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Optical Materials

Inhomogeneous and homogeneous linewidths in Er3+-doped chalcogenide glasses

Laurent Bigot, A.-M. Jurdyc, B. Jacquier, Jean‐Luc Adam

Published May 19, 2003• 17 citations
Publisher
DOI
10.1016/s0925-3467(03)00111-3

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Resonance-fluorescence-line-narrowing studies have been performed on a representative group of Er3+ -doped glasses for excitation in both the 1530 and 980-nm bands at 4.2, 77, 200, and 300 K. Fluorozirconate, fluorophosphate, phosphate, silicate, Ge/P-doped and A1/P-doped silica preforms, and Al/P-doped and Ge-doped fibers were examined. At 77 K the homogeneous linewidths were found to be relatively insensitive to composition. In particular, they vary from 1.4 to 1.8 cm-1 for the different hosts using excitation at 1531 nm. At 300 K weak resonant features were observed in most samples, consistent with a small inhomogeneous contribution to a predominantly homogeneous fluorescence emission.

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Germanosilicate glass shows inhomogeneous saturation behavior,1 whereas aluminogermanosilicate glass shows homogeneous behavior.2 Zemon et al.3 have published a study of nonresonant fluorescence line narrowing (FLN), but their spectra show little evidence of significant spectral narrowing by site selection. Spectral hole-burning spectroscopy has been applied by Desurvire et al.4 on Er3+ in aluminosilicate fiber. They extracted an inhomogeneous linewidth Γin of 12.5 nm and a homogeneous linewidth Γh of 115 nm.

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Resonance-fluorescence-line-narrowing studies have been performed on a representative group of Er3+ -doped glasses for excitation in both the 1530 and 980-nm bands at 4.2, 77, 200, and 300 K. Fluorozirconate, fluorophosphate, phosphate, silicate, Ge/P-doped and A1/P-doped silica preforms, and Al/P-doped and Ge-doped fibers were examined. At 77 K the homogeneous linewidths were found to be relatively insensitive to composition. In particular, they vary from 1.4 to 1.8 cm-1 for the different hosts using excitation at 1531 nm. At 300 K weak resonant features were observed in most samples, consistent with a small inhomogeneous contribution to a predominantly homogeneous fluorescence emission.
Germanosilicate glass shows inhomogeneous saturation behavior,1 whereas aluminogermanosilicate glass shows homogeneous behavior.2 Zemon et al.3 have published a study of nonresonant fluorescence line narrowing (FLN), but their spectra show little evidence of significant spectral narrowing by site selection. Spectral hole-burning spectroscopy has been applied by Desurvire et al.4 on Er3+ in aluminosilicate fiber. They extracted an inhomogeneous linewidth Γin of 12.5 nm and a homogeneous linewidth Γh of 115 nm.