It is proposed to treat the spin of a particle phenomenologically by considering the particle as a small rotating sphere, the rotation of which is described by euler parameters. If the rotation is quantized in the space of the euler parameters, one obtains both integral and half-integral values for the spin. In this way one arrives at a formalism in which the spin components can be represented as differential operators in the Schroedinger representation.
It is proposed to treat the spin of a particle phenomenologically by considering the particle as a small rotating sphere, the rotation of which is described by euler parameters. If the rotation is quantized in the space of the euler parameters, one obtains both integral and half-integral values for the spin. In this way one arrives at a formalism in which the spin components can be represented as differential operators in the Schroedinger representation.
A system of interacting particles is treated by the methods of quantum mechanics. Among the variables the three Euler angles are introduced which give the orientation of the system as a whole in an inertial frame of reference. This allows an expansion of the Schrödinger eigenfunctions in terms of elements of irreducible representations of the rotation group. This method, originally suggested by Wigner, is extended to include particles with spin. Two and three particle systems, one particle having spin 1/2, the rest being spinless, are treated explicitly. If the two spinless particles are regarded as the core of a nucleus, the spin 1/2 particle as an extra nucleon, one can compare this “three particle nuclear model” with other nuclear models. It permits calculations of Nilsson diagrams and, compared with other models, a more straightforward adjustment of parameters to empirical data.
Rigid body rotations are described using the Cayley Klein parametrization. On quantization, the wave functions are simply polynomials in the parameters. Also, half-integral as well as integral angular momenta are allowed. The Cayley Klein parametrization provides a simple representation of both the space fixed and body fixed angular momentum operators. The construction of the allowed energies and the associated wavefunctions basically involves only algebra; no reference needs be made to the Schrödinger partial differential equations of the Euler angle parametrization.
The spin operator s = (ħ/2) σ in the Pauli equation fulfills the commutation relation of the angular momentum and leads to half-integer eigenvalues of the eigenfunctions for s. If one tries to express s by canonically conjugated operators Φ and π = (ħ/i) ∂/∂Φ the formal angular momentum term s = Φ X π fails because it leads only to whole-integer eigenvalues. However, the modification of this term in the form s = 1/2 {π + Φ(Φ π) + Φ X π} leads to the required result. The eigenfunction system belonging to this differential operator s(Φ π) consists of (2s + 1) spin eigenfunctions ξm (Φ) which are given explicitly. They form a basis for the wave functions of a particle of spin s. Applying this formalism to particles with s = 1/2, agreement is reached with Pauli’s spin theory. The function s(Φ π) follows from the theory of rotating rigid bodies. The continuous spinvariable Φ = ((Φx , Φy, Φz) can be interpreted classically as a “turning vector” which defines the orientation in space of a rigid body. Φ is the positioning coordinate of the rigid body or the spin coordinate of the particle in analogy to the cartesian coordinate x. The spin s is a vector fixed to the body.
In this second paper in a series, we show that the the general statistical approach to nonrelativistic quantum mechanics developed in the first paper yields a representation of quantum spin and magnetic moments based on classical nonrelativistic spinning top models, using Euler angle coordinates. The models allow half-odd-integer spin and predict supraluminal speeds only for electrons and other leptons, which must be treated relativistically. The spin operators in the space-fixed frame satisfy the usual commutation rules, while those in the rotating body-fixed frame satisfy "left-handed" rules. The commutation rules are independent of the structure of the top, so all nonrelativistic rigidly rotating objects must have integer or odd-half-integer spin. Physical boundary conditions restrict all mixed spin states to involve only half-odd-integer or only integer spin eigenstates. For spin 1/2, the theory automatically yields a modified Pauli-Schrödinger equation. The Hamiltonian operator in this equation contains a rigid rotator term and a term involving the square of the magmetic field, as well as an interaction term having the usual form in spherically symmetric and some cylindrically symmetric models, valid for any magnetogyric ratio.
The recently established existence of spherical harmonic functions, Yℓm(θ,ϕ) for half-odd-integer values of ℓ and m, allows for the introduction into quantum chemistry of explicit electron spin-coordinates; i.e. spherical polar angles θs,ϕs, that specify the orientation of the spin angular momentum vector in space. In this coordinate representation the spin angular momentum operators, S2,Sz, are represented by the usual differential operators in spherical polar coordinates (commonly used for L2,Lz), and their electron-spin eigenfunctions are sinθsexp(±ϕs/2). This eigenfunction representation has the pedagogical advantage over the abstract spin eigenfunctions, α,β, that ``integration over spin coordinates'' is a true integration (over the angles θs,ϕs). In addition they facilitate construction of many electron wavefunctions in which the electron spins are neither parallel nor antiparallel, but inclined at an intermediate angle. In particular this may have application to the description of EPR correlation experiments.
As part of a probabilistic reconstruction of quantum theory (QT), we show that spin is not a purely quantum mechanical phenomenon, as has long been assumed. Rather, this phenomenon occurs before the transition to QT takes place, namely in the area of the quasi-classical (here better quasi-quantum) theory. This borderland between classical physics and QT can be reached within the framework of our reconstruction by the replacement p→M(q,t), where p is the momentum variable of the particle and M(q,t) is the momentum field in configuration space. The occurrence of spin, and its special value 1/2 , is a consequence of the fact that M(q,t) must have exactly three independent components Mk(q,t) for a single particle because of the three-dimensionality of space. In the Schrödinger equation for a "particle with spin zero", the momentum field is usually represented as a gradient of a single function S. This implies dependencies between the components Mk(q,t) for which no explanation exists. In reality, M(q,t) needs to be represented by three functions, two of which are rotational degrees of freedom. The latter are responsible for the existence of spin. All massive structureless particles in nature must therefore be spin-one-half particles, simply because they have to be described by 4 real fields, one of which has the physical meaning of a probability density, while the other three are required to represent the momentum field in three-dimensional space. We derive the Pauli-Schrödinger equation, the correct value g=2 of the gyromagnetic ratio, the classical limit of the Pauli-Schrödinger equation, and clarify some other open questions in the borderland between classical physics and QT.