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Global Journal of Pure and Applied Sciences

On the Bardeen-Cooper-Schrieffer(BCS) Hamiltonian

MI Umo

Published Jul 15, 2013• 0 citations
Publisher

Abstract

We present a detailed diagonalization calculation of the Bardeen-Cooper-Schrieffer (BCS) Hamiltonian via the unitary transformation method which allows for the Bogolyubov-Valatin transformation to be arrived at naturally. The energy gap equation is derived and solved, and averages of some representative thermodynamic quantities are obtained.KEYWORDS: Hamiltonian, unitary matrix, superconductivity, interaction, ground state.

DOI
10.4314/gjpas.v19i1.7

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We present a detailed diagonalization calculation of the Bardeen-Cooper-Schrieffer (BCS) Hamiltonian via the unitary transformation method which allows for the Bogolyubov-Valatin transformation to be arrived at naturally. The energy gap equation is derived and solved, and averages of some representative thermodynamic quantities are obtained.KEYWORDS: Hamiltonian, unitary matrix, superconductivity, interaction, ground state.
The spectrum and eigenstates of Bardeen-Cooper-Schrieffer's reduced Hamiltonian in the theory of superconductivity are investigated in a mathematically rigorous manner. The Hamiltonian is defined first for a finite number of electrons contained in a finite volume. The interaction Hamiltonian is assumed to take a simple form. The Hamiltonian after the Bogoliubov transformation (transformed Hamiltonian) has a limit in the weak topology of Hilbert space when the volume tends to infinity with the number density of electrons kept constant. In the limit the interaction part vanishes and the free part gives a continuous excitation spectrum of Bogolons (transformed electrons). It should be noticed that the operator norm of the former does not tend to zero and has no strong limit as well as the total Hamilton. An equivalent boson which consists of two Bogolons with opposite momenta and spins is introduced. In the Fock space for the bosons the Hamiltonian has a strong limit for infinite volume. The limit operator has the same excitation spectrum of Bogolons as the free Hamiltonian and the existence of the lower limit of the spectrum is shown for some special class of the interactions. For large volume the limit operator is a good approximation to be transformed Hamiltonian. The ground state of the free part of the transformed Hamiltonian (i.e. the ground state of Bardeen-Cooper-Schrieffer's calculation) is not the exact eigenstate of the transformed total Hamiltonian and the difference does not vanish when the volume tends to infinity.
In their theory of superconductivity, Bardeen, Cooper, and Schrieffer made use of a reduced Hamiltonian which included only scattering of pairs of particles of opposite momentum and spin. It is shown that the solution they obtained by a variational method is correct to O(1n)O(\frac{1}{n})O(n1​) for a large system. The single particle Green's function is derived and used to calculate the interaction energy.
The canonical operator exp [−β(H − μN)] associated with the Bardeen-Cooper-Schrieffer (BCS) model Hamiltonian of superconductivity is represented as a functional integral by the use of Feynman's ordering parameter. General properties of the partition function in this representation are discussed. Taking the inverse volume of the system as an expansion parameter, it is possible to calculate the thermodynamic potential including terms independent of the volume. This yields a new proof that the BCS variational value is asymptotically exact. The behavior of the canonical operator for large volume is described and related to the state of free quasiparticles. A study of the terms of the thermodynamic potential which are of smaller order in the volume in the low-temperature limit, shows that the ground state energy is nondegenerate and belongs to a number eigenstate.
Abstract We calculate Bardeen–Cooper–Schrieffer (BCS) state of a unitary Fermi gas of atoms interacting with the finite-ranged Jost-Kohn potential which has been recently shown to account for the resonant interactions (2019 J. Phys. B: At. Mol. Opt. Phys. 52 165004). Using exact scattering solution of the potential, we derive two-body T-matrix element which is employed to construct the BCS Hamiltonian in momentum space. We present results on the energy- and range-dependence of the pairing gap and superfluid density and the range-dependence of the chemical potential for a wide variation of the scattering length including the unitary regime. In the zero range limit our calculated gap at the Fermi energy is found to be nearly equal to that calculated in mean-field theory with contact potential. The mean gap averaged over the full width at half maximum of the gap function in the zero range and unitary limits is found to be 0.42E F which is quite close to the recent result of the quantum Monte-Carlo simulation (2018 Phys. Rev. A 97 013601). The chemical potential in the zero range limit also agrees well with that for the contact potential.
Abstract One of the important steps leading to the successful formulation of the microscopic theory of superconductivity was the model calculation performed by Cooper (1956) which showed that two electrons, interacting above a filled Fermi sea, had a bound state in the presence of an arbitrarily weak attractive interaction. This chapter first examines Cooper’s calculation. The success of the Cooper model calculation in producing a bound state, with its implication that a proper many-body theory would contain a gap in the excitation spectrum, strongly suggests that the ground state wave function should be constructed from pairs of electrons. However, it is difficult to perform calculations using the many-body pair wave function from Cooper’s model. The chapter then introduces the wave function proposed by Bardeen, Cooper, and Schrieffer (BCS) as an alternative.
The ground-state wave function and some of the excited states of the BCS reduced Hamiltonian are found. In the limit of large volume, the boundary and continuity conditions on the exact wave function lead directly to the equations which Bardeen, Cooper, and Schrieffer found by a variational technique. It is also shown in what sense the BCS trial wave function may be considered asymptotically exact in this limit. Finite-volume corrections are included in an appendix, and explicit calculations are carried out for a one-step model of the kinetic energy which has possible applications to the problem of the finite nucleus.