We have measured the effect of the transfer of excitation on the population of the
33D state of helium. Through careful diagnosis of a proton beam passing through a long target chamber containing helium gas, we have been able to separate the various contributions to the light intensity from the
33D state. Our measurements were performed at target-gas pressures roughly two orders of magnitude lower than those of previously reported measurements. We measure the summation of the excitation-transfer cross sections ${\ensuremath{\sigma}}_{c}(n)$ for the transfer from an
n1P state to the corresponding
n3F state times the branching ratio
Bn for radiative cascade to the
33D state, and obtain $\ensuremath{\Sigma}{B}_{n}{\ensuremath{\sigma}}_{c}(n)=2.2\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}12}$
cm2. This measurement enables us to relate the excitation transferred to the
33D state
QT(33D) to the excitation cross section of the
41P state $\ensuremath{\sigma}(4^{1}P)$. We obtain ${Q}_{T} (3^{3}D)=(1.5\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}15} {\mathrm{cm}}^{3})N\ensuremath{\sigma}(4^{1}P)$, an expression, which for the low pressures used in this experiment, is linear in the number density
N.
An experiment is described which measures the collision cross section for transfer of excitation in rubidium by helium. Rubidium atoms are pumped to either the
2P21 or
2P23 state by irradiation with one of the resonance lines. Some excited rubidium atoms are transferred to the other
P state by collisions with helium atoms. The rubidium atoms then radiate both resonance lines. Measurements of the intensities of both resonance lines as a function of helium pressure are used to calculate the collision cross section. The cross section for
2P21 to
2P23 is 1.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$
cm2\ifmmode\pm\else\textpm\fi{}10% and for
2P23 to
2P21 is 1.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$
cm2\ifmmode\pm\else\textpm\fi{}10%.