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Journal of Physics A Mathematical and Theoretical

Equilibration and asymptotic stationarity for non-Markovian master equations

Joshua Wilkie, Yin Mei Wong

Published Jun 7, 2011• 2 citations
Publisher

Abstract

We show that certain positivity-preserving non-Markovian generalizations of the Kossakowski–Lindblad master equation can exhibit equilibration to an asymptotic state which is stationary with respect to the shifted system Hamiltonian for general system–bath coupling. This is in sharp contrast to results for Markovian forms which require strong relations between these operators (e.g. commutation of isolated system Hamiltonian and coupling operator). We also expand the list of sufficient conditions for positivity of non-Markovian master equations.

DOI
10.1088/1751-8113/44/27/275306

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We show that certain positivity-preserving non-Markovian generalizations of the Kossakowski–Lindblad master equation can exhibit equilibration to an asymptotic state which is stationary with respect to the shifted system Hamiltonian for general system–bath coupling. This is in sharp contrast to results for Markovian forms which require strong relations between these operators (e.g. commutation of isolated system Hamiltonian and coupling operator). We also expand the list of sufficient conditions for positivity of non-Markovian master equations.
Positivity preservation is naturally guaranteed in exact non-Markovian master equations for open quantum system dynamics. However, in many approximated non-Markovian master equations, the positivity of the reduced density matrix is not guaranteed. In this paper we provide a general class of time-local, perturbative, and positivity-preserving non-Markovian master equations generated from stochastic Schr\"odinger equations, particularly quantum-state-diffusion equations. Our method has an expanded range of applicability for accommodating a variety of non-Markovian environments. We show the positivity-preserving master equation for a three-level system coupled to a dissipative bosonic environment as a particular example to exemplify our general approach. We illustrate the numerical simulations with an analysis explaining why the previous approximated non-Markovian master equations cannot guarantee positivity. Our work provides a consistent master equation for studying the non-Markovian dynamics in ultrafast quantum processes and strong-coupling systems.
We investigate the long-time behavior of quantum Markovian dynamics generated by time-dependent Gorini–Kossakowski–Lindblad–Sudarshan (GKLS) master equations. We introduce a notion of weak relaxation and derive sufficient conditions guaranteeing asymptotic independence from the initial state. Our results provide a quantitative extension of the Spohn–Frigerio theorem to time-dependent generators, yielding explicit contraction bounds in terms of the instantaneous steady state and the jump operators. For a class of microscopically derived master equations, we further obtain a graph-theoretic characterization of the aforementioned conditions that directly links the structure of the jump operators to the relaxation properties. The general theory is illustrated by applications to driven finite-level systems, including a detailed three-level example, and is extended to a non-Markovian setting by means of time-local master equations that become of GKLS form at long times. These findings pave the way for the development of a more general theory of relaxation beyond the Markovian case.
We use basic physical motivations to develop sufficient conditions for positive semidefiniteness of the reduced density matrix for generalized non-Markovian integrodifferential Lindblad–Kossakowski master equations with Hermitian generators. We show that it is sufficient for the memory function to be the Fourier transform of a real positive symmetric frequency density function with certain properties. These requirements are physically motivated, and are more general and more easily checked than previously stated sufficient conditions. We also explore the decoherence dynamics numerically for some simple models using the Hadamard representation of the propagator. We show that the sufficient conditions are not necessary conditions. We also show that models exist in which the long time limit is in part determined by non-Markovian effects.
We investigate a case of the Hu-Paz-Zhang master equation of the Caldeira-Leggett model without Lindblad form obtained in the weak-coupling limit up to the second-order perturbation. In our study, we use Gaussian initial states to be able to employ a sufficient and necessary condition, which can expose positivity violations of the density operator during the time evolution. We demonstrate that the evolution of the non-Markovian master equation has problems when the stationary solution is not a positive operator, i.e., does not have physical interpretation. We also show that solutions always remain physical for small times of evolution. Moreover, we identify a strong anomalous behavior, when the trace of the solution is diverging. We also provide results for the corresponding Markovian master equation and show that positivity violations occur for various types of initial conditions even when the stationary solution is a positive operator. Based on our numerical results, we conclude that this non-Markovian master equation is superior to the corresponding Markovian one.
Determining the Markovianity and non-Markovianity of a quantum process is a critical problem in the theory of open quantum systems, as their behaviors differ significantly in terms of complexity. It is well recognized that a quantum process is Markovian if and only if the quantum master equation can be written in the standard Lindblad form with all rates nonnegative for all time. However, here we present a striking result that \textit{any} finite-dimensional open quantum system dynamics can be described by a quantum master equation in the Lindblad form with all rates nonnegative for all time. In fact, it can be shown that one can arbitrarily decide the sign of the rates in any case at any time interval. Note that here we take an unconventional approach where the quantum master equation we construct will in general be state-dependent, which means that the Hamiltonian, jump operators and rates will all depend on the current state of the density matrix ρ(t)ρ(t)ρ(t). Our findings raise serious questions on the current criterion in determining Markovianity and non-Markovianity in open quantum system dynamics.
Master equations govern the time evolution of a quantum system interacting with an environment, and may be written in a variety of forms. Time-independent or memoryless master equations, in particular, can be cast in the well-known Lindblad form. Any time-local master equation, Markovian or non-Markovian, may in fact also be written in a Lindblad-like form. A diagonalization procedure results in a unique, and in this sense canonical, representation of the equation, which may be used to fully characterize the non-Markovianity of the time evolution. Recently, several different measures of non-Markovianity have been presented which reflect, to varying degrees, the appearance of negative decoherence rates in the Lindblad-like form of the master equation. We therefore propose using the negative decoherence rates themselves, as they appear in the canonical form of the master equation, to completely characterize non-Markovianity. The advantages of this are especially apparent when more than one decoherence channel is present. We show that a measure proposed by Rivas et al. [Phys. Rev. Lett. 105, 050403 (2010)] is a surprisingly simple function of the canonical decoherence rates, and give an example of a master equation that is non-Markovian for all times t>0t>0t>0, but to which nearly all proposed measures are blind. We also give necessary and sufficient conditions for trace distance and volume measures to witness non-Markovianity, in terms of the Bloch damping matrix.