The linear, nearest-neighbor, magnetic systems described by the anisotropic, finite-field, spin-1/2, Heisenberg Hamiltonian H = Σi(SxiSxi+1+SyiSyi+1+ΔSziSzi+1 ) −HoΣiSzi, −∞<Δ<∞ and 0?H0, are increasingly attracting attention, both experimentally and theoretically. These systems are now known to be intimately related to models in quantum field theory, for quantum solitons, and for other many-body problems. In its own right, the Hamiltonian describes many physically realized systems; thus the theoretical prediction of some unexpected and interesting properties indicates experimental possibilities. We outline what has been learned, from the method of Bethe’s Ansatz, of the ground state, elementary excitations, and low-temperature thermodynamics as functions of Δ and Ho. We discuss the changes in behavior of the low-temperature thermodynamics as Δ and Ho are varied and give the relationship of these changes to the ground state and excitation spectrum characteristics. In small magnetic fields, unexpected structure in the low-temperature thermodynamics of the ferromagnetic Heisenberg magnet has been predicted.
The excitation spectrum of the ferromagnetic
s=21 Ising-Heisenberg chain as probed by dynamic form factors is studied. Exact results are presented for zero temperature, and the modifications introduced by thermally induced transitions are elucidated by finite-chain calculations. A particularly interesting result is the occurrence of a thermally induced resonance around zero frequency for an Ising-like model. Its origin is traced back to transitions involving magnon bound states. The resonance structure of the dynamic form factors associated with a Heisenberg-like system turns out to be less spectacular, because the contributions of different induced transitions nearly overlap on the frequency scale; so that rather broad resonance structures result. Our findings have an important bearing on related models with
s>21, such as CsNi
F3, and on the soliton aspect of the classically treated systems.
The thermodynamic properties of a spin
S=1/2 tetrameric Heisenberg antiferromagnetic chain with alternating interactions
AF1-AF2-AF1-F (AF and F denote the antiferromagnetic and ferromagnetic couplings, respectively) are studied by means of the transfer-matrix renormalization-group method and Jordan-Wigner transformation. It is found that in the absence of magnetic field, the thermodynamic behaviors are closely related to the gapped low-lying excitations, and a novel structure with three peaks in the temperature dependence of specific heat is unveiled. In a magnetic field, a phase diagram in the temperature-field plane for the couplings satisfying
JAF1=JAF2=JF is obtained, in which various phases are identified. The temperature dependence of thermodynamic quantities including the magnetization, susceptibility, and specific heat are studied to characterize the corresponding phases. It is disclosed that the magnetization has a crossover behavior at low temperature in the Luttinger liquid phase, which is shown falling into the same class as that in the
S=1 Haldane chain. In the plateau regime, the thermodynamic behaviors alter at a certain field, which results from the crossing of two excitation spectra. By means of the fermion mapping, it is uncovered that the system has four spectra from fermion and hole excitations that are responsible for the observed thermodynamic behaviors.
The low-temperature thermodynamic properties of a spin-\textonehalf{} one-dimensional random anisotropic (Heisenberg-Ising) antiferromagnet described by the Hamiltonian $H=\ensuremath{\Sigma}{i}^{}{J}_{i}({\ensuremath{\sigma}}_{x}^{i}{\ensuremath{\sigma}}_{x}^{i+1}+{\ensuremath{\sigma}}_{y}^{i}{\ensuremath{\sigma}}_{y}^{i+1}+\ensuremath{\gamma}{\ensuremath{\sigma}}_{z}^{i}{\ensuremath{\sigma}}_{z}^{i+1})$ are studied as a function of disorder and anisotropy. The
Ji> 0 are independent random variables obeying a probability distribution
P(J), and $0<~\ensuremath{\gamma}<~\ensuremath{\infty}$. The approach used is a numerical implementation of a real-space renormalization-group (RG) method previously introduced. The isotropic Heisenberg case ($\ensuremath{\gamma}=1$), the
XY case ($\ensuremath{\gamma}=0$). and the Ising case ($\ensuremath{\gamma}=\ensuremath{\infty}$) are fixed points of the RG transformation. It is found that in the
XY region $\ensuremath{\gamma}<~1$, including the Heisenberg point, the system exhibits singular behavior in the thermodynamic properties for arbitrary probability distributions for the couplings. For the
XY limit ($\ensuremath{\gamma}=0$) this is in agreement with known exact results. The functional form for the low-temperature susceptibility is found to be $\ensuremath{\chi}\ensuremath{\sim}\frac{1}{(T{\mathrm{ln}}^{m}(\frac{T}{{T}_{0}}))}$ in the entire region $0<~\ensuremath{\gamma}<~1$ for arbitrary probability distributions. In the Ising region ($\ensuremath{\gamma}>1$) the susceptibility shows an approximate power-law divergence for small anisotropy but goes eventually to zero as $T\ensuremath{\rightarrow}0$. Possible relevance of these results to recent experiments on Qn
(TCNQ)2 is discussed.
