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Physica Scripta

Two-photon two-color diode laser spectroscopy of the Rb 5D5/2state

Timothy T. Grove, V. Sánchez-Villicaña, B C Duncan, S. Maleki, P. L. Gould

Published Sep 1, 1995• 73 citations
Publisher

Abstract

We report on spectroscopic measurements of the Rb 5 D 5/2 state performed using two-photon excitation with a resonant intermediate state. With the two beams (5 S 1/2 → 5 P 3/2 at 780 nm and 5 P 3/2 → 5 D 5/2 at 776 nm) counterpropagating, the spectra are Doppler-free and the signals are very robust, even in a room temperature vapor. This is due to the near match of the transition wavelengths. The 5 D 5/2 hyperfine constants have been measured and compared to previous determinations. We have also performed the excitation in a sample of laser-cooled atoms and compare these results to those obtained at room temperature. The fact that the 5 P 3/2 → 5 D 5/2 transition is narrow, robust, diode-laser accessible, and relatively immune to AC-Stark shifts, may make it a promising candidate for a frequency reference at 776 nm.

DOI
10.1088/0031-8949/52/3/008

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Abstract We analyze an optical atomic clock using two-photon 5 S 1 / 2 → 4 D J transitions in rubidium. Four one- and two-color excitation schemes to probe the 4 D 3 / 2 and 4 D 5 / 2 fine-structure states are considered in detail. We compare key characteristics of Rb 4 D J and 5 D 5 / 2 two-photon clocks. The 4 D J clock features a high signal-to-noise ratio due to two-photon decay at favorable wavelengths, low dc electric and magnetic susceptibilities, and minimal black-body shifts. Ac Stark shifts from the clock interrogation lasers are compensated by two-color Rabi-frequency matching. We identify a ‘magic’ wavelength near 1060 nm, which allows for in-trap, Doppler-free clock-transition interrogation with lattice-trapped cold atoms. From our analysis of clock statistics and systematics, we project a quantum-noise-limited relative clock stability at the 10 − 13 / τ ( s ) -level, with integration time τ in seconds, and a relative accuracy of ∼ 10 − 13 . We describe a potential architecture for implementing the proposed clock using a single telecom clock laser at 1550 nm, which is conducive to optical communication and long-distance clock comparisons. Our work could be of interest in efforts to realize small and portable Rb clocks and in high-precision measurements of atomic properties of Rb 4 D J -states.

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Absolute hyperfine energy levels and isotope shift of Rb 5S–6S two-photon transition

Seth Orson, Carson McLaughlin, M. D. Lindsay +1 more

Abstract Using a Rb cell and a wavemeter, with a Doppler-free two-photon transition near 993 nm, we have measured the four hyperfine components (two isotopes, Δ F = 0) of the 5S–6S transition, finding the absolute energies of those transitions to a spectral resolution of 0.002 cm −1 = 60 MHz. We find the (87 minus 85) isotope shift of the 5S–6S transition to be +94(12) MHz. Using our single frequency cw laser with focused intensity up to 10 4 W cm −2 at the cell, we find no AC Stark or light shift of the lines at 6 MHz spectral resolution. We find no density shift of the lines at 6 MHz spectral resolution, for a range of Rb atom densities from 3 × 10 11 to 5 × 10 13 atoms/cm 3 .

