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The Journal of Chemical Physics

Dissipation-induced transition of a simple harmonic oscillator

Zong-Qian Shao, Yuqi Li, Xiao‐Yin Pan

Published Dec 9, 2014• 5 citations
Publisher

Abstract

We investigate the dissipation-induced transition probabilities between any two eigenstates of a simple harmonic oscillator. Using the method developed by Yu and Sun [Phys. Rev. A 49, 592 (1994)], the general analytical expressions for the transition probabilities are obtained. The special cases: transition probabilities from the ground state to the first few excited states are then discussed in detail. Different from the previous studies in the literature where only the effect of damping was considered, it is found that the Brownian motion makes the transitions between states of different parity possible. The limitations of the applicability of our results are also discussed.

DOI
10.1063/1.4903178

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We investigate the dissipation-induced transition probabilities between any two eigenstates of a simple harmonic oscillator. Using the method developed by Yu and Sun [Phys. Rev. A 49, 592 (1994)], the general analytical expressions for the transition probabilities are obtained. The special cases: transition probabilities from the ground state to the first few excited states are then discussed in detail. Different from the previous studies in the literature where only the effect of damping was considered, it is found that the Brownian motion makes the transitions between states of different parity possible. The limitations of the applicability of our results are also discussed.
We investigate the effects of the initial-slip term by studying the dissipation-induced transition probabilities between any two eigenstates of a simple harmonic oscillator. The general analytical expressions for the transition probabilities are obtained, then the special cases of transition probabilities ignoring the Brownian motion from the ground state to the first few excited states are discussed. It is found that the initial-slip term not only makes the forbidden transitions between states of different parity possible but also lifts the initial value of the transition probabilities.
In a recent paper Croxson [Phys. Rev. A 49,49,49, 588 (1994)] reported dissipation-induced transition probabilities from the ground state to higher states for a quantum harmonic oscillator. A partial approximate result was given for the oscillator to remain in its ground state, while for higher transitions the situation became complicated. Our approach provides an exact simple form closed expression for any order of transition. In addition, we supply the evolution of the work done by the system on its environment.
Applying a technique developed recently [L. H. Yu and C. P. Sun, Phys. Rev. A 49, 592 (1994); L. H. Yu, Phys. Lett. 202, 167 (1995)] for a harmonic oscillator coupled to a bath of harmonic oscillators, we present an exact solution for the tunneling problem in an Ohmic dissipative system with inverted harmonic potential. The result shows that while the dissipation tends to suppress the tunneling, the Brownian motion tends to enhance the tunneling. Whether the tunneling rate increases or not would then depend on the initial conditions. We give a specific formula to calculate the tunneling probability determined by various parameters and the initial conditions. \textcopyright{} 1996 The American Physical Society.
The need for a quantum-mechanical formalism for systems with dissipation which is applicable to the radiation field of a cavity is discussed. Two methods that have been used in this connection are described. The first, which starts with the classical Newtonian equation of motion for a damped oscillator and applies the conventional formal quantization techniques, leads to an exact solution; but subsequent discussion shows that this method is invalid, the results being unacceptable from a quantum-mechanical viewpoint. The second method, which considers the interaction of two systems, the lossless oscillator and the loss mechanism, is adopted in the present article. No special model is used for the loss mechanism, but this mechanism is assumed to have a large number of densely-spaced energy states.The approximations with respect to the loss mechanism that underlie the concept of dissipation are discussed. These approximations are then applied to the analysis, and a differential equation for a coordinate operator of the harmonic oscillator is obtained which has the formal appearance of the Newtonian equation of motion for a driven damped harmonic oscillator, the driving term being an operator referring to the loss mechanism. The presence of the driving term is responsible for the difference between the present theory and that of the first method mentioned above. A solution of the differential equation for the coordinate operator is given explicitly. An examination of the physical significance of the solution shows that the driving term is responsible not only for the thermal fluctuations which are due to the loss mechanism, but also for the proper commutation relationship of the conjugate coordinates of the oscillator and for its zero-point fluctuations.A generalization of the solution to provide for a classical driving force and coupled atomic systems is given. The results are then restated in a form that refers to the loss mechanism only through the two parameters by which it is usually described---the dissipation constant and the temperature.
The development of a quantum-mechanical formalism for systems with dissipation that was presented in an earlier article, and intended mainly for application to the electromagnetic field in a cavity, is extended. The problem of the harmonic oscillator with dissipation is shown to be the same as that of a harmonic oscillator coupled to a thermal reservoir, and the need of the formalism to contain the appropriate statistical mechanics is discussed. The derivation of relationships which permit the calculation of all moments of the oscillator coordinate and momentum provides the necessary extension of the theory. The formal resemblance of the completed theory to that of classical Brownian motion, some differences due to quantum mechanics, and the fact that certain fundamental relationships which are assumed in the latter are derived in the present analysis, are pointed out. The application of the theory is illustrated by the consideration of three problems: the proof of Ott's formula, and the derivation of both the probability density and energy distribution of the oscillator in equilibrium with a thermal reservoir.