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arXiv:1408.2236 · Physical Review E

Thermodynamic curvature for a two-parameter spin model with frustration

George Ruppeiner, Stefano Bellucci A

Published Jan 9, 2015• 25 citations
arXivHTMLPDF

Abstract

Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated (1+3) Ising spin chain containing two microscopic parameters: a stiff parameter K mediating the long-range interactions, and a sloppy J operating within local spin groups. We show that K dominates the macroscopic behavior, with varying J having only a weak effect, except in regions where J brings about transitions between phases through its conditioning of the local spin groups with which K interacts. We calculate the heat capacity C(H), the magnetic susceptibility χ(T), and the thermodynamic curvature R. For large |J/K|, we identify four magnetic phases: ferromagnetic, antiferromagnetic, and two ferrimagnetic, according to the signs of K and J. We argue that for characterizing these phases, the strongest picture is offered by the thermodynamic geometric invariant R, proportional to the correlation length ξ. This picture has correspondences to other cases, such as fluids.

DOI
10.1103/physreve.91.012116

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Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated (1+3) Ising spin chain containing two microscopic parameters: a stiff parameter K mediating the long-range interactions, and a sloppy J operating within local spin groups. We show that K dominates the macroscopic behavior, with varying J having only a weak effect, except in regions where J brings about transitions between phases through its conditioning of the local spin groups with which K interacts. We calculate the heat capacity C(H), the magnetic susceptibility χ(T), and the thermodynamic curvature R. For large |J/K|, we identify four magnetic phases: ferromagnetic, antiferromagnetic, and two ferrimagnetic, according to the signs of K and J. We argue that for characterizing these phases, the strongest picture is offered by the thermodynamic geometric invariant R, proportional to the correlation length ξ. This picture has correspondences to other cases, such as fluids.
In this work we revisit the axial third-nearest-neighbor Ising chain and examine in detail some aspects of its phase behavior ensuing from competing interactions and resulting frustration. We probe the phase behavior with two complimentary tools: a microscopic two-point correlation function C(n), which we carefully construct after appropriate spin transformations, and a macroscopic, thermodynamic curvature R which we obtain from the free entropy. We report observations of phenomena such as hyperscaling breakdown and intermediate-ranged modulations among others. The zero-field thermodynamic curvature R_{0} is shown to systematically subdivide the ground-state phases into regions of attractive or repulsive effective interactions of varying strength. Furthermore, R_{0} brings forth the significance of some third-order moments in describing the effects of frustration, including the multiphase lines. Combined use of both the tools in the short-ranged modulated order regime confirms and further clarifies the discussion in [S. Khatua et al., Phys. Rev. E 111, L022105 (2025)10.1103/PhysRevE.111.L022105] regarding the appropriate measure of high temperature correlation length in this regime.
This Letter examines the full scope of long-standing conjectures identifying the invariant thermodynamic curvature R as the correlation volume ξ^{d} and also as a measure of underlying statistical interactions. To this end, we set up a two-parameter axial next nearest neighbor Ising (ANNNI) chain featuring two next nearest neighbor (nnn) and a nearest neighbor (nn) interaction. Competing interactions and resulting frustrations engender a rich phase behavior including a crossover between two ferrimagnetic subphases. We show that R attests to all its conjectured attributes with valuable physical insights into the character of mesoscopic fluctuating substructures. In a remarkable demonstration of its relevance at a far-from-critical point, R is shown to resolve a hitherto unnoticed tricky issue involving ξ. A physically transparent expression for the zero field R helps bring into focus the pivotal role played by some third order fluctuation moments.
This work examines the full scope of long-standing conjectures identifying the invariant thermodynamic curvature RRR as the correlation volume ξdξ^dξd and also as a measure of underlying statistical interactions. To this end, we set up a two-parameter ANNNI (Axial Next Nearest Neighbour Ising) chain featuring two next nearest neighbour (nnn) and a nearest neighbour (nn) interaction. Competition between interactions and resulting frustration engender a rich phase behaviour including a cross-over between two ferrimagnetic sub-phases. We show that RRR attests to all its conjectured attributes with valuable insights into the character of mesoscopic fluctuating substructures. In a remarkable demonstration of its relevance at a far-from-critical point, RRR is shown to resolve a hitherto unnoticed tricky issue involving ξξξ. A physically transparent expression for the zero field RRR helps bring into focus the pivotal role played by some third order fluctuation moments.
