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Physical Review

Stochastic Dynamics of Quantum-Mechanical Systems

E. C. G. Sudarshan, P. M. Mathews, Jayaseetha Rau

Published Feb 1, 1961• 362 citations
Publisher

Abstract

The most general dynamical law for a quantum mechanical system with a finite number of levels is formulated. A fundamental role is played by the so-called "dynamical matrix" whose properties are stated in a sequence of theorems. A necessary and sufficient criterion for distinguishing dynamical matrices corresponding to a Hamiltonian time-dependence is formulated. The non-Hamiltonian case is discussed in detail and the application to paramagnetic relaxation is outlined.

DOI
10.1103/physrev.121.920

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The most general dynamical law for a quantum mechanical system with a finite number of levels is formulated. A fundamental role is played by the so-called "dynamical matrix" whose properties are stated in a sequence of theorems. A necessary and sufficient criterion for distinguishing dynamical matrices corresponding to a Hamiltonian time-dependence is formulated. The non-Hamiltonian case is discussed in detail and the application to paramagnetic relaxation is outlined.
For physical systems with Hamiltonians analytic in the position and momentum operators the diagonal matrix elements of the density operator in the coherent state representation may be considered as a phase-space probability measure in the stochastic formulation of quantum mechanics. The correspondence rule relating quantum-mechanical observables to ordinary functions in phase space is obtained. It is shown that the dynamics of the time-dependent phase-space probability densities is again representable in the form of a stochastic process.
This work concerns itself with the exact study of the dynamical properties of two model systems. After a brief summary of theory and concepts previous work is discussed, and this provides the motivation for the formulation of the first model. This quantum mechanical lattice model and some of its equilibrium properties are described in Chapter II. The dynamical problem to be studied is formulated in Chapter III; this is essentially the study of the time evolution (generated by the Hamiltonian) of a finite system at temperature T1 coupled to an infinite copy of itself at a temperature T2 and acting as a heat bath for the system. The problem is solved for the special case, when the coupling as scaled by the parameter γ, takes the value γ = 1. The general case for arbitrary γ values is treated in Chapter IV. It is shown that the system approaches the equilibrium state of the heat bath in a non-exponential manner, provided the spectrum of the Hamiltonian is continuous and does not have a discrete part. This result is in complete accord with the findings of other work summarised in Chapter I. The mixing properties of the model and behaviour of the relaxation rate in the weak coupling limit are studied in Chapter V. The model is shown to fail to behave as a calorimeter and in view of this result the relevance of the concept of mixing to irreversible behaviour is discussed. The main conclusions and results for the model are summarised at the end of Chapter V. The second model discussed, was first introduced by R.J. Glauber to study the dynamics of the Ising chain. The main feature here is that the time evolution is defined through a Master equation, and the associated stochastic operator. It is shown in Chapter VI that exploiting fully the free fermion character of the stochastic operator for the Glauber model, it is possible to provide a simple method to the study of the dynamics of the Ising Chain.
Stochastic methods are ubiquitous to a variety of fields, ranging from physics to economics and mathematics. In many cases, in the investigation of natural processes, stochasticity arises every time one considers the dynamics of a system in contact with a somewhat bigger system, an environment with which it is considered in thermal equilibrium. Any small fluctuation of the environment has some random effect on the system. In physics, stochastic methods have been applied to the investigation of phase transitions, thermal and electrical noise, thermal relaxation, quantum information, Brownian motion and so on. In this review, we will focus on the so-called stochastic Schrödinger equation. This is useful as a starting point to investigate the dynamics of open quantum systems capable of exchanging energy and momentum with an external environment. We discuss in some detail the general derivation of a stochastic Schrödinger equation and some of its recent applications to spin thermal transport, thermal relaxation, and Bose-Einstein condensation. We thoroughly discuss the advantages of this formalism with respect to the more common approach in terms of the reduced density matrix. The applications discussed here constitute only a few examples of a much wider range of applicability.
This paper introduces several new classes of mathematical structures that have close connections with physics and with the theory of dynamical systems. The most general of these structures, called indivisible stochastic processes, collectively encompass many important kinds of stochastic processes, including Markov chains and random dynamical systems. This paper then states and proves a new theorem that establishes a precise correspondence between any indivisible stochastic process and a unitarily evolving quantum system. This theorem therefore leads to a new formulation of quantum theory, alongside the Hilbert-space, path-integral, and quasi-probability formulations. The theorem also provides a first-principles explanation for why quantum systems are based on the complex numbers, Hilbert spaces, linear-unitary time evolution, and the Born rule. In addition, the theorem suggests that by selecting a suitable Hilbert space, together with an appropriate choice of unitary evolution, one can simulate any indivisible stochastic process on a quantum computer, thereby potentially opening up an extensive set of novel applications for quantum computing.
In this chapter we set up a classical Lagrangian and Hamiltonian dynamics for matrix models. The fundamental idea is to set up an analog of classical dynamics in which the phase space variables are non-commutative, and the basic tool that allows one to accomplish this is cyclic invariance under a trace. Since no assumptions about commutativity of the phase space variables (such as canonical commutators/anticommutators) are made at this stage, the dynamics that we set up is not the same as standard quantum mechanics. Quantum mechanical behavior will be seen to emerge only when, in Chapters 4 and 5, we study the statistical mechanics of the classical matrix dynamics formulated here. In Section 1.1, we introduce our basic notation for bosonic and fermionic matrices, and give the cyclic identities that will be used repeatedly throughout the book. In Section 1.2, we define the derivative of a trace quantity with respect to an operator, and give the basic properties of this definition. In Section 1.3, we use the operator derivative to formulate a Lagrangian and Hamiltonian dynamics for matrix models. In Section 1.4, we introduce a generalized Poisson bracket appropriate to trace dynamics, constructed from the operator derivative defined in Section 1.2, and give its properties and some applications. Finally, in Section 1.5 we discuss the relation between the trace dynamics time evolution equations, and the usual unitary Heisenberg picture equations of motion obtained when one assumes standard canonical commutators/anticommutators. Bosonic and fermionic matrices and the cyclic trace identities We shall assume finite-dimensional matrices, although ultimately an extension to the infinite-dimensional case may be needed. The matrix elements of these matrices will be constructed from ordinary complex numbers, and from complex anticommuting Grassmann numbers.