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Journal of Non-Crystalline Solids

Photonics glass for PHB holographic memory

Kimihiko Hirao

Published Mar 1, 1996• 31 citations
Publisher
DOI
10.1016/0022-3093(95)00552-8

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We have reported persistent spectral hole burning (PHB) in anthraquinone derivatives. 1-3) Hole burning spectroscopy desires high resolution to detect narrow and shallow holes. Laser induced grating (Holography) technique is very effective for the investigation of a shallow hole, because it enables to detect a small signal without a large background. 4-6) In addition, we can achieve many holographic applications: 3D image storage and reconstruction, holographic memory, holographic computing, etc. However, we should note that hole signal represents a diffraction efficiency in holographic detection, not the absorption spectrum. Consequently, material characteristics, hole width, depth, area, Debye-Waller factor, etc., are not directly obtainable using holographic detection.
Photochemical Hole Burning (PHB) has attracted considerable interest not only as a tool for high resolution spectroscopy of amorphous solid at low temperature but also as a possible means for freguency-domain high-density optical storage.1) Many recent investigations have been devoted to a photon-gated mechanism because it allows nondestructive readout in utilizing PHB for a practical optical memory system. The mechanisms of previously reported photon-gated PHB systems are two-step photoionization, photodecomposition, and photoinduced donor-acceptor electron transfer reactions.1)