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Optics Communications

Positions and widths of anticrossings for Cs Rydberg Stark states

Yong Li, Jianguo Rao, Baiwen Li

Published Feb 1, 1997• 4 citations
Publisher
DOI
10.1016/s0030-4018(96)00611-6

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Numerical calculations of the positions and widths for anticrossings in Rydberg Stark states are scarce, largely due to the results' sensitive dependence on the wavefunctions chosen. With wavefunctions derived from a kind of potential model as a basis, we calculate the positions and sizes for the anticrossings of potassium Rydberg states in a static electric field by means of diagonalization, and show that the results are in good agreement with available experimental data. The results show that this potential model can be used to deal with the problem of anticrossings, and the accuracy of the potential model is sensitively and numerically tested in the situation of external fields for the first time.
We have measured the avoided crossings between the Cs (n+4)s states and the lowest three members of the adjacent n Stark manifold for 20<or=n<or=24 using a novel technique based on the differences in the pulsed field ionization of the states under study. The measured positions of the avoided crossings are in excellent agreement with values calculated by matrix diagonalization, and the experimentally determined widths of the avoided crossings, which range from 29 to 78 MHz, are in reasonable agreement with the calculated values.