In analyzing atomic systems undergoing interactions with external fields that are nearly resonant with two, and only two of the atom's energy levels, one commonly employs a two-level or resonance approximation in which all states of the atom are neglected except for the two in resonance with the field. In this paper, we examine the assumptions necessary to make the transition from a differential equation for the exact polarization of an atomic system to the corresponding equation in the two-level approximation. Only when one includes contributions from states outside the two-level subspace does he find the exact equation reduces to the two-level equation within correctional factors of an intuitive nature.
In analyzing atomic systems undergoing interactions with external fields that are nearly resonant with two, and only two of the atom's energy levels, one commonly employs a two-level or resonance approximation in which all states of the atom are neglected except for the two in resonance with the field. In this paper, we examine the assumptions necessary to make the transition from a differential equation for the exact polarization of an atomic system to the corresponding equation in the two-level approximation. Only when one includes contributions from states outside the two-level subspace does he find the exact equation reduces to the two-level equation within correctional factors of an intuitive nature.
The interaction of simple, two- and three-level atomic systems with monochromatic and nonmonochromatic laser radiation near resonance transitions is discussed based on the Schroedinger equation with radiation decay and no collisional relaxation, outside the framework of the usual perturbation theory. The mathematical schemes employed include the resonance approximation, exact methods, the quasi-energy method, the adiabatic approximation, etc. A large number of physical phenomena, such as oscillating and inverted populations, self-induced resonances, processes of first order in the weak field, Raman scattering, coherent population transfer, etc. are considered. The review is intended for a broad readership.
One of the simplest nontrivial problems involving the atom–field interaction is the coupling of a two-level atom with a single mode of the electromagnetic field. A two-level atom description is valid if the two atomic levels involved are resonant or nearly resonant with the driving field, while all other levels are highly detuned. Under certain realistic approximations, it is possible to reduce this problem to a form which can be solved exactly; allowing essential features of the atom-field interaction to be extracted. In this chapter we present a semiclassical theory of the interaction of a single two-level atom with a single mode of the field in which the atom is treated as a quantum two-level system and the field is treated classically. A fully quantum mechanical theory will be presented in Chapter 6. A two-level atom is formally analogous to a spin-1/2 system with two possible states. In the dipole approximation, when the field wavelength is larger than the atomic size, the atom–field interaction problem is mathematically equivalent to a spin-1/2 particle interacting with a time-dependent magnetic field. Just as the spin-1/2 system undergoes the so-called Rabi oscillations between the spin-up and spin-down states under the action of an oscillating magnetic field, the two-level atom also undergoes optical Rabi oscillations under the action of the driving electromagnetic field. These oscillations are damped if the atomic levels decay. An understanding of this simple model of the atom–field interaction enables us to consider more complicated problems involving an ensemble of atoms interacting with the field.
We propose a general perturbative approach to quantum-optical models without the rotating-wave approximation. We show that a generic Hamiltonian describing interaction between two subsystems can be represented as a series of operators corresponding to different transitions between bare energy levels of the whole system. Under certain relations between frequencies of interacting subsystems one of these transitions becomes resonant. The rotating-wave approximation leads to separation of the resonant transition and to appearance of the integral of motion, which makes the problem exactly solvable in this approximation. (Different resonance conditions lead to different integrals of motion.) All of the other terms in these expansion can be considered as a perturbation. They result in dynamic Stark shifts and small corrections to the integrals of motion. All possible resonances are classified, and approximate integrals of motion are found for each resonance. Examples of field-field, field-atom, and atom-atom interactions are considered.
In describing the nonlinear interaction of radiation with matter it is well known that the perturbation expansion technique is used to calculate the atomic wave functions and the transitions between the states of a system. However the technique, though involving all states of the system, is valid only in the limit of weak interaction fields and non-resonant interactions. For strong fields and resonant interactions, density matrix or dressed atom formulisms are commonly used though these exact treatments are restricted to simple two level schemes or approximations of these; their application to general resonant-near resonant multilevel interactions being prohibitively complex.
We derive the stochastic equations and consider the non-Markovian dynamics of a system of multiple two-level atoms in a common quantum field. We make only the dipole approximation for the atoms and assume weak atom–field interactions. From these assumptions, we use a combination of non-secular open- and closed-system perturbation theory, and we abstain from any additional approximation schemes. These more accurate solutions are necessary to explore several regimes: in particular, near-resonance dynamics and low-temperature behavior. In detuned atomic systems, small variations in the system energy levels engender timescales which, in general, cannot be safely ignored, as would be the case in the rotating-wave approximation (RWA). More problematic are the second-order solutions, which, as has been recently pointed out (Fleming and Cummings 2011 Phys. Rev. E 83 031117), cannot be accurately calculated using any second-order perturbative master equation, such as RWA, Born–Markov, Redfield, etc. The latter problem, which applies to all perturbative open-system master equations, has a profound effect upon calculation of entanglement at low temperatures. We find that even at zero temperature all initial states will undergo finite-time disentanglement (sometimes termed ‘sudden death’), in contrast to the previous work. We also use our solution, without invoking the RWA, to characterize the necessary conditions for Dicke subradiance at finite temperature. We find that the sub-radiant states fall into two categories at finite temperature: one that is temperature independent and one that acquires temperature dependence. With the RWA, there is no temperature dependence in any case.
Light is both radiated and absorbed by atoms, and the interaction between the quantized electromagnetic field and an atom represents one of the most fundamental problems in quantum optics. However, real atoms are complicated systems, and even the simplest real atom, the hydrogen atom, has a non-trivial energy level structure. It is therefore often necessary or desirable to approximate the behavior of a real atom by that of a much simpler quantum system. For many purposes only two atomic energy levels play a significant role in the interaction with the electromagnetic field, so that it has become customary in many theoretical treatments to represent the atom by a quantum system with only two energy eigenstates. This is the most basic of all quantum systems, and it generally simplifies the treatment substantially. In a real atom the selection rules limit the allowed transitions between states, so that, in some cases, a certain state may couple to only one other. Moreover, optical pumping techniques have been developed that allow such preferred states to be prepared in the laboratory, and they have been successfully used in experiments (Abate, 1974). The two-level atom approximation is therefore close to the truth and not merely a mathematical convenience in some experimental situations. In the following we begin by developing the algebra for such a two-level atom. Dynamical variables for a two-level atom We consider an atomic quantum system with the two energy levels shown in Fig. 15.1.