Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated (1+3) Ising spin chain containing two microscopic parameters: a stiff parameter K mediating the long-range interactions, and a sloppy J operating within local spin groups. We show that K dominates the macroscopic behavior, with varying J having only a weak effect, except in regions where J brings about transitions between phases through its conditioning of the local spin groups with which K interacts. We calculate the heat capacity C(H), the magnetic susceptibility χ(T), and the thermodynamic curvature R. For large |J/K|, we identify four magnetic phases: ferromagnetic, antiferromagnetic, and two ferrimagnetic, according to the signs of K and J. We argue that for characterizing these phases, the strongest picture is offered by the thermodynamic geometric invariant R, proportional to the correlation length ξ. This picture has correspondences to other cases, such as fluids.Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated (1+3) Ising spin chain containing two microscopic parameters: a stiff parameter K mediating the long-range interactions, and a sloppy J operating within local spin groups. We show that K dominates the macroscopic behavior, with varying J having only a weak effect, except in regions where J brings about transitions between phases through its conditioning of the local spin groups with which K interacts. We calculate the heat capacity C(H), the magnetic susceptibility χ(T), and the thermodynamic curvature R. For large |J/K|, we identify four magnetic phases: ferromagnetic, antiferromagnetic, and two ferrimagnetic, according to the signs of K and J. We argue that for characterizing these phases, the strongest picture is offered by the thermodynamic geometric invariant R, proportional to the correlation length ξ. This picture has correspondences to other cases, such as fluids.

arXiv:1408.2236Physical Review EJan 9, 201525 citations

Thermodynamics of Quantum Spin Systems

Masanori Ohya, Dėnes Petz

Springer eBooksJan 1, 19930 citations

Thermodynamics of Spin-1 Systems

Paul B. Slater

Feb 6, 19983 citations

Exactly solvable mixed-spin Ising-Heisenberg diamond chain with biquadratic interactions and single-ion anisotropy

Onofre Rojas, S. M. de Souza, Vadim Ohanyan +1 more

An exactly solvable variant of a mixed spin-(1/2,1) Ising-Heisenberg diamond chain is considered. Vertical spin-1 dimers are taken as quantum ones with Heisenberg bilinear and biquadratic interactions and with single-ion anisotropy, while all interactions between spin-1 and spin-1/2 residing on the intermediate sites are taken in the Ising form. The detailed analysis of the $T=0$ ground-state phase diagram is presented. The phase diagrams have been shown to be rather rich, demonstrating a large variety of ground states: a saturated one, three ferrimagnetic ones with magnetization equal to 3/5, and another four ferrimagnetic ground states with magnetization equal to 1/5. There are also two frustrated macroscopically degenerated ground states that could exist at zero magnetic filed. Solving the model exactly within a classical transfer-matrix formalism we obtain exact expressions for all thermodynamic functions of the system. The thermodynamic properties of the model have been described exactly by exact calculation of the partition function within the direct classical transfer-matrix formalism.An exactly solvable variant of a mixed spin-(1/2,1) Ising-Heisenberg diamond chain is considered. Vertical spin-1 dimers are taken as quantum ones with Heisenberg bilinear and biquadratic interactions and with single-ion anisotropy, while all interactions between spin-1 and spin-1/2 residing on the intermediate sites are taken in the Ising form. The detailed analysis of the $T=0$ ground-state phase diagram is presented. The phase diagrams have been shown to be rather rich, demonstrating a large variety of ground states: a saturated one, three ferrimagnetic ones with magnetization equal to 3/5, and another four ferrimagnetic ground states with magnetization equal to 1/5. There are also two frustrated macroscopically degenerated ground states that could exist at zero magnetic filed. Solving the model exactly within a classical transfer-matrix formalism we obtain exact expressions for all thermodynamic functions of the system. The thermodynamic properties of the model have been described exactly by exact calculation of the partition function within the direct classical transfer-matrix formalism.

arXiv:1007.0098Physical Review BMar 29, 201161 citations

Thermodynamics of quantum spin chains

Alessandro Cuccoli, V. Tognetti, Ruggero Vaia +1 more

Springer eBooksApr 7, 20080 citations

T=0

ground-state phase diagram is presented. The phase diagrams have been shown to be rather rich, demonstrating a large variety of ground states: a saturated one, three ferrimagnetic ones with magnetization equal to 3/5, and another four ferrimagnetic ground states with magnetization equal to 1/5. There are also two frustrated macroscopically degenerated ground states that could exist at zero magnetic filed. Solving the model exactly within a classical transfer-matrix formalism we obtain exact expressions for all thermodynamic functions of the system. The thermodynamic properties of the model have been described exactly by exact calculation of the partition function within the direct classical transfer-matrix formalism.