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Journal of Mathematical Physics

On path integral solutions of the Schrödinger equation, without limiting procedure

Maurice M. Mizrahi

Published Apr 1, 1976• 55 citations
Publisher

Abstract

Techniques for integration in function spaces which are not necessarily vector spaces are presented in the light of DeWitt-Morette’s recent redefinition of path integrals, which does not involve the usual limiting process, and is therefore free from the ambiguities inherent in this approach. General translated Gaussian measures defined by their Fourier transforms are introduced on various path spaces and used to derive generalized moments formulas, and what is essentially the Feynman–Kac formula for the expression of solutions of the Schrödinger equation as functional integrals.

DOI
10.1063/1.522945

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arXiv:quant-ph/9703031•Mar 18, 1997•0 citations
Techniques for integration in function spaces which are not necessarily vector spaces are presented in the light of DeWitt-Morette’s recent redefinition of path integrals, which does not involve the usual limiting process, and is therefore free from the ambiguities inherent in this approach. General translated Gaussian measures defined by their Fourier transforms are introduced on various path spaces and used to derive generalized moments formulas, and what is essentially the Feynman–Kac formula for the expression of solutions of the Schrödinger equation as functional integrals.
The Schrödinger equation is fundamental in quantum mechanics as it makes it possible to determine the wave function from energies and to use this function in the mean calculation of variables, for example, as the most likely position of a group of one or more massive particles. In this paper, we present a survey on some theories involving the Schrödinger equation and the Feynman path integral. We also consider a Feynman–Kac-type formula, as introduced by Patrick Muldowney, with the Henstock integral in the description of the expectation of random walks of a particle. It is well known that the non-absolute integral defined by R. Henstock “fixes” the defects of the Feynman integral. Possible applications where the potential in the Schrödinger equation can be highly oscillating, discontinuous or delayed are mentioned in the end of the paper.
In 1948, Richard Feynman published the first paper on his new approach to non-relativistic quantum mechanics. Before Feynman's work there were two mathematical formulations of quantum mechanics. Schrödinger's formulation was based on PDE (the Schrödinger equation) and states representation by wave functions, so it was in the framework of analysis and differential equations. The other formulation was Heisenberg's matrix algebra. Initially, they were thought to be competing. The proponents of one claimed that the other was “ wrong. ” Within a couple of years, John von Neumann had proved that they are equivalent.\nAlthough Feynman's theory was not fundamentally new, it nonetheless offered an entirely fresh and different perspective: via a precise formulation of Bohr's correspondence principle, it made quantum mechanics similar to classical mechanics in a precise sense. In addition, Feynman's approach made it possible to explain physical experiments, and, via diagrams, link them directly to computations. What resulted was a very powerful device for computing energies and scattering amplitudes - the famous Feynman's diagrams.\nIn his formulation, Feynman aimed at representing the solution to the non-relativistic Schrödinger equation in the form of an “ average ” over histories or paths of a particle. This solution is commonly known as the Feynman path integral. It plays an important role in the theory but appears as a postulate based on intuition coming from physics rather than a justified mathematical object. This is why Feynman's vision has caught the attention of many mathematicians as well as physicists.\nThe papers of Gelfand, Cameron, and Nelson are among the first, and more substantial, attempts to supply Feynman's theory with a rigorous mathematical foundation. These attempts were followed by many others, but unfortunately all of them were not quite satisfactory. The difficulty comes from a need to define a measure on an infinite-dimensional space of continuous functions that represent all possible paths of a particle. This Feynman's measure has to produce an integral with the properties requested by Feynman. In particular, the expression for the Feynman measure has to involve the non-absolutely integrable Fresnel integrands. The non-absolute integrability of the Fresnel integrands makes the measure fail to be positive and to have the countably additive property. Thus, a well-defined measure in the case of the Feynman path integral does not exist.\nExtensive research has been done on the methods of relating the Feynman path integral to the integral with respect to the Wiener measure. The method of analytic continuation in mass defines the Feynman path integral as a certain limit of the Wiener integrals. Unfortunately, this method can be used as definition for only almost all values of the mass parameter in the Schrödinger equation. For physicists, this is not a satisfactory result and needs to be improved.\nIn this work we examine those questions which originally led to the Feynman path integral. By now we know that Feynman's “ dream ” cannot be realized as a positive and countably additive measure on the path-space. Here, we offer a new way out by modifying Feynman's question, and thereby achieving a solution to the Schrödinger equation via a different kind of averages in the path-space.\nWe give our version of the question that Feynman “ should have asked ” in order to realize the elusive path integral. In our formulation, we get a Feynman path integral as a limit of linear functionals, as opposed to the more familiar inductive limits of positive measures, traditionally used for constructing the Wiener measure, and related Gaussian families. We adapt here an approach pioneered by Patrick Muldowney. In it, Muldowney suggested a Henstock integration technique in order to deal with the non-absolute integrability of the kind of Fresnel integrals which we need in our solution to Feynman's question. By applying Henstock's theory to Fresnel integrals, we construct a complex-valued “ probability distribution functions ” on the path-space. Then we use this “ probability ” distribution function to define the Feynman path integral as an inductive limit. This establishes a mathematically rigorous Feynman limit, and at the same time, preserves Feynman's intuitive idea in resulting functional. In addition, our definition, and our solution, do not place any restrictions on any of the parameters in the Schrödinger equation, and have a potential to offer useful computational experiments, and other theoretical insights.
A nonstandard path space * -measure is constructed to justify the path integral formula for the Dirac equation in two-dimensional space–time. A standard measure as well as a standard path integral is obtained from it. We also show that, even for the Schrödinger equation, for which there is no standard measure appropriate for a path integral, there exists a nonstandard measure to define a * -path integral whose standard part agrees with the ordinary path integral as defined by a limit from time-slice approximant.
A generalized Feynman-Kac formula based on the Wiener measure is presented. Within the setting of a quantum particle in an electromagnetic field it yields the standard Feynman-Kac formula for the corresponding Schrödinger semigroup. In this case rigorous criteria for its validity are compiled. Finally, phase-space path-integral representations for more general quantum Hamiltonians are derived. These representations rely on a generalized Lie-Trotter formula which takes care of the operator-ordering multiplicity, but in general is not related to a path measure.