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Physical Review A

Strong-field approximation for the Schrödinger equation

Marco Frasca

Published Jan 1, 1992• 23 citations
Publisher

Abstract

A perturbation series is derived for the Schr\"odinger equation where the perturbation is permitted to go to \ensuremath{\infty}. Such an asymptotic series can be obtained in a representation where the time evolution of the states is due to the unperturbed part of the Hamiltonian of the problem and the time evolution of the observables is determined by the perturbation, contrary to the interaction picture. The equivalence between the series given by such a picture, and an asymptotic perturbation scheme is given. The method is applied to a spin-1/2 particle in a two-component magnetic field, one component of which, considered as a perturbation, can be time varying. Choosing a constant perturbation we show the equivalence between the exact solution and the approximate one when a component of the magnetic field is much larger than the other. In this case the limit t\ensuremath{\rightarrow}\ensuremath{\infty} cannot be taken, as mixed-secular terms appear in the asymptotic series. Taking a linear time-varying dependence for a component of the magnetic field, we get a nonanalytic asymptotic series.

DOI
10.1103/physreva.45.43

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A perturbation series is derived for the Schr"odinger equation where the perturbation is permitted to go to \ensuremath{\infty}. Such an asymptotic series can be obtained in a representation where the time evolution of the states is due to the unperturbed part of the Hamiltonian of the problem and the time evolution of the observables is determined by the perturbation, contrary to the interaction picture. The equivalence between the series given by such a picture, and an asymptotic perturbation scheme is given. The method is applied to a spin-1/2 particle in a two-component magnetic field, one component of which, considered as a perturbation, can be time varying. Choosing a constant perturbation we show the equivalence between the exact solution and the approximate one when a component of the magnetic field is much larger than the other. In this case the limit t\ensuremath{\rightarrow}\ensuremath{\infty} cannot be taken, as mixed-secular terms appear in the asymptotic series. Taking a linear time-varying dependence for a component of the magnetic field, we get a nonanalytic asymptotic series.
We prove that, for a quantum system that undergoes a strong perturbation, the solution of the leading order equation of the strong field approximation (M.Frasca, Phys. Rev. A, {\bf 45}, 43 (1992)) can be derived by the adiabatic approximation. In fact, it is shown that greatest is the perturbation and more similar the quantum system is to an adiabatic one, the solution being written as a superposition of eigenstates of the time-dependent perturbation.A direct consequence of this result is that the solution of the Schrödinger equation in the interaction picture, in the same approximation for the perturbation, coincides with the one of the leading order of the strong field approximation. The limitation due to the requirement that the perturbation has to commute at different times is so overcome. Computational difficulties could arise to go to higher orders. Beside, the method is not useful for perturbations that are constant in time. In such a case a small time series is obtained, indicating that this approximation is just an application to quantum mechanics of the Kirkwood-Wigner expansion of statistical mechanics. The theory obtained in this way is applied to a time-dependent two-level spin model, already considered for the study of the Berry's phase, showing that a geometrical phase could arise if a part of the hamiltonian is considered as a strong perturbation. No adiabatic approximation is taken on the parameters of the hamiltonian, while their cyclicity is retained.
The orders of the perturbation approximation to the Schroedinger-picture time evolution operator in powers of the presumed-small perturbation part of the Hamiltonian operator are developed by the iteration of an identity; the possibly confusing switch to the interaction picture isn't needed. Those time-evolution operator approximations are sandwiched between two orthogonal, normalized eigenstates of the unperturbed part of the Hamiltonian operator to produce the transition amplitude approximations, whose calculation is reduced to quadrature when every occurrence of the perturbation part of the Hamiltonian operator in them is expanded in the unperturbed basis. That expansion also reveals the time-dependent parts of those approximations to be multiply nested integrals which in the long-time limit approach simple products of non-singular inverses (principle value plus delta function) of differences of unperturbed energy eigenvalues. Closely related to the long-time limits of transition amplitudes are the long-time averages of transition rates. When the unperturbed basis is that of free-particle states, sums over relevant final states of transition rates from an initial state, divided by the initial state's particle flux, produce cross sections. Here the perturbation approximations to generic quantum transition rates are parlayed to the corresponding approximations to differential cross sections for nonrelativistic-particle potential scattering.
We derive the integral form of the Schr\"odinger equation taking the Green function originating from the perturbation and prove the equivalence with the free representation. The equation is applied to a class of strong perturbing potentials of the form \ensuremath{\lambda}w(x)g(t) with \ensuremath{\lambda}\ensuremath{\rightarrow}\ensuremath{\infty}. The method of stationary phase applied in this case gives the first terms of an asymptotic series for the probability amplitudes to find the system in one of the states of the unperturbed Hamiltonian, and these are shown to go to zero in the considered limit.
We propose a method to describe the evolution of two spins coupled by hyperfine i nteraction in an external time- dependent magnetic field. We apply the approach to the case of hyperfine interaction with axial symmetry, which can be solved exactly in a constant, appropriately oriented magnetic field. In order to t reat t he n onstationary d ynamical p roblem, we modify the time-dependent Schrödinger equation through a change of representation that, by exploiting an instantaneous (adiabatic) basis makes the time-dependent Hamiltonian diagonal at any time instant. The solution of the transformed time-dependent Schrödinger FRVBUJPO in the form of chronologically ordered exponents with transparent pre-exponential coefficients is reported. This solution is highly simplified when an adiabatically varying magnetic field perturbs the system. The approach here proposed may be used for the perturbative treatment of other dynamical problems with no exact solution.
We develop a systematic method of operator perturbation theory in the Heisenberg picture, which is the formal analog of time-independent stationary-state perturbation theory in the Schr\"odinger picture. However, we use the eigenoperators and operator eigenfrequencies to calculate the time evolution of the dynamical variables of interest. The spectrum of the unperturbed Hamiltonian is assumed to be discrete. The method is especially well-suited for treating systems where the unperturbed Hamiltonian represents noninteracting fermions and/or bosons, and therefore, we illustrate the method using the exactly solvable model of Jaynes and Cummings: a single two-level atom interacting with a single quantized field mode. The time evolution of these operator solutions is shown to be unitary order by order in powers of the interaction strength. We find that the time evolution of exact operator solutions is well approximated for significantly longer times by the time evolution of this method's operator solutions than by the time evolution of the same operator solutions calculated using the Dyson expansion. We also demonstrate that time-dependent operator solutions are very convenient for computing quantities such as correlation functions.
The inherently homogeneous stationary-state and time-dependent Schroedinger equations are often recast into inhomogeneous form in order to resolve their solution nonuniqueness. The inhomogeneous term can impose an initial condition or, for scattering, the preferred permitted asymptotic behavior. For bound states it provides sufficient focus to exclude all but one of the homogeneous version's solutions. Because of their unique solutions, such inhomogeneous versions of Schroedinger equations have long been the indispensable basis for a solution scheme of successive perturbational corrections which are anchored by their inhomogeneous term. Here it is noted that every such perturbational solution scheme for an inhomogeneous linear vector equation spins off a nonperturbational continued-fraction scheme. Unlike its representation-independent antecedent, the spin-off scheme only works in representations where all components of the equation's inhomogeneous term are nonzero. But that requirement seems to confer theoretical physics robustness heretofore unknown: for quantum fields the order of the perturbation places a bound on unperturbed particle number, the spin-off scheme contrariwise has only basis elements of unbounded unperturbed particle number. It furthermore is difficult to visualize such a continued-fraction spin-off scheme generating infinities, since its successive iterations always go into denominators.