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arXiv:2206.12639 · Physical Review Research

Thermodynamics of permutation-invariant quantum many-body systems: A group-theoretical framework

Benjamin Yadin, Benjamin Morris, Kay Brandner

Published Jul 10, 2023• 13 citations
arXivHTMLPDF

Abstract

Quantum systems of indistinguishable particles are commonly described using the formalism of second quantization, which relies on the assumption that any admissible quantum state must be either symmetric or antisymmetric under particle permutations. Coherence-induced many-body effects such as superradiance, however, can arise even in systems whose constituents are not fundamentally indistinguishable as long as all relevant dynamical observables are permutation-invariant. Such systems are not confined to symmetric or antisymmetric states and therefore require a different theoretical approach. Focusing on noninteracting systems, here we combine tools from representation theory and thermodynamically consistent master equations to develop such a framework. We characterize the structure and properties of the steady states emerging in permutation-invariant ensembles of arbitrary multilevel systems that are collectively weakly coupled to a thermal environment. As an application of our general theory, we further explore how these states can in principle be used to enhance the performance of quantum thermal machines. Our group-theoretical framework thereby makes it possible to analyze various limiting cases that would not be accessible otherwise. In addition, it allows us to show that the properties of multilevel ensembles differ qualitatively from those of spin ensembles, which have been investigated earlier using the standard Clebsch-Gordan theory. Our results have a large scope for future generalizations and pave the way for systematic investigations of collective effects arising from permutation invariance in quantum thermodynamics.

DOI
10.1103/physrevresearch.5.033018

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Quantum systems of indistinguishable particles are commonly described using the formalism of second quantization, which relies on the assumption that any admissible quantum state must be either symmetric or antisymmetric under particle permutations. Coherence-induced many-body effects such as superradiance, however, can arise even in systems whose constituents are not fundamentally indistinguishable as long as all relevant dynamical observables are permutation-invariant. Such systems are not confined to symmetric or antisymmetric states and therefore require a different theoretical approach. Focusing on noninteracting systems, here we combine tools from representation theory and thermodynamically consistent master equations to develop such a framework. We characterize the structure and properties of the steady states emerging in permutation-invariant ensembles of arbitrary multilevel systems that are collectively weakly coupled to a thermal environment. As an application of our general theory, we further explore how these states can in principle be used to enhance the performance of quantum thermal machines. Our group-theoretical framework thereby makes it possible to analyze various limiting cases that would not be accessible otherwise. In addition, it allows us to show that the properties of multilevel ensembles differ qualitatively from those of spin ensembles, which have been investigated earlier using the standard Clebsch-Gordan theory. Our results have a large scope for future generalizations and pave the way for systematic investigations of collective effects arising from permutation invariance in quantum thermodynamics.
We describe the implications of permutation symmetry for the state space and dynamics of quantum mechanical systems of matrices of general size NNN. We solve the general 11-parameter permutation invariant quantum matrix harmonic oscillator Hamiltonian and calculate the canonical partition function. The permutation invariant sector of the Hilbert space, for general Hamiltonians, can be described using partition algebra diagrams forming the bases of a tower of partition algebras Pk(N){P}_{k}(N)Pk​(N). The integer kkk is interpreted as the degree of matrix oscillator polynomials in the quantum mechanics. Families of interacting Hamiltonians are described which are diagonalized by a representation theoretic basis for the permutation invariant subspace which we construct for $N\ensuremath{\ge}2k$. These include Hamiltonians for which the low-energy states are permutation invariant and can give rise to large ground state degeneracies related to the dimensions of partition algebras. A symmetry-based mechanism for quantum many body scars discussed in the literature can be realized in these matrix systems with permutation symmetry. A mapping of the matrix index values to lattice sites allows a realization of the mechanism in the context of modified Bose-Hubbard models. Extremal correlators analogous to those studied in AdS/CFT\mathrm{AdS}/\mathrm{CFT}AdS/CFT are shown to obey selection rules based on Clebsch-Gordan multiplicites (Kronecker coefficients) of symmetric groups.
The symmetry properties of the N-particle multilevel system are studied. For indistinguishable particles, the total wave function must be either symmetric or antisymmetric in the exchange of any two particles. The internal states of the multilevel system are combined with suitable spatial wave functions to produce a totally symmetric or antisymmetric wave function. The problem of degeneracy and the method of combining a given permutational symmetry of the internal wave function with the same or the conjugate symmetry for the spatial part are described. It is found that Young’s diagram corresponding to the given irreducible representation of the permutation group plays an important role.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Quantum Mechanics was established as the theory of the microscopic world, which allowed to understand processes in atoms and molecules. Its emergence led to a new scientific paradigm that quickly spread to different research fields. Two relevant examples are Quantum Thermodynamics and Quantum Many-Body Theory, where the former aims to characterize thermodynamic processes in quantum systems and the latter intends to understand the properties of quantum many-body systems. In this thesis, we tackle some of the questions in the overlap between these disciplines, focusing on the concepts of temperature and correlations. Specifically, it contains results on the following topics: locality of temperature, correlations in long-range interacting systems and thermometry at low temperature. The problem of locality of temperature is considered for a system at thermal equilibrium and consists in studying whether it is possible to assign a temperature to any of the subsystems of the global system such that both local and global temperatures are equal. We tackle this problem in two different settings, for generic one-dimensional spin chains and for a bosonic system with a phase transition at non-zero temperature. In the first case, we consider generic one-dimensional translation-invariant spin systems with short-range interactions and prove that it is always possible to assign a local temperature equal to the global one for any temperature, including at criticality. For the second case, we consider a three-dimensional discretized version of the Bose-Einstein model at the grand canonical ensemble for some temperature and particle density, and characterize its non-zero-temperature phase transition. Then, we show that temperature is locally well-defined at any temperature and at any particle density, including at the phase transition. Additionally, we observe a qualitative relation between correlations and locality of temperature in the system. Moving to correlations, we consider fermionic two-site long-range interacting systems at thermal equilibrium. We show that correlations between anti-commutative operators at non-zero temperature are upper bounded by a function that decays polynomially with the distance and with an exponent that is equal to the interaction exponent, which characterizes the interactions in the Hamiltonian. Moreover, we show that our bound is asymptotically tight and that the results extend to density-density correlations as well as other types of correlations for quadratic and fermionic Hamiltonians with long-range interactions. Regarding the results on thermometry, we consider a bosonic model and prove that strong coupling between the probe and the system can boost the thermal sensitivity for low temperature. Furthermore, we provide a feasible measurement scheme capable of producing optimal estimates at the considered regime.
1. Cooperative phenomena and processes in various many-body physical systems (atoms, molecules, nuclei etc.) are now the topic of great interest (see e.g. [ 1-6 ] and references therein). A natural and efficient tool for studying cooperative phenomena in quantum systems is the second quantization method [ 7 ], which is closely connected with the representation theory of Lie groups and supergroups [ 8 – 12 ]. Therefore, group-theoretical methods are very adequate to an analysis of different cooperative effects within the general approach of dynamic symmetries [ 13 ].