The magnetic and thermodynamic properties of spin-
1∕2 Heisenberg diamond chains are investigated in three different cases: (a)
J1,
J2,
J3>0 (frustrated), (b)
J1,
J3<0,
J2>0 (frustrated), and (c)
J1,
J2>0,
J3<0 (nonfrustrated), where the bond coupling
Ji (i=1,2,3)>0 stands for an antiferromagnetic (AF) interaction, and
<0 for a ferromagnetic (F) interaction. The density-matrix renormalization-group (DMRG) technique is invoked to study the properties of the system in the ground state, while the transfer-matrix renormalization-group (TMRG) technique is applied to explore the thermodynamic properties. The local magnetic moments, spin-correlation functions, and static structure factors are discussed in the ground state for the three cases. It is shown that the static structure factor
S(q) shows peaks at wave vectors $q=a\ensuremath{\pi}∕3$
(a=0,1,2,3,4,5) for different couplings in a zero magnetic field, which, however, in the magnetic fields where the magnetization plateau with
m=1∕6 pertains, exhibits the peaks only at
q=0, $2\ensuremath{\pi}∕3$, and $4\ensuremath{\pi}∕3$, which are found to be couplings independent. The DMRG results of the zero-field static structure factor can be nicely fitted by a linear superposition of six modes, where two fitting equations are proposed. It is observed that the six modes are closely related to the low-lying excitations of the system. At finite temperatures, the magnetization, susceptibility, and specific heat show various behaviors for different couplings. The double-peak structures of the susceptibility, and specific heat against temperature are obtained, where the peak positions and heights are found to depend on the competition of the couplings. It is also uncovered that the
XXZ anisotropy of F and AF couplings leads the system of case (c) to display quite different behaviors. In addition, the experimental data of the susceptibility, specific heat, and magnetization for the compound
Cu3(CO3)2(OH)2 are fairly compared with our TMRG results.
The anisotropic
XXZ spin-
21 Heisenberg chain is studied using renormalization-group theory. The specific heats and nearest-neighbor spin-spin correlations are calculated throughout the entire temperature and anisotropy ranges in both ferromagnetic and antiferromagnetic regions, obtaining a global description and quantitative results. We obtain, for all anisotropies, the antiferromagnetic spin-liquid spin-wave velocity and the Ising-like ferromagnetic excitation spectrum gap, exhibiting the spin-wave to spinon crossover. A number of characteristics of purely quantum nature are found: The in-plane interaction
sixsjx+siysjy induces an antiferromagnetic correlation in the out-of-plane
siz component, at higher temperatures in the antiferromagnetic
XXZ chain, dominantly at low temperatures in the ferromagnetic
XXZ chain, and, in-between, at all temperatures in the
XY chain. We find that the converse effect also occurs in the antiferromagnetic
XXZ chain: an antiferromagnetic
sizsjz interaction induces a correlation in the
sixy component. As another purely quantum effect, (i) in the antiferromagnet, the value of the specific heat peak is insensitive to anisotropy and the temperature of the specific heat peak decreases from the isotropic (Heisenberg) with introduction of either type (Ising or
XY) of anisotropy; and (ii) in complete contrast, in the ferromagnet, the value and temperature of the specific heat peak increase with either type of anisotropy.