We apply the Lieb–Schupp method to the isotropic spin- S Hamiltonian with bilinear (− J / S 2 ) and biquadratic (− J '/ S 4 ) exchange interactions on finite lattices with reflection-symmetry to prove that finite volume ground states of the models are spin singlet in the parameter region J ' ≥ 2 S 2 J , J ' ≥ 0.
We show that the ground state of the bilinear-biquadratic exchange Hamiltonian is always singlet on a connected finite lattice with an even number of sites, while it is always triplet on one with an odd number of sites, if coefficients of the bilinear term $\ensuremath{-}J$ and that of the biquadratic term $\ensuremath{-}{J}^{\ensuremath{'}}$ satisfy the condition ${J}^{\ensuremath{'}}>J>0.$ We also find that the total-spin eigenvalue Stot of the lowest-energy state in each subspace classified by M, an eigenvalue of z component of the total spin, depends on the parity of M, i.e., Stot=∣M∣ for even M and Stot=∣M∣+1 for odd M on an even number site lattice and vice versa on an odd number site lattice.
Two quantum spin models with bilinear-biquadratic exchange interactions are constructed on the checkerboard lattice. It is proved that, under certain sufficient conditions on the exchange parameters, their ground states consist of two degenerate Shastry-Sutherland singlet configurations. The constructions are studied for arbitrary spin S. The sufficient conditions for the existence of ferromagnetic ground state are also found exactly. The approximate quantum phase diagrams are presented using the exact results, together with a variational estimate for the N\'eel antiferromagnetic phase. A two-leg spin-1∕2 ladder model, based on one of the above constructions, is considered which admits exact solution for a large number of eigenstates. The ladder model is shown to have exact level crossing between the rung-singlet state and the AKLT state in the singlet ground state. Also introduced is the notion of perpendicularity for quantum spin vectors, which appears in the discussion on one of the two checkerboard models, and is discussed in the Appendix.
An efficient valence-bond technique is introduced for the numerical study of singlet states of spin-1 antiferromagnetic chains and is applied to the general bilinear-biquadratic Hamiltonian. The results support the hypothesis that the gap first vanishes, with increasing biquadratic exchange, at the Bethe ansatz integrable point, which separates regular and dimerised regimes. The authors distinguish between real gaps and the mixing of degenerate ground states due to quantum tunnelling in small systems.