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Journal of Magnetism and Magnetic Materials

A new scaling formulation for finite size ferromagnets

Denjoe O’Connor, Christopher Rhodes Stephens

Published Feb 1, 1992• 2 citations
Publisher
DOI
10.1016/0304-8853(92)90806-y

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Physical review. B, Condensed matter•Jul 1, 1985•179 citations
The transfer matrices for the ferromagnetic Ising model on the two- and three-dimensional lattices with finite size are formulated using the screw method introduced by Kramers and Wannier, and the largest and next largest eigenvalues of matrices are obtained by a computer. Then the specific heats and magnetic susceptibilities are calculated for each system with various sizes. By use of the finite-size scaling and Roomany-Wyld approximations, the critical exponents of the infinite-size systems are evaluated. They are in quite good agreement with the reliable ones.
We report exact results on the zero-field susceptibility \ensuremath{\chi}(T;L), the correlation length \ensuremath{\xi}(T;L), and the ``singular'' part of the specific heat c(s){\mathrm{c}}^{(\mathrm{s})}c(s) (T;L) of a finite-sized spherical model of ferromagnetism subjected to periodic boundary conditions. We take the total dimensionality of the system d to be 4 and deal with the geometry ${\mathrm{L}}^{4\mathrm{\ensuremath{-}}\mathrm{d}\ensuremath{'}}$\ifmmode\times\else\texttimes\fi{}${\mathrm{\ensuremath{\infty}}}^{\mathrm{d}\ensuremath{'}}$ (d\ensuremath{'}\ensuremath{\leqslant}2). In the region of first-order phase transition (TTc{\mathrm{T}}_{\mathrm{c}}Tc​), our results are formally the same as in other cases with d>2. The ``core'' region (T\ensuremath{\simeq}Tc{\mathrm{T}}_{\mathrm{c}}Tc​), however, is characterized by the appearance of factors involving lnL, which appear only when d=4. The relationship between these results and the corresponding ones following from the hyperscaling regime as d\ensuremath{\rightarrow}4- or from the mean-field regime as d\ensuremath{\rightarrow}4+ is explored, and a formulation in terms of the finite-size scaling theory is presented.
The finite-size rounding of a first-order transition is studied in systems representable as n-vector ferromagnets, so that O(n) symmetry (n\ensuremath{\ge}2) is broken at the bulk transition point. Both ``block,'' V=Ld{L}^{d}Ld, and ``cylinder,'' ${L}^{d\mathrm{\ensuremath{-}}1}$\ifmmode\times\else\texttimes\fi{}\ensuremath{\infty}, geometries are considered for general dimensionality d. Explicit expressions are obtained for the scaling functions describing the rounded transitions and the crossover in shape. Spin-wave effects are shown to be of relative order 1/${L}^{d\mathrm{\ensuremath{-}}2}$, and are calculated in detail in the block case. For n=3 (and d=3) this provides an extension of N\'eel's phenomenological theory of superparamagnetism. The analysis for cylinders involves the formulation of a ``degeneracy kernel'' to describe the asymptotic rounding of first-order transitions and establishes a general relation between the helicity modulus (or ``spin-wave stiffness'' or ``superfluid density'') and the transfer operator spectrum. The relationship to finite-size scaling in the critical region is examined with emphasis on the extra scaling combination, ${\mathrm{Vt}}^{2\mathrm{\ensuremath{-}}\ensuremath{\alpha}}$, that is needed for d>d>{d}_{>}d>​=4. All the results found can be checked in the limit n\ensuremath{\rightarrow}\ensuremath{\infty} against exact results for spherical models (described elsewhere).