There has been considerable recent philosophical debate over the implications of many particle quantum mechanics for the metaphysics of individuality (cf. Huggett [1997]). In this paper I look at things from a rather different perspective: by investigating the significance of permutation symmetry. I consider how various philosophical positions link up to the physical postulate of the indistinguishability of permuted states-permutation invariance-and how this postulate is used to explain quantum statistics. I offer an explanation of the statistics that relies on the neglected parallel between permutations and covariant spatial transformation. And I explore the parallel, showing that a further kind of symmetry explains why permutations are invariant when spatial symmetries are not.
There has been considerable recent philosophical debate over the implications of many particle quantum mechanics for the metaphysics of individuality (cf. Huggett [1997]). In this paper I look at things from a rather different perspective: by investigating the significance of permutation symmetry. I consider how various philosophical positions link up to the physical postulate of the indistinguishability of permuted states-permutation invariance-and how this postulate is used to explain quantum statistics. I offer an explanation of the statistics that relies on the neglected parallel between permutations and covariant spatial transformation. And I explore the parallel, showing that a further kind of symmetry explains why permutations are invariant when spatial symmetries are not.
If a system in atomic physics contains a number of particles of the same kind, e.g. a number of electrons, the particles are absolutely indistinguishable one from another. No observable change is made when two of them are interchanged … A satisfactory theory ought, of course, to count any two observationally indistinguishable states as the same state and to deny that any transition does occur when two similar particles exchange places. ( Dirac, 1958, p. 207 ) Introduction In our contribution to this volume we deal with discrete symmetries: these are symmetries based upon groups with a discrete set of elements (generally a set of elements that can be enumerated by the positive integers). In physics we find that discrete symmetries frequently arise as ‘internal’, non-spacetime symmetries. Permutation symmetry is such a discrete symmetry, arising as the mathematical basis underlying the statistical behaviour of ensembles of certain types of indistinguishable quantum particle (e.g. fermions and bosons). Roughly speaking, if such an ensemble is invariant under a permutation of its constituent particles (i.e. permutation symmetric) then one doesn't ‘count’ those permutations which merely ‘exchange’ indistinguishable particles; rather, the exchanged state is identified with the original state. This principle of invariance is generally called the ‘indistinguishability postulate’ (IP), but we prefer to use the term ‘permutation invariance’ (PI).
This chapter analyzes permutation symmetry, focusing on the proper understanding of pchapter indistinguishability in classical statistical mechanics and in quantum theory. It shows that it is possible to treat the statistical mechanical statistics for classical pchapters as invariant under permutation symmetry and argues that while the concept of indistinguishable, permutation invariant, classical pchapters is coherent, it is in contradiction with many claims found in the literature. The chapter also contends that the concept of permutation symmetry should be considered in the same level as other symmetries and invariances of physical theories.
The treatment of identical particles in quantum mechanics rests on two (related) principles: the spin‐statistics connection and the Symmetrization Postulate. In light of recent theories (such as q‐deformed commutators) that allow for ‘small’ violations of the spin‐statistics connection and the Symmetrization Postulate, we revisit the issue of how quantum mechanics deals with identical particles and how it supports or fails to support various philosophical stances concerning individuality. As a consequence of the expanded possibilities for quantum statistics, we argue that permutation symmetry is best formulated as a formal property of the state function describing the system of particles rather than as a property of the individual particles.1 Introduction2 Philosophical background2.1 Important terminology2.1.1 Identity2.1.2 Indistinguishability2.1.3 Indiscernibility2.2 When are particles indistinguishable?2.3 The Principle of the Identity of Indiscernibles and quantum mechanics2.4 The Principle of the Identity of Indiscernibles and logic2.5 Particle history2.6 Transcendental individuality3 Some quantum formalism3.1 The Principle of Permutation Invariance and the Symmetrization Postulate3.2 The configuration‐space approach3.3 Commutators and anticommutators, and identical particle statistics3.4 Q‐mutators4 Identical particle statistics: a holistic point of view5 Conclusions
The permutation symmetry of quantum mechanics is widely thought to imply a sort of metaphysical underdetermination about the identity of particles. Despite claims to the contrary, this implication does not hold in the more fundamental quantum field theory, where an ontology of particles is not generally available. Although permutations are often defined as acting on particles, a more general account of permutation symmetry can be formulated using superselection theory. As a result, permutation symmetry applies even in field theories with no particle interpretation. The quantum mechanical account of permutations acting on particles is recovered as a special case.
Physical theories continue to be interpreted in terms of particles. The idea of a particle has required modification for successive theories but remains central to scientific explanation. Particle ontologies also have the virtue of explaining basic epistemic features of the world and so remain appealing for the scientific realist. However, particle ontologies are untenable when coupled with the empirically necessary postulate of permutation invariance—the claim that permuting the roles of particles in a representation of a physical state results in a representation of the same state. I demonstrate that any permutation invariant theory is incompatible with a particle ontology.
In classical physics, the question whether there are subsets of identical particles is not particularly interesting. After all, whether the particles are identical or not, we can always track each of them at any time. As we shall see, in quantum mechanics identical particles are indistinguishable because we cannot track trajectories, and this fact induces some important symmetry properties on the total wave function describing the system of particles under consideration. Generally speaking, a symmetry is an effect of an invariance, that is, the system does not change if one effects certain transformations (see Ch. 8). In this case, the system is not modified under exchange of two identical particles. Moreover, such a symmetry yields a most interesting connection between spin and statistics. After a short introduction to the significance of statistics in quantum mechanics (in Sec. 7.1), we define the permutation operator and discuss the symmetry properties of the wave function of N identical particles (Sec. 7.2). In Sec. 7.3 we show that quantum particles, differently from classical particles (that obey the Maxwell–Boltzmann statistics), may be subject to two different statistics, namely the Fermi–Dirac statistics for fermions and the Bose–Einstein statistics for bosons. In Sec. 7.4 we treat the so-called exchange interaction and, finally, in Sec. 7.5 we consider some applications of the two statistics. Statistics and quantum mechanics Identical particles are those particles whose Hamiltonian is symmetric under exchange of one particle with the other.