For autonomous quantum systems with modular structure we demonstrate that the Jarzynski relation can be reinterpreted to apply even locally: For this purpose certain contexts have to be introduced by selecting the system of interest versus its environment. The respective energy exchange is then divided into heat and work based on a generalized definition of these notions. In this way we are able to identify functional parts of the environment as either heat or work sources, respectively. We investigate different combinations of these functional parts with respect to contextual Jarzynski relations. Our analytical results are confirmed by numerical investigations on small multipartite systems.
For autonomous quantum systems with modular structure we demonstrate that the Jarzynski relation can be reinterpreted to apply even locally: For this purpose certain contexts have to be introduced by selecting the system of interest versus its environment. The respective energy exchange is then divided into heat and work based on a generalized definition of these notions. In this way we are able to identify functional parts of the environment as either heat or work sources, respectively. We investigate different combinations of these functional parts with respect to contextual Jarzynski relations. Our analytical results are confirmed by numerical investigations on small multipartite systems.
We study the quantum Jarzynski relation for driven quantum models embedded in various environments. We do so by generalizing a proof presented by Mukamel [Phys. Rev. Lett. 90, 170604 (2003)] for closed quantum systems. In this way, we are able to prove that the Jarzynski relation also holds for a bipartite system with microcanonical coupling. Furthermore, we show that, under the assumption that the interaction energy remains constant during the whole process, the relation is valid even for canonical coupling. The same follows for open quantum systems at high initial temperatures up to third order of the inverse temperature. Our analytical study is complemented by a numerical investigation of a special model system.
Abstract We compare definitions of the internal energy of an open quantum system and strategies to split the internal energy into work and heat contributions as given by four different approaches from the autonomous system framework. Our discussion focuses on methods that allow for arbitrary environments (not just heat baths) and driving by a quantum mechanical system. As a simple application we consider an atom as the system of interest and an oscillator field mode as the environment. Three different types of coupling are analyzed. We discuss ambiguities in the definitions and highlight differences that appear if one aims at constructing environments that act as pure heat or work reservoirs. Further, we identify different sources of work (e.g. coherence, correlations, or frequency offset), depending on the underlying framework. Finally, we give arguments to favour the approach based on minimal dissipation.
Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was introduced aiming at extending the thermodynamic formalism to genuine quantum settings, also referred to as autonomous quantum systems: free from external controls, only quantum systems interacting with each other. In this paper, we apply such a thermodynamic framework to common experimental situations of interacting quantum systems. In situations where traditional frameworks detect only heat exchanges, the recent autonomous thermodynamic framework points at work exchanges based on two mechanisms: population inversion and coherence generation / consumption. Such mechanisms are well known in the literature for being related to work expenditure and extraction, in particular in relation with ergotropy, which emphasizes the relevance of the autonomous framework and the limitations of traditional ones. Furthermore, the autonomous framework also identifies a genuine non-unitary mechanism of work exchange related to athermality. %, also pointed out as a resource for work extraction. Finally, in the semi-classical limit, the autonomous framework identifies all energy exchanges as pure work, but distinguishes between local work and interaction energy.
Our results show that the autonomous framework provides a refined analysis of work exchange mechanisms in the quantum realm and serves as a consistent approach to analyze thermodynamic processes in realistic quantum devices.
In this thesis focus is laid on fluctuation theorems in autonomous modular quantum systems. Moreover, non-equilibrium cyclic processes using a quantum system as working agent are investigated. The first part is concerned with possible pitfalls in adopting idealized model systems from quasistatic thermodynamics for processes driving the system far away from equilibrium. Investigations of a one-dimensional quantum analogue of a gas confined in a cylinder show that the idealization of the cylinder as being absolutely impenetrable leads to questionable results when the gas is in a highly non-equilibrium state during an enforced process. Only when the quasistatic case is recovered, this idealization, well proven in equilibrium thermodynamics, regains its validity. For the investigations concerning fluctuation theorems this thesis focuses on the Jarzynski relation which relates the work performed during a non-equilibrium process with the free energy difference of two equilibrium states. In order to formulate the Jarzynski relation for a specific local part of a closed modular quantum system, the energy transfer between different subparts has to be divided into work and heat, respectively. This separation is performed using LEMBAS, a method to distinguish between heat and work for quantum systems in arbitrary states. In the second part functional environments for a system of interest are identified by using LEMBAS. These functional environments are classified as work or heat sources, respectively. Using these work and heat sources in the third part, different estimation methods for the local effective free energy for the system of interest are studied. This way it is shown that it is possible to generalize the Jarzynski relation to local effective dynamics, giving good estimates for the free energy difference if the correct estimation method is used. In this context, LEMBAS provides a feasible separation of heat and work. The last part of this thesis is concerned with a quantum generalization of the classical Otto cycle. The working agent is to be taken as a quantum system whereas the heat baths are assumed to be classical. For this setting the efficiency of cyclic processes is shown to be limited by the corresponding classical efficiency.
One of the most important problems in quantum thermodynamics is how to distinguish work and heat in autonomous quantum systems. In this paper, work and heat are defined through the following criterion, i.e., work is the energy that cannot change the entropy of the energy resource, and satisfies the Jarzynski equality, while heat does not. Two kinds of definitions satisfying the two corresponding requirements are proposed and demonstrated, and the consistency condition of the two kinds is given. Through the first definition, the problem of entropy production is investigated. A model study is also presented to verify the proposal.
We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main ingredient is the identification of work depending on the quantum history of the system and the proper definition of various quantum ensembles over which the averages should be made. We also discuss a number of different regimes that have been considered by other authors and which are unified in the present set-up. In all cases, quantum or classical, it is a general relation between heat and time-reversal that makes the Jarzynski relation so universally valid.