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Physical Review Letters

Quantum Superchemistry: Dynamical Quantum Effects in Coupled Atomic and Molecular Bose-Einstein Condensates

J. J. Hope, M. K. Olsen

Published Apr 9, 2001• 110 citations
Publisher

Abstract

We show that in certain parameter regimes there is a macroscopic dynamical breakdown of the Gross-Pitaevskii equation. Stochastic field equations for coupled atomic and molecular condensates are derived using the functional positive- P representation. These equations describe the full quantum state of the coupled condensates and include the commonly used Gross-Pitaevskii equation as the noiseless limit. The full quantum theory includes the spontaneous processes which will become significant when the atomic population is low. The experimental signature of the quantum effects will be the time scale of the revival of the atomic population after a near total conversion to the molecular condensate.

DOI
10.1103/physrevlett.86.3220

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We show that in certain parameter regimes there is a macroscopic dynamical breakdown of the Gross-Pitaevskii equation. Stochastic field equations for coupled atomic and molecular condensates are derived using the functional positive- P representation. These equations describe the full quantum state of the coupled condensates and include the commonly used Gross-Pitaevskii equation as the noiseless limit. The full quantum theory includes the spontaneous processes which will become significant when the atomic population is low. The experimental signature of the quantum effects will be the time scale of the revival of the atomic population after a near total conversion to the molecular condensate.
This paper examines the parameter regimes in which coupled atomic and molecular Bose-Einstein condensates do not obey the Gross-Pitaevskii equation. Stochastic field equations for coupled atomic and molecular condensates are derived using the functional positive-PPP representation. These equations describe the full quantum state of the coupled condensates and include the commonly used Gross-Pitaevskii equation as the noiseless limit. The model includes all interactions between the particles, background gas losses, two-body losses, and the numerical simulations are performed in three dimensions. It is found that it is possible to differentiate the quantum and semiclassical behavior when the particle density is sufficiently low and the coupling is sufficiently strong.
We study the dynamics of the atomic and molecular Bose-Einstein condensates (BECs) of 87Rb^{87}\text{R}\text{b}87Rb in a spherically symmetric trap coupled by stimulated Raman photoassociation process. Considering the higher order nonlinearity in the atom-atom interaction we analyze the dynamics of the system using coupled modified Gross-Pitaevskii (MGP) equations and compare it with mean-field coupled Gross-Pitaevskii (GP) dynamics. Considerable differences in the dynamics are obtained in these two approaches at large scattering length, i.e., for large values of peak-gas parameter ${x}_{pk}\ensuremath{\ge}{10}^{\ensuremath{-}3}$. We show how the dynamics of the coupled system is affected when the atom-molecule and molecule-molecule interactions are considered together with the atom-atom interaction and also when the strengths of these three interactions are increased. The effect of detuning on the efficiency of conversion of atomic fractions into molecules is demonstrated and the feasibility of maximum molecular BEC formation by varying the Raman detuning parameter at different values of time is explored. Thus by varying the Raman detuning and the scattering length for atom-atom interaction one can control the dynamics of the coupled atomic-molecular BEC system. We have also solved coupled Gross-Pitaevskii equations for atomic to molecular condensate formation through magnetic Feshbach resonance in a BEC of 85Rb^{85}\text{R}\text{b}85Rb. We found similar features for oscillations between atomic and molecular condensates noted in previous theoretical study and obtained fairly good agreement with the evolution of total atomic condensate observed experimentally.
We use numerical integration of coupled differential equations in a truncated Wigner representation to show that the initial quantum state of an atomic Bose-Einstein condensate plays an important role in the process of Raman photoassociation to form a molecular condensate. Comparing the predictions for different initial quantum states, we find that, even when the stochastic prediction for an initial coherent state is close to the Gross-Pitaevskii prediction, other possible states may result in very different dynamics. The mean-field dynamics can be appreciably different, depending on the initial conditions.
An atomic Bose-Einstein condensate (BEC) is often described as a macroscopic object which can be approximated by a coherent state. This, on the surface, would appear to indicate that its behavior should be close to being classical. In this paper, we clarify the extent of how "classical" a BEC is by exploring the semiclassical equations for BECs under the mean field Gaussian approximation. Such equations describe the dynamics of a condensate in the classical limit in terms of the variables < x > and < p > as well as their respective variances. We compare the semiclassical solution with the full quantum solution based on the Gross-Pitaevskii Equation (GPE) and find that the interatomic interactions which generate nonlinearity make the system less "classical." On the other hand, many qualitative features are captured by the semiclassical equations, and the equations to be solved are far less computationally intensive than solving the GPE which make them ideal for providing quick diagnostics, and for obtaining new intuitive insight.
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Quantum phenomena appear in a macroscopic scale in Bose-Einstein condensates. The Gross-Pitaevskii (GP) equation describes the dynamics of the weakly interacting Bose-Einstein condensates. The GP equation has a form of the Schroedinger equation with self-interaction. The coupled Gross-Pitaevskii equations are used to describe some mixtures of Bose-Einstein condensates. In this paper, we will show some numerical results of coupled Gross-Pitaevskii equations without self-interaction, which has a form of nonlinearly-coupled Schroedinger equations. We demonstrate that the macroscopic oscillation and the interference of two quantum wave packets decay in time owing to mutual interaction, which is analogous to the decoherence in quantum mechanics of many particles.