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Journal of Mathematical Physics

Schrödinger equation with time-dependent boundary conditions

Alain Munier, J. R. Burgan, Marc Roy Feix, Eric Fijalkow

Published Jun 1, 1981• 97 citations
Publisher

Abstract

A Schrödinger equation for a well potential with varying width is studied. Generalized canonical transformations are shown to transform the problem into a time-dependent harmonic oscillator problem submitted to fixed boundary conditions. This transformed problem is solved by a perturbation technique and gives the evolution of the average energy of the system according to the motion of the well. Motions corresponding to a renormalization or compaction group are shown to be solvable by separation of variables.

DOI
10.1063/1.525033

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A Schrödinger equation for a well potential with varying width is studied. Generalized canonical transformations are shown to transform the problem into a time-dependent harmonic oscillator problem submitted to fixed boundary conditions. This transformed problem is solved by a perturbation technique and gives the evolution of the average energy of the system according to the motion of the well. Motions corresponding to a renormalization or compaction group are shown to be solvable by separation of variables.
The method of the effective Schrodinger equation applied to the one-dimensional problem of a moving particle in a potential box with a potential function and high-frequency time-dependent boundary conditions is investigated. The method of converting the initial equation written for a system with time-dependent boundary conditions to an equation describing a system in a constant region is briefly presented. The resulting system can be considered as a particle in a potential box, located in the field of some effective potential, different from the initial one. Next we consider a particular case of wall motion, with the subsequent construction of the effective Schrodinger equation. Rapid oscillations of the potential box as a whole (i.e., without changing its width) lead to an additional term in the effective equation proportional to the second derivative of the potential. This, in particular, can lead to the formation of potential wells at potential peaks in which bound states of a particle are possible. In the considered case, it was assumed that the oscillation amplitudes are small in comparison with the characteristic dimensions of the system.
The time-dependent Schrodinger problem of an oscillator .5kx*x together with the additional potential -x f(t), where f(t) is a function of time (often periodic), has already been solved in the literature (1). The solution involves a variable transformation y= x - b(t), where b(t) is a function of time which will turn out to be related to f(t) and W(x,t)= exp(i y d/dt b(t)) Wosc( y) exp(i Eosc t) . This yields an oscillator type time dependent equation with a term q(t) Wosc(y) which can be removed by using Wosc(y) exp(i c(t)). Wosc( y) is the oscillator wavefunction with the space-time variable y and Eosc the usual oscillator energy levels. Thus, by using the variable transformation together with W(x,t)=Wosc(x)exp(iEosc t) g(x,t) (i.e. a product of factors) one can obtain an “time-independent like” Schrodinger equation in y (after performing one more transformation Wosc(y)exp(i c(t)). In a previous note (2), we argued that if one writes a wavefunction as W(x)=Wo(x)q(x), where Wo(x) is the ground state wavefunction, one obtains a time-independent Schrodinger equation for Wo(x), which contains V(x), and a second eigenvalue equation coupling Wo(x) and q(x) with an eigenvalue equal to E-Eo. In particular, it is the time flux [d/dt W(x,t)]/W(x,t) which becomes linked with q(x) and the spatial flux [d/dx W(x)]/W(x). In (3), we argued that bound state quantum mechanics contains two velocities v(x), the classical velocity and u(x)/m = [d/dx W(x)]/ W(x) and that each behave differently. For example, v(x) behaves according to Newton’s law, while u(x)/m does not (except for the oscillator ground state). In this note, we try to apply these two ideas to the case of the oscillator with the time-dependent extra potential x f(t). We see that writing W(x,t) as a product (after the variable change) leads to two sets equation, one being a time-independent like equation for the oscillator and the other linking u(x)/m to a portion of time flux [d/dt W(x,t) ]/ W(x,t) |x constant. In this case, the time flux is directly related to d/dx [W*(x,t)W(x,t)] i.e. the physical density. Thus, a change in physical density in time is related to a change in physical density in space. Thus, two physical processes, it seems, are occurring. One is the W osc (y) resonance (albeit it a strange one because y=x + b(t)) and the second flux coupling with exp(i b(t) y), part of the oscillator potential and part of the additional potential -x f(t). Given that the problem has been mathematically solved already in the literature (1), our objective is to attempt to see if there is physical meaning in terms of ideas we have presented in previous notes, namely flux, the notion of a product wavefunction leading to a separate resonance type of reaction and double resonances.
We solve the Schrodinger equation analytically for systems whose potentials have a certain time-dependence (which is monotonously decreasing) and general coordinate-dependences.Only a few time-dependent systems have been reported to be analytically solved whose potentials are constant, linear, and quadratic functions of coordinate with arbitrary time-dependences.From a different perspective, we focus on the time-dependent systems whose potentials are monotonously decreasing functions of time with arbitrary coordinate dependences.Time-dependent potential of any coordinate-dependence can be handled analytically by transforming it to a time-independent potential of known solutions if its time-dependence is monotonously decreasing.We do this by a unitary transformation of the wavefunction and variable transformations to change the Schrodinger equation to be time-independent in new variables.These variables are then determined by solving a set of simple differential equations.This way we are able to find and to obtain analytical solutions for time-dependent potentials which we mention above.
A canonical transformation changes variables such as coordinates and momenta to new variables preserving either the Poisson bracket or the commutation relations depending on whether the problem is classical or quantal respectively. Classically canonical transformations are well established as a powerful tool for solving differential equations. Quantum canonical transformations have been defined and used relatively recently because of the non-commutativeness of the quantum variables. Three elementary canonical transformations and their composite transformations have quantum implementations. Quantum canonical transformations have been mostly used in time-independent Schrodinger equations and a harmonic oscillator with time-dependent angular frequency is probably the only time-dependent problem solved by these transformations. In this work, we apply quantum canonical transformations to a harmonic oscillator in which both angular frequency and equilibrium position are time-dependent.
Quantum canonical transformations corresponding to time-dependent diffeomorphisms of the configuration space are studied. A special class of these transformations which correspond to time-dependent dilatations is used to identify a previously unknown class of exactly solvable time-dependent harmonic oscillators. The Caldirola-Kanai oscillator belongs to this class. For a general time-dependent harmonic oscillator, it is shown that choosing the dilatation parameter to satisfy the classical equation of motion, one obtains the solution of the Schrödinger equation. A simple generalization of this result leads to the reduction of the Schrödinger equation to a second-order ordinary differential equation whose special case is the auxiliary equation of the Lewis-Riesenfeld invariant theory. The time-evolution operator is expressed in terms of a positive real solution of this equation in a closed form, and the time-dependent position and momentum operators are calculated.