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Journal of Physics A Mathematical and General

t-violation and quaternionic state oscillations

G. Scolarici, Luigi Solombrino

Published Oct 19, 2000• 2 citations
Publisher

Abstract

We derive, using the quaternionic group representation theory, the possible forms of the t -violating Hamiltonians, and consider time evolution in a two-level system when a t -violating term is added to a t -preserving unperturbed Hamiltonian. Transition probabilities are calculated; moreover, the time evolution of a complex state is determined analytically, showing that a quaternionic component arises naturally in its evolution. Finally, some properties of the time-reversal observable are studied and a set of selection rules is obtained.

DOI
10.1088/0305-4470/33/43/311

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We derive, using the quaternionic group representation theory, the possible forms of the t -violating Hamiltonians, and consider time evolution in a two-level system when a t -violating term is added to a t -preserving unperturbed Hamiltonian. Transition probabilities are calculated; moreover, the time evolution of a complex state is determined analytically, showing that a quaternionic component arises naturally in its evolution. Finally, some properties of the time-reversal observable are studied and a set of selection rules is obtained.
Abstract We revisit the formulation of quantum mechanics over the quaternions and investigate the dynamical structure within this framework. Similar to standard complex quantum mechanics, time evolution is then mediated by a unitary operator which can be written as the exponential of the generator of time shifts. By imposing physical assumptions on the correspondence between the energy observable and the generator of time shifts, we prove that quaternionic quantum theory admits a time evolution only for systems with a quaternionic dimension of at most two. Applying the same strategy to standard complex quantum theory, we reproduce that the correspondence dictated by the Schrödinger equation is the only possible choice, up to a shift of the global phase.
The conventional time-dependent perturbation theory in quantum mechanics is established within the framework of Hermitian Hamiltonians, applicable for describing quantum transitions and associated energy level responses in such systems. However, this theory has fundamental limitations when applied to non-Hermitian systems. Consequently, researchers have systematically extended time-dependent perturbation theory to non-Hermitian systems, establishing a corresponding mature framework. Building on this foundation, this study extends the theory to investigate the transition dynamics induced by non-Hermitian interactions in non-Hermitian Hamiltonian systems. We employ a biorthogonal basis representation for a three-level non-Hermitian system. This work investigates a system comprising an unperturbed static non-Hermitian Hamiltonian and a periodically driven time-dependent perturbation Hamiltonian. Taking the three-level system as a concrete example, we combine analytical methods with numerical simulations to solve and analyze its dynamical evolution equations. These complementary approaches reveal that when system parameters complete a full cycle around an exceptional point, the transitional behavior exhibits specific evolutionary patterns. In this system, quantum transition probabilities exhibit significant asymmetry and non-conservation that depend on the initial and final states, revealing inherent directional characteristics in the dynamical process. Furthermore, for a three-level, periodically driven non-Hermitian system with time-dependent perturbations, this asymmetry is even more pronounced, manifesting as a distinct disparity between forward and reverse transition probabilities. The periodic driving actively amplifies the asymmetry in the transition process. By designing the perturbation spectrum, selective manipulation of specific quantum states can be achieved. Moreover, transition probabilities can be significantly enhanced under resonance conditions, while non-Hermiticity further breaks the system's inherent symmetry, leading to substantial amplification of transitions in a single direction. By precisely tuning the drive frequency, interactions between specific coupling channels can be selectively enhanced or suppressed. The amplification of channel asymmetry by non-Hermitian properties provides a novel mechanism for directional control of quantum states and opens new pathways for realizing related quantum technologies.
We now consider systems for which the Hamiltonian contains time-dependent interaction terms. In such cases we cannot reduce the time-dependent Schro¨dinger equation to an eigenvalue equation. However, if the time-dependent terms can be regarded as small perturbations, we can develop a form of perturbation theory that can be used to calculate the effects of time-dependent terms. Consider a system for which the Hamiltonian may be written as the sum of a dominant unperturbed part Hˆ0 and a small perturbation Hˆ ′ as Hˆ = Hˆ0 + λHˆ ′(t) , (10.1.1) where the unperturbed Hamiltonian Hˆ0 is independent of time, whereas the perturbation Hˆ ′ may depend on time. The parameter 0 < λ < 1 has been introduced to keep track of various orders of approximations as in the case of time-independent perturbation theory discussed in Chapter 8. The basic idea is that a small perturbation to the Hamiltonian will produce a small change in the wave function. For a time-dependent perturbation, this change means that a system, initially in a particular eigenstate of Hˆ0, will find itself in a time-dependent admixture of the eigenstates. Thus the time-dependent perturbation causes the system to undergo transition to different eigenstates of Hˆ0. So for time-dependent perturbations our interest lies in calculating the probabilities for transition to different states.
