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Physical Review Letters

Anomalous low-temperature properties of the degenerate one-dimensional Hubbard model

Kong-Ju-Bock Lee, P. Schlottmann

Published Nov 13, 1989• 26 citations
Publisher

Abstract

Unusual properties of the Hubbard chain of arbitrary degeneracy N and excluded-site occupations of more than two electrons are presented: (i) In zero field and in the limit of large N the ground state resembles an interacting Bose gas. The 1/N contributions vanish identically, so that corrections to leading order are 1/${\mathrm{N}}^{2}$. (ii) The susceptibility at T=0 shows logarithmic singularities as H\ensuremath{\rightarrow}0. (iii) The Hubbard model and the Heisenberg chain have the same low-energy spin excitations for all U. (iv) The specific-heat coefficient \ensuremath{\gamma} is singular. These properties hold for arbitrary band filling and (ii)--(iv) hold for all N\ensuremath{\ge}2.

DOI
10.1103/physrevlett.63.2299

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Unusual properties of the Hubbard chain of arbitrary degeneracy N and excluded-site occupations of more than two electrons are presented: (i) In zero field and in the limit of large N the ground state resembles an interacting Bose gas. The 1/N contributions vanish identically, so that corrections to leading order are 1/N2{\mathrm{N}}^{2}N2. (ii) The susceptibility at T=0 shows logarithmic singularities as H\ensuremath{\rightarrow}0. (iii) The Hubbard model and the Heisenberg chain have the same low-energy spin excitations for all U. (iv) The specific-heat coefficient \ensuremath{\gamma} is singular. These properties hold for arbitrary band filling and (ii)--(iv) hold for all N\ensuremath{\ge}2.
The degenerate Hubbard chain with N internal degrees of freedom is integrable if site occupations of more than two electrons are excluded. The ground state of the model has several unusual properties; e.g., the magnetic susceptibility has logarithmic singularities as the field H\ensuremath{\rightarrow}0 and also the specific-heat coefficient is singular. An extensive discussion of ground-state properties as a function of U and the band filling is presented. The elemental charge and spin excitations are derived for arbitrary U and band filling. If, on average, there is exactly one electron per site as a function of U, a qualitative change in the low-energy charge excitations is found at a critical value Uc{\mathit{U}}_{\mathit{c}}Uc​. This change is probably associated with a Mott metal-insulator transition (Uc{\mathit{U}}_{\mathit{c}}Uc​=0 for N=2). The Fermi velocity is finite for UUc{\mathit{U}}_{\mathit{c}}Uc​ but vanishes for U>Uc{\mathit{U}}_{\mathit{c}}Uc​ (for one electron per site). The spin-wave velocity is inversely proportional to the magnetic susceptibility for all U and band fillings. There are N-1 elemental spin-wave branches. For arbitrary band filling there are then N-1 soft modes at different finite momenta, all related to the Fermi surface. For exactly one electron per site, the spin-excitation spectrum can be mapped onto the one of the SU(N) Heisenberg chain. The implications of the hole states on superconductivity are also discussed.
The thermodynamic Bethe-ansatz equations for the one-dimensional Hubbard model with attractive on-site interaction of the electrons are solved numerically at low temperatures. At low temperatures the dominant states consist of spin-paired electrons (Cooper-pair--like) and excitations of such pairs (without breaking up the singlet bound states). A critical field (energy required to depair a Cooper pair) is obtained at T=0 (note that the superconducting Tc{T}_{c}Tc​=0), which disappears for T\ensuremath{\ne}0. The specific heat is linear in temperature, and the dependence of the coefficient \ensuremath{\gamma} on band filling and magnetic field is discussed. The excitation spectrum shows some analogies with that of resonant valence bonds in two dimensions.
We consider the SU(N) generalization of the one-dimensional Hubbard model with arbitrary degeneracy N (spin and orbital degrees of freedom). This model is integrable and has several unusual properties at low temperatures. The Bethe-Ansatz equations at T=0 are analyzed in the thermodynamic limit in the absence of external fields. In the continuum limit, the effective interaction between the charge degrees of freedom corresponds to a potential of the form [sinh(ax)${]}^{\mathrm{\ensuremath{-}}2}$, where x is the distance between the particles involved and a is an inverse length scale. In the limit N\ensuremath{\rightarrow}\ensuremath{\infty} and in the continuum limit, the charges reduce to a Bose gas interacting via a \ensuremath{\delta}-function potential. We further address here the properties of the charge degrees of freedom for a band filling close to one electron per site. The charge excitations obey Fermi statistics. We find a Mott metal-insulator transition at a critical value Uc{\mathit{U}}_{\mathit{c}}Uc​ of the Coulomb repulsion. Uc{\mathit{U}}_{\mathit{c}}Uc​ depends on N (Uc{\mathit{U}}_{\mathit{c}}Uc​=0 for N=2). A qualitative change in the charge-rapidity distribution is found at Uc{\mathit{U}}_{\mathit{c}}Uc​. The Fermi velocity is finite for UUc{\mathit{U}}_{\mathit{c}}Uc​, diverges as U\ensuremath{\rightarrow}Uc{\mathit{U}}_{\mathit{c}}Uc​, and vanishes for U>Uc{\mathit{U}}_{\mathit{c}}Uc​.
Even though the Hubbard model is one of the most fundamental models of highly correlated electrons, analytical and numerical data describing its thermodynamics at nonzero magnetization are relatively scarce. We present a detailed investigation of the thermodynamic properties for the one-dimensional repulsive Hubbard model in the presence of an arbitrary magnetic field for all values of the filling fraction and temperatures as low as $T\ensuremath{\sim}0.005t.$ Our analysis is based on the system of integral equations derived in the quantum transfer matrix framework. We determine the critical exponents of the quantum phase transitions and also provide analytical derivations for some of the universal functions characterizing the thermodynamics in the vicinities of the quantum critical points. Extensive numerical data for the specific heat, susceptibility, compressibility, and entropy are reported. The experimentally relevant double occupancy presents an interesting doubly nonmonotonic temperature dependence at intermediate values of the interaction strength and also at large repulsion and magnetic fields close to the critical value. The susceptibility in zero magnetic field has a logarithmic singularity at low temperatures for all filling factors similar to the behavior of the same quantity in the spin-1/2 isotropic Heisenberg model. We determine the density profiles for a harmonically trapped system and show that while the total density profile seems to depend mainly on the value of chemical potential at the center of the trap the distribution of phases in the inhomogeneous system changes dramatically as we increase the magnetic field.
In order to investigate the thermal properties (specific heat, magnetic susceptibility, entropy, internal energy, and some correlation functions) of the one-dimensional half-filled-band Hubbard model, we have studied linear chains and rings containing two to six atoms, by performing machine calculations. Supplementing the low-temperature behavior obtained from the exact solution for the infinite chain by Lieb and Wu, our results should be suggestive of the properties of the infinite system throughout the entire temperature domain. It is shown that when the ratio of the correlation energy UUU to the total width $\ensuremath{\Delta}$ of the band of single-particle excitations is larger than 1, the specific heat has two peaks. The high-temperature peak arises from the gradual metal-insulator transition (or the gradual formation of local moments), while the low-temperature peak is associated with the antiferromagnetic short-range ordering. When $\frac{U}{\ensuremath{\Delta}}$ becomes small, the two peaks merge into one. This picture is consistent with all other thermal properties, including correlation functions. The high-temperature properties are compared with the results predicted by Hubbard's approximate theory based on the truncation of the equations of motion of the Green's functions.