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Journal of Mathematical Physics

Continuum calculus. IV. The Laplace transform method in the evaluation of the Feynman path integrals with a Gaussian measure and applications in quantum mechanics

L. L. Lee

Published May 1, 1980• 1 citation
Publisher

Abstract

The continuum calculus, proposed earlier [J. Math. Phys. 17, 1988 (1976)], is here applied to the development of a functional version of Laplace transform and a method for the evaluation of path integrals containing a Gaussian-like measure. Two methods in functional integration are proposed. First, the Gaussian integral for polynomial functionals and consequently functionals that can be expanded in Taylor series are examined. Formula (2.12) is derived. Next, we define the Laplace transform in the function space through the weak distribution formulation of Skorohod. Comparison of both approaches enables us to determine the expression of the functional integeral through a series of Laplace transformations. The second formula is given in Eq. (4.5). The latter formula is applicable to all Laplace transformable functionals. As an illustration of the utility of the formulas derived, we evaluate the integral of a cosine functional by methods 1 and 2, and obtain consistent results. Further applications to quantum mechanics are also presented. We examine the cases of a free particle,the quantum harmonic oscillator, the forced oscillator, and charged particle in a magnetic field. In all cases, we obtain correct results in comparison with known expressions. A numerical procedure is employed in the calculation of infinite products. The usefulness of the p-integral method is stressed.