It has been suggested previously by the author that the correlation length $\ensuremath{\xi}$ can be calculated from the Gaussian curvature in a Riemannian geometric model of thermodynamics. In the present paper, this hypothesis is tested for the one-dimensional Ising model. It is found that for ferromagnetic interactions (J>0J>0J>0) the thermodynamic ${\ensuremath{\xi}}_{G}$ is in excellent agreement with the correlation length $\ensuremath{\xi}$ which gives the range of the exponentially decaying spin-spin correlation function G(r)G(r)G(r); ${\ensuremath{\xi}}_{G}$ and $\ensuremath{\xi}$ are never found to deviate by more than one lattice site. If J=0J=0J=0, there is no curvature, in accordance with expectations that curvature be a measure of interactions. If J<0J<0J<0, ${\ensuremath{\xi}}_{G}$ does not give the range of the envelope of the oscillatory G(r)G(r)G(r), and hence, does not agree with usual definitions of the correlation length; however, ${\ensuremath{\xi}}_{G}$ can be interpreted satisfactorily as giving the average length, due to interactions, of clusters of aligned spins. The results in this paper support the contention that thermodynamics in general contains more information than had previously been thought.
In this paper the exact solution and correlation functions for a double-chain Ising model with multi-spin interactions and symmetric Hamiltonian density are obtained. The study employs the transfer matrix method to derive fundamental thermodynamic characteristics of the system. The main results include exact expressions for the partition function, free energy, internal energy, specific heat capacity, magnetization, susceptibility, and entropy in a strip of finite length and in the thermodynamic limit. The work provides explicit formulas for the eigenvalues and shows structure of eigenvectors of the transfer matrix. The expression for magnetization in the thermodynamic limit using components of normalized eigenvector corresponding to the maximum eigenvalue is obtained. A detailed analysis is conducted for a special case of interactions involving all kinds of two- and four-spin interactions. This gives the simplified formula for free energy, it is calculated using the root of quadratic equation. Using special relation between parameters the solution for gonihedric model on the plane is obtained. The research reveals properties of the system, including specific features of ground states and phase diagram characteristics. Particular attention is given to the behavior of physical quantities near frustration points and the investigation of spin correlation functions. Plots of physical characteristics, including inverse correlation length, illustrating the obtained results are constructed.
The thermodynamics of coupled frustrated ferromagnetic chains is studied within a spin-rotation-invariant Green's-function approach. We consider an isotropic Heisenberg spin-half system with a ferromagnetic in-chain coupling J1<0{J}_{1}<0J1​<0 between nearest neighbors and a frustrating antiferromagnetic next-nearest-neighbor in-chain coupling J2>0{J}_{2}>0J2​>0. We focus on the moderate strength of frustration J2<∣J1∣/4{J}_{2}<|{J}_{1}|/4J2​<∣J1​∣/4 such that the in-chain spin-spin correlations are predominantly ferromagnetic. We consider two interchain couplings (ICs) ${J}_{\ensuremath{\perp},y}$ and ${J}_{\ensuremath{\perp},z}$, corresponding to the two axes perpendicular to the chain, where ferromagnetic as well as antiferromagnetic ICs are taken into account. We discuss the influence of frustration on the ground-state properties for antiferromagnetic ICs, where the ground state is of a quantum nature. The major part of our study is devoted to the finite-temperature properties. We calculate the critical temperature Tc{T}_{c}Tc​ as a function of the competing exchange couplings ${J}_{2},{J}_{\ensuremath{\perp},y},{J}_{\ensuremath{\perp},z}$. We find that for fixed ICs, Tc{T}_{c}Tc​ decreases monotonically with increasing frustration J2{J}_{2}J2​, where as ${J}_{2}\ensuremath{\rightarrow}|{J}_{1}|/4$ the Tc(J2){T}_{c}({J}_{2})Tc​(J2​) curve drops down rapidly. To characterize the magnetic ordering below and above Tc{T}_{c}Tc​, we calculate the spin-spin correlation functions $\ensuremath{\langle}{\mathbf{S}}_{0}{\mathbf{S}}_{\mathbf{R}}\ensuremath{\rangle}$, the magnetic order parameter MMM, the uniform static susceptibility ${\ensuremath{\chi}}_{0}$, as well as the correlation length $\ensuremath{\xi}$. Moreover, we discuss the specific heat CV{C}_{V}CV​ and the temperature dependence of the excitation spectrum ${\ensuremath{\omega}}_{\mathbf{q}}$. As ${J}_{2}\ensuremath{\rightarrow}|{J}_{1}|/4$, some unusual frustration-induced features were found, such as an increase of the in-chain spin stiffness (in the case of ferromagnetic ICs) or of the in-chain spin-wave velocity (in the case of antiferromagnetic ICs) with growing temperature.