + which is located closer to one of the atoms than to the other. On each link of the network there thus exist two equilibrium positions for H + (Pauling, 1960). If the coordination number at each site equals 4, as is the case for the oxygen atom in hexagonal ice, we indeed have eight possible proton configurations on a given site, which give rise to the eight vertices. In contrast, for the physical systems for which this model could be viewed as a valid idealization – ice H 2 O, the ferroelectric PO 4 H 2 K, the antiferroelectric PO 4 H 2 NH 4 – there exist at most two H + next to each site.
Some features of integrable lattice models are reviewed for the case of the six-vertex model.By the Bethe ansatz method we derive the free energy of the six-vertex model.Then, from the expression of the free energy we show analytically the critical singularity near the phase transition in the anti-ferroelectric regime, where the essential singularity similar to the Kosterlitz-Thouless transition appears.We discuss the connection of the six-vertex model to the conformal field theory with c = 1.We also introduce various exactly solvable models defined on two-dimensional lattices such as the chiral Potts model and the IRF models.We show that the six-vertex model has rich mathematical structures such as the quantum groups and the braid group.The graphical approach is emphasized in this review.We explain the meaning of the Yang-Baxter equation by its diagram.Furthermore, we can understand the defining relation of the algebraic Bethe ansatz by the graphical representation.We can thus easily translate formulas of the algebraic Bethe ansatz into those of the statistical models.As an illustration, we show explicitly how we can derive Baxter's expressions from those of the algebraic Bethe ansatz.
Some features of integrable lattice models are reviewed for the case of the six-vertex model. By the Bethe ansatz method we derive the free energy of the six-vertex model. Then, from the expression of the free energy we show analytically the critical singularity near the phase transition in the anti-ferroelectric regime, where the essential singularity similar to the Kosterlitz-Thouless transition appears. We discuss the connection of the six-vertex model to the conformal field theory with c=1. We also introduce various exactly solvable models defined on two-dimensional lattices such as the chiral Potts model and the IRF models. We show that the six-vertex model has rich mathematical structures such as the quantum groups and the braid group. The graphical approach is emphasized in this review. We explain the meaning of the Yang-Baxter equation by its diagram. Furthermore, we can understand the defining relation of the algebraic Bethe ansatz by the graphical representation. We can thus easily translate formulas of the algebraic Bethe ansatz into those of the statistical models. As an illustration, we show explicitly how we can derive Baxter's expressions from those of the algebraic Bethe ansatz.