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Journal of Mathematical Physics

Correlated states and collective transition operators for multilevel atomic systems. II. Symmetry properties

Jagdish Rai, C. L. Mehta, Narasimhaiengar Mukunda

Published Nov 1, 1988• 1 citation
Publisher

Abstract

The symmetry properties of the N-particle multilevel system are studied. For indistinguishable particles, the total wave function must be either symmetric or antisymmetric in the exchange of any two particles. The internal states of the multilevel system are combined with suitable spatial wave functions to produce a totally symmetric or antisymmetric wave function. The problem of degeneracy and the method of combining a given permutational symmetry of the internal wave function with the same or the conjugate symmetry for the spatial part are described. It is found that Young’s diagram corresponding to the given irreducible representation of the permutation group plays an important role.

DOI
10.1063/1.528132

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The symmetry properties of the N-particle multilevel system are studied. For indistinguishable particles, the total wave function must be either symmetric or antisymmetric in the exchange of any two particles. The internal states of the multilevel system are combined with suitable spatial wave functions to produce a totally symmetric or antisymmetric wave function. The problem of degeneracy and the method of combining a given permutational symmetry of the internal wave function with the same or the conjugate symmetry for the spatial part are described. It is found that Young’s diagram corresponding to the given irreducible representation of the permutation group plays an important role.
The correlated states of an assembly of N multilevel atoms interacting with resonant radiation fields are determined. On the basis of the duality between the permutation group and the linear group, one can construct the internal states for an assembly of N atoms, with n levels each. The possible states are determined by various allowed Young diagrams, corresponding to various representations of the permutation group SN. The collective transition operators are obtained as the generators of the group SU(n).
Quantum systems of indistinguishable particles are commonly described using the formalism of second quantization, which relies on the assumption that any admissible quantum state must be either symmetric or antisymmetric under particle permutations. Coherence-induced many-body effects such as superradiance, however, can arise even in systems whose constituents are not fundamentally indistinguishable as long as all relevant dynamical observables are permutation-invariant. Such systems are not confined to symmetric or antisymmetric states and therefore require a different theoretical approach. Focusing on noninteracting systems, here we combine tools from representation theory and thermodynamically consistent master equations to develop such a framework. We characterize the structure and properties of the steady states emerging in permutation-invariant ensembles of arbitrary multilevel systems that are collectively weakly coupled to a thermal environment. As an application of our general theory, we further explore how these states can in principle be used to enhance the performance of quantum thermal machines. Our group-theoretical framework thereby makes it possible to analyze various limiting cases that would not be accessible otherwise. In addition, it allows us to show that the properties of multilevel ensembles differ qualitatively from those of spin ensembles, which have been investigated earlier using the standard Clebsch-Gordan theory. Our results have a large scope for future generalizations and pave the way for systematic investigations of collective effects arising from permutation invariance in quantum thermodynamics.
It is demonstrated that in a system of NNN similar particles, the permissible wave functions are either symmetrical or antisymmetrical with respect to interchanges of the particles, if the following principles are assumed to be valid: (1) The interchange of two like particles produces no change in any measurable property of the system. In particular, if $\ensuremath{\psi}$ is to be a permissible wave function, $\ensuremath{\psi}\overline{\ensuremath{\psi}}$ must be unaltered by such an interchange. (2) All the wave functions obtained from a given permissible wave function by permuting the similar particles are also permissible wave functions for the same eigenvalue.
Abstract It is well known that the allowed wavefunctions for an N -electron system should be antisymmetric with respect to the permutation of any pair of electron labels. On the other hand, the Hamiltonian for such a system is invariant under any permutation of electron labels and, consequently, its eigenfunctions are the basis for the irreducible representations of the symmetric group S N . Here, we investigate which symmetry species of the S N group are compatible with the antisymmetry principle. We illustrate the conclusions by means of simple N -particle one-dimensional models with harmonic interactions.
It is well known that the allowed wavefunctions for an N-electron system should be antisymmetric with respect to the permutation of any pair of electron labels. On the other hand, the Hamiltonian for such system is invariant under any permutation of electron labels and, consequently, its eigenfunctions are basis for the irreducible representations of the symmetric group SN.Here, we investigate which symmetry species of the SN group are compatible with the antisymmetry principle. We illustrate the conclusions by means of simple N-particle one-dimensional models with harmonic interactions.
In this paper we analyze a recently proposed approach for the construction of antisymmetric functions for atomic and molecular systems. It is based on the assumption that the main problems with Hartree-Fock wavefunctions stem from their lack of proper permutation symmetry. This alternative building approach is based on products of a space times a spin function with opposite permutation symmetry. The main argument for devising such factors is that the eigenfunctions of the non-relativistic Hamiltonian are either symmetric or antisymmetric with respect to the transposition of the variables of a pair of electrons. However, since the eigenfunctions of the non-relativistic Hamiltonian are basis for the irreducible representations of the symmetric group they are not necessarily symmetric or antisymmetric, except in the trivial case of two electrons. We carry out a simple and straightforward general analysis of the symmetry of the eigenfunctions of the non-relativistic Hamiltonian and illustrate our conclusions by means of two exactly-solvable models of N=2N=2N=2 and N=3N=3N=3 identical interacting particles.