The orthodox formulation of quantum theory invokes the mathematical apparatus of complex Hilbert space. In this thesis, we consider a quaternionic quantum formalism for the description of quantum states, quantum channels, and quantum measurements. We prove that probabilities for outcomes of quaternionic quantum measurements arise from canonical inner products of the corresponding quaternionic quantum effects and a unique quaternionic quantum state. We embed quaternionic quantum theory into the framework of usual complex quantum information theory. We prove that quaternionic quantum measurements can be simulated by usual complex positive operator valued measures. Furthermore, we prove that quaternionic quantum channels can be simulated by completely positive trace preserving maps on complex quantum states. We also derive a lower bound on an orthonormality measure for sets of positive semi-definite quaternionic linear operators. We prove that sets of operators saturating the aforementioned lower bound facilitate a reconciliation of quaternionic quantum theory with a generalized Quantum Bayesian framework for reconstructing quantum state spaces.
This thesis is centred around the role of non-Hermitian Hamiltonians in Physics both at the quantum and classical levels. In our investigations of two-level models we demonstrate [1] the phenomenon of fast transitions developed in the PT -symmetric quantum brachistochrone problem may in fact be attributed to the non-Hermiticity of evolution operator used, rather than to its invariance under PT operation. Transition probabilities are calculated for Hamiltonians which explicitly violate PT -symmetry. When it comes to Hilbert spaces of infinite dimension, starting with non-Hermitian Hamiltonians expressed as linear and quadratic combinations of the generators of the su(1; 1) Lie algebra, we construct [2] Hermitian partners in the same similarity class. Alongside, metrics with respect to which the original Hamiltonians are Hermitian are also constructed, allowing to assign meaning to a large class of non-Hermitian Hamiltonians possessing real spectra. The finding of exact results to establish the physical acceptability of other non-Hermitian models may be pursued by other means, especially if the system of interest cannot be expressed in terms of Lie algebraic elements. We also employ [3] a representation of the canonical commutation relations for position and momentum operators in terms of real-valued functions and a noncommutative product rule of differential form. Besides exact solutions, we also compute in a perturbative fashion metrics and isospectral partners for systems of physical interest. Classically, our efforts were concentrated on integrable models presenting PT - symmetry. Because the latter can also establish the reality of energies in classical systems described by Hamiltonian functions, we search for new families of nonlinear differential equations for which the presence of hidden symmetries allows one to assemble exact solutions. We use [4] the Painleve test to check whether deformations of integrable systems preserve integrability. Moreover we compare [5] integrable deformed models, which are thus likely to possess soliton solutions, to a broader class of systems presenting compacton solutions. Finally we study [6] the pole structure of certain real valued nonlinear integrable systems and establish that they behave as interacting particles whose motion can be extended to the complex plane in a PT -symmetric way.
The axioms of quantum mechanics require that the Hamiltonian of any closed system is self-adjoint, so that energy levels are real and time evolution preserves probability. On the other hand, non-Hermitian Hamiltonians with PT\mathcal{PT}PT symmetry can have both real spectra and unitary time evolution. In this paper, we study in detail a pair of quantum oscillators coupled by an imaginary bilinear term, both in quantum mechanics and in quantum field theory. We discuss explicitly how such Hamiltonians lead to perfectly sound physical theories with real spectra and unitary time evolution, in spite of their non-Hermiticity. We also analyze two-point correlation functions and their associated K\"allen-Lehmann representation. In particular, we discuss the intimate relation between positivity violation of the spectral functions and the nonobservability of operators in a given correlation function. Finally, we conjecture that positivity violation of some spectral functions of the theory could be a generic sign of the existence of complex pairs of energy eigenvalues (i.e., a PT\mathcal{PT}PT-broken phase) somewhere in its parameter space.