Journal of Physics B Atomic Molecular and Optical Physics•Sep 8, 2021•4 citations
We report on spectroscopic measurements of the Rb 5 D 5/2 state performed using two-photon excitation with a resonant intermediate state. With the two beams (5 S 1/2 → 5 P 3/2 at 780 nm and 5 P 3/2 → 5 D 5/2 at 776 nm) counterpropagating, the spectra are Doppler-free and the signals are very robust, even in a room temperature vapor. This is due to the near match of the transition wavelengths. The 5 D 5/2 hyperfine constants have been measured and compared to previous determinations. We have also performed the excitation in a sample of laser-cooled atoms and compare these results to those obtained at room temperature. The fact that the 5 P 3/2 → 5 D 5/2 transition is narrow, robust, diode-laser accessible, and relatively immune to AC-Stark shifts, may make it a promising candidate for a frequency reference at 776 nm.
Accessing the 5S1/2→5D5/2\rm 5S_{1/2} \rightarrow 5D_{5/2}5S1/2​→5D5/2​ two-photon transition in Rb using a diode laser system
We report observation of the 5S1/2→5D5/2\rm 5S_{1/2} \rightarrow 5D_{5/2}5S1/2​→5D5/2​ two-photon transition in Rb vapor at 778 nm, using an external cavity diode laser system and a heated vapor cell. The spectra in the two isotopes show well-resolved hyperfine transitions. The peaks are Doppler free, and have a Lorentzian lineshape with a typical linewidth of 2.2 MHz. This linewidth is larger than the natural linewidth of 300 kHz, but is still 5--10 times smaller than the linewidth for single-photon transitions in the D2_22​ line. Since the absolute frequency of this transition is measured with 8 kHz precision, it can form a better secondary reference in the optical regime compared to the D2_22​ line.
Abstract We report a measurement of the hyperfine-structure constants of the 85Rb 4 D 3 / 2 state using two-photon optical spectroscopy of the 5 S 1 / 2 → 4 D 3 / 2 transition. The spectra are acquired by measuring the transmission of the low-power 795 nm lower-stage laser beam through a cold-atom sample as a function of laser frequency, with the frequency of the upper-stage, 1476 nm laser fixed. All 4 hyperfine components of the 4 D 3 / 2 state are well-resolved in the experimental data. The dominant systematic is the light shift from the 1476 nm laser, which is addressed by extrapolating line positions measured for a set of 1476 nm laser powers to zero laser power. The analysis of our experimental data yields both the magnetic-dipole and electric-quadrupole constants for the 85Rb 4 D 3 / 2 level, without using earlier hyperfine measurements of other atomic levels. The respective results, A = 7.419(35) MHz and B = 4.19(19) MHz, are discussed in context with previous works. Our investigation may be useful for optical atomic clocks for precision metrology and emerging atom-based quantum technologies, all-infrared excitation of Rb Rydberg levels, and molecular physics.
Abstract We analyze an optical atomic clock using two-photon 5 S 1 / 2 → 4 D J transitions in rubidium. Four one- and two-color excitation schemes to probe the 4 D 3 / 2 and 4 D 5 / 2 fine-structure states are considered in detail. We compare key characteristics of Rb 4 D J and 5 D 5 / 2 two-photon clocks. The 4 D J clock features a high signal-to-noise ratio due to two-photon decay at favorable wavelengths, low dc electric and magnetic susceptibilities, and minimal black-body shifts. Ac Stark shifts from the clock interrogation lasers are compensated by two-color Rabi-frequency matching. We identify a ‘magic’ wavelength near 1060 nm, which allows for in-trap, Doppler-free clock-transition interrogation with lattice-trapped cold atoms. From our analysis of clock statistics and systematics, we project a quantum-noise-limited relative clock stability at the 10 − 13 / τ ( s ) -level, with integration time τ in seconds, and a relative accuracy of ∼ 10 − 13 . We describe a potential architecture for implementing the proposed clock using a single telecom clock laser at 1550 nm, which is conducive to optical communication and long-distance clock comparisons. Our work could be of interest in efforts to realize small and portable Rb clocks and in high-precision measurements of atomic properties of Rb 4 D J -states.
Abstract We report an experimental investigation of the 5 S 1/2 –7 S 1/2 one-color two-photon transition in rubidium vapor with a single continuous-wave laser operating at 760 nm. By utilizing a robust intensity modulation method, high-resolution spectra with a signal-to-noise ratio of ~120 are obtained. A perfect match between experimental results and the theoretical analysis is obtained by characterizing the probability of a two-photon transition with vapor temperature and laser power. Moreover, the influence of electric dipole selection rules on the two-photon transition is also investigated by changing the polarization of the laser beam. Since the 5 S 1/2 –7 S 1/2 two-photon transition is insensitive to stray magnetic fields and has an extremely narrow linewidth, we confidently believe that it can provide a concrete frequency standard for quantum telecommunication in the S -band window (1480–1530 nm). Meanwhile, the atomic system at 760 nm will serve as a good candidate for a quantum repeater.
Direct evidence of excitation of the $5{p}_{3/2}\ensuremath{\rightarrow}6{p}_{3/2}$ electric-dipole-forbidden transition in atomic rubidium is presented. The experiments were performed in a room-temperature rubidium cell with continuous-wave external cavity diode lasers. Optical-optical double-resonance spectroscopy with counterpropagating beams allows the detection of the nondipole transition free of Doppler broadening. The 5p3/25{p}_{3/2}5p3/2​ state is prepared by excitation with a laser locked to the maximum FFF cyclic transition of the D2{D}_{2}D2​ line, and the forbidden transition is produced by excitation with a 911 nm laser. Production of the forbidden transition is monitored by detection of the 420 nm fluorescence that results from decay of the 6p3/26{p}_{3/2}6p3/2​ state. Spectra with three narrow lines ($\ensuremath{\approx}13$ MHz FWHM) with the characteristic $F\ensuremath{-}1, F$, and F+1F+1F+1 splitting of the 6p3/26{p}_{3/2}6p3/2​ hyperfine structure in both rubidium isotopes were obtained. The results are in very good agreement with a direct calculation that takes into account the $5s\ensuremath{\rightarrow}5{p}_{3/2}$ preparation dynamics, the $5{p}_{3/2}\ensuremath{\rightarrow}6{p}_{3/2}$ nondipole excitation geometry, and the $6{p}_{3/2}\ensuremath{\rightarrow}5{s}_{1/2}$ decay. The comparison also shows that the electric-dipole-forbidden transition is a very sensitive probe of the preparation dynamics.
Abstract Using a Rb cell and a wavemeter, with a Doppler-free two-photon transition near 993 nm, we have measured the four hyperfine components (two isotopes, Δ F = 0) of the 5S–6S transition, finding the absolute energies of those transitions to a spectral resolution of 0.002 cm −1 = 60 MHz. We find the (87 minus 85) isotope shift of the 5S–6S transition to be +94(12) MHz. Using our single frequency cw laser with focused intensity up to 10 4 W cm −2 at the cell, we find no AC Stark or light shift of the lines at 6 MHz spectral resolution. We find no density shift of the lines at 6 MHz spectral resolution, for a range of Rb atom densities from 3 × 10 11 to 5 × 10 13 atoms/cm 3 .