DOI
10.1063/1.524555

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The continuum calculus, proposed earlier [J. Math. Phys. 17, 1988 (1976)], is here applied to the development of a functional version of Laplace transform and a method for the evaluation of path integrals containing a Gaussian-like measure. Two methods in functional integration are proposed. First, the Gaussian integral for polynomial functionals and consequently functionals that can be expanded in Taylor series are examined. Formula (2.12) is derived. Next, we define the Laplace transform in the function space through the weak distribution formulation of Skorohod. Comparison of both approaches enables us to determine the expression of the functional integeral through a series of Laplace transformations. The second formula is given in Eq. (4.5). The latter formula is applicable to all Laplace transformable functionals. As an illustration of the utility of the formulas derived, we evaluate the integral of a cosine functional by methods 1 and 2, and obtain consistent results. Further applications to quantum mechanics are also presented. We examine the cases of a free particle,the quantum harmonic oscillator, the forced oscillator, and charged particle in a magnetic field. In all cases, we obtain correct results in comparison with known expressions. A numerical procedure is employed in the calculation of infinite products. The usefulness of the p-integral method is stressed.
Path integrals for functionals are studied from the point of view of the continuum calculus proposed earlier [J. Math. Phys. 17, 1988 (1976)]. The weak distributions of Skorohod in an infinite-dimensional Hilbert space and the p-integral method of continuum calculus are employed to derive a formula for the functional integral, which is in turn evaluated through a natural extension of the weak distribution expression. Generalizations are made to measures with density functions in the function space. As a demonstration, the formula is tested against the polynomial functionals studied by Friedrichs, and valid results are obtained for the general case.
In this paper, four distinct ideas are combined, which under a wide range of circumstances can give very rapidly converging series expansions for functional integrals. (1) Expansion of the functional being integrated in functional Taylor series. In the familiar case arising in quantum statistical mechanics, that of the Wiener integral of exp[−∫V(x(t))dt],V(x) being the perturbing potential, this is equivalent to expanding the characteristic functional of the probability functional of V(x(t)) in central moments of V(x(t)). The lowest-order term of the series is the approximation obtained by Feynman and Hibbs through a variational method. (2) Transfer of the harmonic term of the potential, when the functional integral is the quantum-statistical density matrix (Green's function of the Bloch equation), to the weighting function. This transforms the functional integral from a Wiener to an Uhlenbeck-Ornstein integral. The formal expressions for the terms of the expansion are somewhat more complicated, but they can be worked out, and the result is a great improvement in the speed of convergence of the series with decreasing temperature and/or decreasing relative magnitude of the anharmonic part of the potential. (3) ``Reservation of variables'' in the integration. This amounts to breaking the averaging process down into an average over subsets of the distributed random function (conditional average), followed by an averaging of these averages. Any step of this kind (it may be repeated within the subsets, etc.) gives an improvement of accuracy. (4) When the quantity being evaluated through functional integration is the partition function, the device introduced by Feynman and Hibbs, of interchanging the functional integration with the integration of the Green's function over the equated initial and final configuration-space points, may be combined with the above techniques. This eliminates one integration in the terms of the expansion and seems to improve accuracy at the same time. The general series obtained is correlated with more conventional operator techniques of quantum-mechanical perturbation theory, in order to answer the perennial question, does the path-integral method bring with it anything that could not be derived by other methods? It is in some sense a Feynman-Dyson expansion of the Green's function, but one that is further modified mathematically in a way characteristic only of the path-integral point of view, and which, moreover, improves its accuracy. It thus appears unlikely that the result is merely one of standard type disguised as a functional integral result. Sample numerical calculations are given to assay the accuracy of the methods, which are shown to compare very favorably with the traditional approximation of finite subdivision of the time interval.
Techniques for integration in function spaces which are not necessarily vector spaces are presented in the light of DeWitt-Morette’s recent redefinition of path integrals, which does not involve the usual limiting process, and is therefore free from the ambiguities inherent in this approach. General translated Gaussian measures defined by their Fourier transforms are introduced on various path spaces and used to derive generalized moments formulas, and what is essentially the Feynman–Kac formula for the expression of solutions of the Schrödinger equation as functional integrals.
Operator calculusThe operator calculus developed by Feynman [Fey51] makes it possible to represent functions of (noncommuting) operators as path integrals, with the integrand being the path-ordered exponential of operators, the order of which is controlled by a parameter that varies along the trajectory.This procedure is termed Feynman disentangling.It is also applicable to functions of matrices (say, γ-matrices which are associated with a spinor particle).When applied to the evolution operator, this procedure results in the standard path-integral representation of quantum mechanics.In this chapter we first demonstrate the general technique using the simplest example, a free propagator in Euclidean space, and then consider the path-integral representation of quantum mechanics, as well as propagators in an external electromagnetic field. Free propagatorLet us first consider the simplest propagator of a free scalar field which is given in the operator formalism by the vacuum expectation value of thewith ϕ being the field-operator.The T -product (1.1) obeys the equationwhere d = 4 is the dimension of space-time, however the formulas are applicable at any value of d.In the operator formalism, Eq. (1.2) is a * The ordered products of operators were introduced by Dyson [Dys49].This paper and other classical papers on quantum electrodynamics are collected in the book edited by Schwinger [Sch58].
A direct procedure for determining the propagator associated with a quantum mechanical problem was given by the Path Integration Procedure of Feynman.The Green function, which is the Fourier Transform with respect to the time variable of the propagator, can be derived later.In our approach, with the help of a Laplace transform, a direct way to get the energy dependent Green function is presented, and the propagator can be obtained later with an inverse Laplace transform.The method is illustrated through simple one dimensional examples and for time independent potentials, though it can be generalized to the derivation of more complicated propagators.
Abstract The focus of Chapter 12 is the Feynman path integral formulations of quantum mechanics and quantum statistical mechanics. The connection between real-time quantum propagator and the density matrix is established via the Wick rotation, and a Trotter expansion is used to derive discrete path integral expressions for both. The continuous limit of the discrete path integral is derived to yield the functional integral formulation of the path integral. The construction of estimators and their averages for computing quantum observables is discussed. Next, the path integral is extended to incorporate Boltzmann, Fermi-Dirac, and Bose-Einstein statistics, and a useful recursive formula for the partition function is derived that accelerates convergence by building up N-body partition functions from those of smaller systems. Quantum free energies are discussed, and algorithms for the evaluation of path integrals using molecular dynamics or Monte Carlo are presented. The chapter concludes with a discussion of higher-order factorizations and ring-polymer contraction methods to reduce the computational overhead of path-integral calculations