An experiment is described which measures the collision cross section for transfer of excitation in rubidium by helium. Rubidium atoms are pumped to either the
2P21 or
2P23 state by irradiation with one of the resonance lines. Some excited rubidium atoms are transferred to the other
P state by collisions with helium atoms. The rubidium atoms then radiate both resonance lines. Measurements of the intensities of both resonance lines as a function of helium pressure are used to calculate the collision cross section. The cross section for
2P21 to
2P23 is 1.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$
cm2\ifmmode\pm\else\textpm\fi{}10% and for
2P23 to
2P21 is 1.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$
cm2\ifmmode\pm\else\textpm\fi{}10%.