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Physical Review A

Construction of exactly soluble double-well potentials

Ariel Caticha

Published May 1, 1995• 19 citations
Publisher

Abstract

Solving the tunneling problem in a double-well potential requires knowing the wave function not just of the ground state, but also of the first excited state. A method is described that allows one to construct potentials together with these two wave functions. No approximations are made. To illustrate the method several examples are given. These include potentials that either diverge for large \ensuremath{\Vert}x\ensuremath{\Vert} or become asymptotically flat, with one or two wells, which may be symmetric or asymmetric.

DOI
10.1103/physreva.51.4264

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Solving the tunneling problem in a double-well potential requires knowing the wave function not just of the ground state, but also of the first excited state. A method is described that allows one to construct potentials together with these two wave functions. No approximations are made. To illustrate the method several examples are given. These include potentials that either diverge for large \ensuremath{\Vert}x\ensuremath{\Vert} or become asymptotically flat, with one or two wells, which may be symmetric or asymmetric.
An asymmetric double-well potential is considered, assuming that the minima of the wells are quadratic with a frequency ω and the difference of the minima is close to a multiple of �ω. A WKB wave function is constructed on both sides of the local maximum between the wells, by matching the WKB function to the exact wave functions near the classical turning points. The continuities of the wave function and its first derivative at the local maximum then give the energy-level splitting formula, which not only reproduces the instanton result for a symmetric potential, but also elucidates the appearance of resonances of tunneling in the asymmetric potential. Key words: quantum tunneling, energy splitting, double-well potential PACS: 03.65.Sq, 03.65.Ge, 82.20.Xr 1
The double-well potential is arguably one of the most important potentials in quantum mechanics, because the solution contains the notion of a state as a linear superposition of 'classical' states, a concept which has become very important in quantum information theory. It is therefore desirable to have solutions to simple double-well potentials that are accessible to the undergraduate student. We describe a method for obtaining the numerically exact eigenenergies and eigenstates for such a model, along with the energies obtained through the Wentzel–Kramers–Brillouin (WKB) approximation. The exact solution is accessible with elementary mathematics, though numerical solutions are required. We also find that the WKB approximation is remarkably accurate, not just for the ground state, but also for the excited states.
For an asymmetric double-well potential system, it is shown that, if the potential is quadratic until it reaches several times of the zero-point energies from the bottoms in each well, the energy eigenvalues of the low lying excited states of the double-well system must be close to the eigenvalues of the quadratic potentials. These eigenvalue structures suggest a method for the coherent control of the tunneling as well as realizing almost complete localization of the wave packet in one of the wells, by handling the double-well asymmetry. Numerical examples are included to indicate that the method could be useful also in a more general potential, and to propose experimental confirmations.